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1、JournalofPowerSources146(2005)107110ApplicationsofhighpowerdensitylithiumionbatteriesT.Horibaa,∗,T.Maeshimaa,T.Matsumuraa,M.Kosekia,J.Araib,Y.MuranakabaShin-KobeElectricMachineryCo.,Ltd.,Okabe-machiOhsato-gun,Saitama369-0297,JapanbHitachiResearchLaboratory,Hitachi,Ltd.,Ohmika-choHitachi
2、,Ibaraki319-1292,JapanAvailableonline20June2005AbstractIn2003,wedevelopedanewtypeoflithiumionbatteryforthelightvehicleapplication,inwhich14cellsof7Ahwereintegratedintoabatterypack.Ithasthehighratedischargecapabilityupto5Crate(35A),aenergydensityof74Whkg−1,andthelowtemperaturedischargeca
3、pacityat−5◦Cmorethan90%ofthatat25◦C.Thelifecycletestof100%depthofdischarge(DOD)at35◦Cshowedthecapacityfadingaround10%after500cycles,whichconfirmedmuchlongerpracticallifethan2years.Recently,wehavedevelopedanewhighpowercell.Ithasthecapacityof5.5Ah,andhastheoutputpowerdensityof3000Wkg−1at50
4、%stateofcharge(SOC)andat25◦Cfor5sdischargebasis,andtheinputpowerdensityof2200Wkg−1atthesameconditions.Thenewcellsshowedmuchlessincreaseindirectcurrentresistance(DCR)inboththecyclelifetestandthestoragelifetestthanthecellsdevelopedbefore,whichconsequentlyimpliedmuchlongercalendarlifethano
5、urpreviousonesdevelopedin2000.©2005ElsevierB.V.Allrightsreserved.Keywords:Directcurrentresistance;Lithiumionbattery;Calendarlife1.Introductioniesinmodulebasis.Thehighenergydensityperformanceoflithiumionbatteriesisexplicitlyillustratedinthefigure.Wehavebeendevelopinglithiumionbatteriessin
6、cetheTheplotsofHEVandpure-EVarethosethatwedevel-beginningof1990s,asamemberofnationalprojectofJapan,opedin2000asdescribedabove.ThesetwoplotsprovethatnamedTheDevelopmentofDispersed-TypeBatteryEnergythelithiumionbatteriesareflexibleenoughtobedesignedStorageTechnology.Wehavebeenconcentrating
7、onthefromhighpowerspecificationtohighenergyspecification.manganese-basedpositiveelectrodematerialsintheprojectTheplotoflightvehicleinFig.1correspondstothatwe[1].Byutilizingtheresultsdevelopedintheproject,wehavedevelopedrecentlyanditalsoprovestheflexibilitymentionedreleasedlargecap