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1、KineticsofCatalyticReactionsM.AlbertVanniceKineticsofCatalyticReactionsWith48IllustrationsM.AlbertVanniceWilliamH.JoyceChairedProfessorDepartmentofChemicalEngineeringThePennsylvaniaStateUniversityUniversityPark,PA16802mavche@engr.psu.eduLibraryofCongressControlNumber:2005923777ISBN-10:0-387-2
2、4649-5e-ISBN:0-387-25972-4Printedonacid-freepaper.ISBN-13:978-0387-24649-9ß2005SpringerScienceþBusinessMedia,Inc.Allrightsreserved.Thisworkmaynotbetranslatedorcopiedinwholeorinpartwithoutthewrittenpermissionofthepublisher(SpringerScienceþBusinessMedia,Inc.,233SpringStreet,NewYork,NY10013,USA)
3、,exceptforbriefexcerptsinconnectionwithreviewsorscholarlyanalysis.Useinconnectionwithanyformofinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilarmethodologynowknownorhere-afterdevelopedisforbidden.Theuseinthispublicationoftradenames,trademarks,servicem
4、arksandsimilarterms,eveniftheyarenotidentifiedassuch,isnottobetakenasanexpressionofopinionastowhetherornottheyaresubjecttoproprietaryrights.PrintedintheUnitedStatesofAmerica.(SPI/SBA)987654321springeronline.comForewordHeterogeneouscatalysishasshapedourpastandwillshapeourfuture.Alreadyinvolved
5、inatrilliondollar’sworthofgrossdomesticproduct,catalysisholdsthekeytoneartermimpactareassuchasimprovedchemicalprocessefficiency,environmentalremediation,developmentofnewenergysources,andnewmaterials.Furthermore,recentadvancesinunderstandingandcomputingchemicalreactivityatthequantumlevelareope
6、ningnewpathwaysthatwillacceleratethedesignofcatalystsforspecificfunctions.Thisenormouspotentialwillultimatelybeturnedintorealityinlaboratoryreactorsandhaveitsimpactonsocietyandtheeconomyintheindustrialreactorsthatlieattheheartofallchemicalprocesses.Becausethequantita-tivemeasureofcatalystperf
7、ormanceisthereactionrate,itsmeasurementiscentraltoprogressincatalysis.Thepagesthatfollowareacomprehensiveguidetosuccessforreactionratemeasurementsandanalysisincatalyticsystems.Thetopicschosen,theclarityofpresentation,andtheliberaluseofspecifi
