资源描述：
《02-德国应化-Heterogeneously Hybridized Porous Coordination Polymer Crystals Fabrication .pdf》由会员上传分享，免费在线阅读，更多相关内容在学术论文-天天文库。
1、CommunicationsDOI:10.1002/anie.200804836Metal–OrganicFrameworksHeterogeneouslyHybridizedPorousCoordinationPolymerCrystals:FabricationofHeterometallicCore–ShellSingleCrystalswithanIn-PlaneRotationalEpitaxialRelationship**ShuheiFurukawa,KenjiHirai,KeijiNakagawa,YoheiTakashima,Ryot
2、aroMatsuda,TakaakiTsuruoka,MioKondo,RieHaruki,DaisukeTanaka,HirotoshiSakamoto,SatoruShimomura,OsamiSakata,*andSusumuKitagawa*TheformationofinterfacesbetweentwosolidphasesisofwithoutchangingthecharacteristicfeaturesofthePCP[4]greatsignificanceinthedevelopmentofnewmaterials,crysta
3、litself,resultinginthefabricationofmultifunctionalbecausemechanicalandelectronicpropertiesofmaterialsPCPs.OnewaytodecoratethecrystalsurfacesofaPCPistoarestronglyinfluencedbydistortedinterfacialstructures,hybridizethecorePCPcrystalwithadifferentshellcrystalbyleadingtopropertiesth
4、atdifferfromthoseoftheindividualepitaxialgrowthatthesingle-crystallevel,thuscreatingcore–phases.Moreover,propertiesofporousmaterials,suchasgasshellPCPheteroepitaxialcrystals.Suchalatticematchsorptionandguest-moleculeaccommodation,shouldalsopromisesporeconnectionsattheinterfacebe
5、tweencrystals,correlatewiththeinterfacialstructureofsuchmaterials,wherethemodifiedcrystalstructureshouldinfluencethebecauseguestmolecules(adsorbates)firstencounterthemobilityanddiffusionofadsorbates.Suchfabricationofsurfaceoftheporousmaterials.Hence,theaffinityofporoushybridized
6、PCPsinglecrystalsinthenanometerormicro-materialsforguestmoleculescanbetunedbymodifyingthemeterregimealsoallowsforutilizationofthesematerialsin[1][4,5]surfacestructure.biologicalsystemsandassensorsinelectronicdevices.Porouscoordinationpolymers(PCPs),ormetal–organicAlthoughafewpio
7、neeringsyntheticstudiesonthehybrid-frameworks(MOFs),areaninterestingclassofcrystallineizationofextendedcoordinationstructureshavebeen[6]porousmaterials,asitispossibletodesigntheirframeworkreported,structuraldeterminationattheinterfacesisnottopologiesandporesizesandthefunctionali
8、tyoftheporeyetknown,mostlikelybecauseofthelacko
