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ID:34043079
大小:9.36 MB
页数:91页
时间:2019-03-03
《%5bmo(cn)8%5d4-基配位聚合物微%2f纳米材料的可控合成及表征》由会员上传分享,免费在线阅读,更多相关内容在教育资源-天天文库。
1、【Mo(CN)8】4鼍釜配位聚合物微/纳米材料的可控合成及表征(3)采用聚合物保护法,以【Mo(CN)8】4’和Mn2+为构筑单元,PVP或PEG为保护剂,成功制备了方片状、米粒状、花状、棒状、八面体等多种形貌的Mn2【Mo(CN)8】。xH20微/纳米晶体。系统研究了各种反应条件对Mn2【Mo(CN)8】·xH20微/纳米晶体合成的影响并探讨了生长机理。并尝试对方片状Mn2【Mo(CN)8】·xH20微/纳米晶进行煅烧。(4)采用反相微乳液法,以【Mo(CN)8】4一和zn2+为构筑单元,双(2一乙己基)磺基丁二酸钠(
2、AOT)为表面活性剂,探索合成了立方块状及球状Zn2【Mo(CN)8】·xH20微/纳米晶体,研究了反应物浓度等对其形貌的影响。关键词:配位聚合物(CP),八氰合钼,微纳米材料,可控合成江苏大学硕士学位论文Coordinationpolymers(CP)aremetal-ligandcompoundswiththehighlyorderedandinfmitestructllres,andhavenumefouspotential叩plicationsinthefieldsofmagnetism,gasstorage,c
3、atalysis,nolllillearoptics,andsoon.Recently,CPnaJlocrystalswithfiniterepeatingunitsandnoVelmo叩holo百eshaVeraisedrenewedandgrowinginterestbecauseoftheirspecialpropertiesdi虢rentfI.omConventionalbulkCP.T11emostwidelyinvestigatedCPmicro/nano.stmcturesarePmssianbluepB)
4、anditsanalogues,inwhichthemicro/nano—crystalswithdifc色rentsizesandmo叩holo酉esincludingspheres,cubes,nlbes,wiresandpolyhedronshavebeensynthesizedttlrou曲solution-basedroutesortemplatetechniques.Asonenewl【indoffunctionalmaterials,octacyanometalate_basedCPofTM2【M(CN)8
5、】’IlH20(M=Mo,W;TM=Mn,Fe,Co,NiandCuetc)havebeenattractingmoreandmoreattentionbecauseoftheiruniquepropertiesinthema驴etic,the咖alandadso印tionissues.HoweVer,littleattentionhasbeendeVotedtothestudyofmicro/nano.objectsbasedonsuchasystem.Inthispaper,thecurrentprogressiIl
6、CPmicro/nanomaterialswasreviewedandavarietyofCPmicro/nanocrysyalsofoctacyano-bridgedcomplexesofFe2【Mo(CN)8】。xH20,C02【Mo(CN)8】。xH20,Mn2【Mo(CN)8】·xH20andZn2【Mo(CN)8】‘xH20weresuccessfuUysynthesizedbymildsolutionapproachssuchaspolymerprotectingmethod,reVersemicroemul
7、sionmethodetc·Infra.red(IR)spectroscopy,x—raydiff}action(xRD),sca皿ingelectronmicroscopy(SEM),fieldemissionsca皿ingelectronmicroscopy(FESEM),transmissionelectronmicroscopy(TEM)andThenIlo掣av油etric-Di虢rentialSca衄ingCalorimetry(TG-DSC)wereusedtocharacterizetheas-synth
8、esiZedCPmicr0/nanometerials.AseriesofsystematicallycontrolledexperiIIlentshaVebeencaHiedouttoreVealthee1三f色ctsofVariousexperimentalpar锄eterssuchasreactiontempe
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