探究金属保护用水性醇酸涂料的研制

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1、复旦大学工程硕士学位论文目录摘要(4)Abstraet(5)第一章绪论·、················..···························……(7)1.1醇酸树脂的产生与发展(7)1.2醇酸树脂分子结构及特点····························……(7)1.3醇酸树脂的分类(8)干性油和不干性油醇酸树脂(8)3.2短油度、中油度、长油度醇酸树脂...................……(8)4制备醇酸树脂过程中主要的化学反应···············……(9)1.4.1酉旨化反应········

2、.·······..·······.··..····..……。…。.…(9)1.4.2醇解反应····························..·······……。。.。。…(9)1.4.3醋交换反应·····························.............……(10)1.4.4醚化反应(10)1.4.5不饱和脂肪酸的加成反应···························.……(10)5醇酸树脂的制造方法(10)脂肪酸法(11)5.2醇解法二(11)6醇酸树脂的制备工艺(12)熔融法(12)6.2溶剂

3、法(13)7水性醇酸树脂·············...........................……(14)1.7.1水性醇酸树脂的发展历史”””‘.”’:”’“‘”””’“”””’(14)1.7.2水性醇酸树脂的干燥机理及特点·····················……(14)1.7.3水性醇酸树脂组成及其作用··························……(15)1.7.4影响醇酸树脂水溶性的因素·················.···.....……(17)/复旦大学工程硕士学位论文1.7.5水性醇酸树脂的稳定性··.·

4、···……。.。。..···……。……(19)1.7.6配方拟定中酸超量、醇超量问题··················.····……(19)1.7.7终点控制。..···……。·.·……。.···.··……。.······……(19)1.7.8水性醇酸树脂的制造途径。···……。。。。.·····……。二。。。二(20)1.7.9水性醇酸树脂的改性·································……(21)1.7.10制备水性醇酸涂料的关键问题······……。。·.·····……(23)1.7.H水性醇酸树脂涂料的应用·，

5、’··········……，’····……(25)1.8选题的目的和意义···································……(25)第二章磺酸盐基水性醇酸树脂的合成····················……(28)2.1引言··················································……(28)2.2实验部分·····························~·············.……(28)2.2.1主要原料规格与配比…。······....·.···……。。。··

6、···……(29)2.2.2主要原料物化性能·····.········.·...···········..···……(29)2.2.3实验设备及装置图···……。.0.·····.·……。········……(30)2.2.4合成工艺············································……(32)2.2.5磺酸盐基水性醇酸树脂的表征·······················……(32)2.2.5.1胶色谱法测定磺酸盐基水性醇酸树脂的分子量.……，·(33)2.2.5.2磺酸盐基水性醇酸树脂红外光谱图··

7、············……(35)2.2.5.3磺酸盐基水性醇酸树脂乳液粒径分布······..····……(36)2.3结果与讨论···········································……(37)2.3.1脂肪酸及油度对磺酸盐基水性醇酸树脂性能的影响····……(37)2.3.2多元醇的选择·······································……(38)2.3.3多元酸的选择·······································……(39)2.3.45一(钠代

8、磺基)间苯二甲酸对水性醇酸树脂性能的影响·……(39)2.3.5磺酸盐基水性醇酸树脂醇超量与酸值的控制···········……(40)2.3.6反应