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1、ChemicalPhysicsLetters510(2011)1–13ContentslistsavailableatScienceDirectChemicalPhysicsLettersjournalhomepage:www.elsevier.com/locate/cplettFRONTIERSARTICLEMagneticallyresponsiveorderedmesoporousmaterials:AburgeoningfamilyoffunctionalcompositenanomaterialsYonghui
2、Deng,YueCai,ZhenkunSun,DongyuanZhao⇑DepartmentofChemistry,ShanghaiKeyLaboratoryofMolecularCatalysisandInnovativeMaterialsandAdvancedMaterialsLaboratory,FudanUniversity,Shanghai200433,PRChinaarticleinfoabstractArticlehistory:Magneticmesoporousmaterials,asafamilyof
3、novelfunctionalnanomaterials,haveattractedincreasingAvailableonline3May2011attentionduetotheiruniqueproperties.Muchworkhasbeendonetosynthesizethesematerialsandtoexploreapplicationsinvariousfields,suchascatalysis,separation,hyperthermia,drugdelivery,andMRimaging.Th
4、isLetterreviewsthesynthesisapproaches,whichcanbegroupedintothreecategories,i.e.sol–gelcoating,post-loading,andnanocastingapproaches.Emphasisisplacedontheelucidationofthedesignprinciples,synthesisstrategiesandtheproperties–applicationsrelationshipofthemesopor-ousm
5、aterials.Ó2011ElsevierB.V.Allrightsreserved.1.Orderedmesoporousmaterialsapplications,whichledtoanexponentialincreaseinpublicationswithinthepastdecades(Figure1),andtheproductionofalargeOrderedmesoporousmaterialsareatypeofporousmolecularnumberofmesoporousmaterialsw
6、ithvaryingchemicalcomposi-sieveswithporesizeof2.0–50nmwhicharealignedin2-Dor3-tionsandporestructures.Darraysthroughoutthematerials.Inthisarticle,unlessotherwiseThesynthesisapproachesformesoporousmaterialscanbebasi-specified,mesoporousmaterialsreferto‘orderedmesopo
7、rouscallycategorizedintotwogroups,soft-andhard-templating.Thematerials’.Retrospectively,theresearchinterestinmesoporousformerusuallyreliesontheuseofsurfactantmoleculesoramphi-materialsoriginatedfromconventionalzeolitesandmolecularphilicblockcopolymersastemplates.
8、Thetemplatemoleculessievespossessingorderedmicropores(<2.0nm)intheearlyinteractwithframeworkprecursorsandcooperativelyassemble1990swhenscientistswerepursuingsy
