碳基纳米材料（单壁碳纳米管和单层石墨）的性质及应用探索

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1、AbstracttransmittinghighfrequencyACsignals．Finally,graphenewasusedasanewacceptormaterialinorganicBHJphotovoltaicdeviceswithP3HTandP30Taselectrondonor．ThefunctionalizedgraphenematerialcanbedispersedintoorganicsolventwithacceptingmaterialP30TandP3HTtoformhomogeneouss

2、olution．Theinteractionbe“VeengrapheneandP30T厅3HTmakethiscompositeworkwellastheactivelayerintheBI-IJPVdevices．ControlledannealingiI】1p郴thePVdeviceperformanceconsiderably,andthebestpowerconversionefficiencyof1．4％Wasobtainedforthedevicewi吐lastructureITO(～17Qsq-1)／PEDO

3、T：PSS(40nm)／P30T：graphene(100nm)／LiF(1nm)／Al(70nm)under100mWAMI．5Gcondition．Withtheuniquestructureandexcellentelectronicproperties，abundantandhighlypurefunetionalizedgraphenematerialreadilyavailable,andmuchoptimizationahead,wefullyexpectthisorganicsolublefunctioanl

4、izedgraphenematerialmaywellserveasacompetitivealternativeofPCBMforhighperformanceorganicPVdeviceandotherapplications．Keywords：singlewalledcarbonnanombes，electromagneticinterferenceshieldingelectromagneticwaveabsorption，halloreactor,organicphotovoltaiccellV符号说明CNT(C

5、NTs)SWNT(SWNTs)MWNT(MWNTs)D、ⅣNT(DWtCrs)He-SW№C02一SWNl’sC02-SWNT-annealedAPSWNTsGoSPFG．PSPUPEOSCPUPⅦFABSPCBMP30TP3HTHTPBPrCBICuPeDPM—12DM【FDCBMDIBDTritonX．100PTCDAAPNABPOITO丌oPEDOT：PSS碳纳米管单壁碳纳米管多壁碳纳米管双壁碳纳米管He气氛下制备的单壁碳纳米管C02．He混合气体下制备的单壁碳纳米管热处理后的C02=He混合气体下制备的单壁碳纳米管制

6、备出未加处理的单壁碳纳米管单层氧化石墨有机可溶的单层氧化石墨聚苯乙烯聚氨酯聚氧乙烯可溶解交联聚氨酯聚偏氟乙烯丙烯氰．丁二烯．苯乙烯三元共聚物苯基C6l丁酸甲酯(PCBM)聚(3．辛基噻吩)聚(3．己基噻吩)羟基封端的聚丁二烯lO．四羧基j芭酞箐铜二苯基富勒烯N，N’．二甲基甲酰胺邻二氯苯二苯甲烷二异氰酸酯1，4一丁二醇Polyoxyethylerie(1o)isooctylphenyletherj毛四甲酸二酐二腺苔酸三磷酸过氧化二苯甲酰氧化铟锡氟化氧化锡聚二氧乙基噻吩／聚对苯乙烯磺酸XII符号说明PPVMDMo-PPVM匝H

7、—PPVsil{NABSCCOEMlSTMSEMTEMHR．1琶MFEGTEMphaserestoreTEMEELSⅪmFr．ⅡtAFMRamaa矧DSCNMRlHNMRUV啊s-NIRArcingCvDHipCOQHEEgMIMIUMoHOMOD／ARCSl璩MfwhmEiiDFrMDAbinitiodB聚苯撑乙烯2．甲氧基-5-(3，7．二甲基辛氧基)对苯撑乙烯聚【2．甲氧基-5-(2’．乙烯基．己氧基)聚对苯乙烯撑】信使RNABSrCaCu氧化物电磁波屏蔽扫描探针显微镜扫描电子显微镜透射电子显微镜高分辨透射电子显微镜场

8、发射枪扫描透射电子显微镜相还原透射电子显微镜能量损失谱X射线衍射法傅立叶变换红外光谱原子力显微镜拉曼光谱热失重分析法差示扫描量热法核磁共振核磁共振氢谱紫外一可见一近红外光谱电弧放电法化学气相沉积法高压裂解法量子霍尔效应带隙宽度’金属一非金属．金属模型最低占据轨道最高空轨道给／受体雷达散射截