[化学丛书].Principles.and.Applications.of.Asymmetric.Synthesis

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1、PrinciplesandApplicationsofAsymmetricSynthesisGuo-QiangLin,Yue-MingLi,AlbertS.C.ChanCopyright(2001JohnWiley&Sons,Inc.ISBNs:0-471-40027-0(Hardback);0-471-22042-6(Electronic)PRINCIPLESANDAPPLICATIONSOFASYMMETRICSYNTHESISPRINCIPLESANDAPPLICATIONSOFASYMMETRICSYNTHESISGuo-Qiang

2、LinYue-MingLiAlbertS.C.ChanAJOHNWILEY&SONS,INC.,PUBLICATIONNewYork.Chichester.Weinheim.Brisbane.Singapore.TorontoDesignationsusedbycompaniestodistinguishtheirproductsareoftenclaimedastrademarks.InallinstanceswhereJohnWiley&Sons,Inc.,isawareofaclaim,theproductnamesappearini

3、nitialcapitalorallcapitalletters.Readers,however,shouldcontacttheappropriatecompaniesformorecompleteinformationregardingtrademarksandregistration.Copyright(2001byJohnWiley&Sons,Inc.Allrightsreserved.Nopartofthispublicationmaybereproduced,storedinaretrievalsystemortransmitt

4、edinanyformorbyanymeans,electronicormechanical,includinguploading,downloading,printing,decompiling,recordingorotherwise,exceptaspermittedunderSections107or108ofthe1976UnitedStatesCopyrightAct,withoutthepriorwrittenpermissionofthePublisher.RequeststothePublisherforpermissio

5、nshouldbeaddressedtothePermissionsDepartment,JohnWiley&Sons,Inc.,605ThirdAvenue,NewYork,NY10158-0012,(212)850-6011,fax(212)850-6008,E-Mail:PERMREQ@WILEY.COM.Thispublicationisdesignedtoprovideaccurateandauthoritativeinformationinregardtothesubjectmattercovered.Itissoldwitht

6、heunderstandingthatthepublisherisnotengagedinrenderingprofessionalservices.Ifprofessionaladviceorotherexpertassistanceisrequired,theservicesofacompetentprofessionalpersonshouldbesought.ISBN0-471-22042-6ThistitleisalsoavailableinprintasISBN0-471-40027-0.Formoreinformationab

7、outWileyproducts,visitourwebsiteatwww.Wiley.com.DedicatedtoProfessorsChung-KwongPoonandWei-ShanZhouCONTENTSPrefacexiiiAbbreviationsxv1Introduction11.1TheSigni®canceofChiralityandStereoisomericDiscrimination31.2Asymmetry71.2.1ConditionsforAsymmetry71.2.2Nomenclature81.3Dete

8、rminingEnantiomerComposition161.3.1MeasuringSpeci®cRotation171.3.2TheNuclearMagneticReson