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ID:33331314
大小:13.03 MB
页数:75页
时间:2019-02-24
《以生物质为碳源制备多孔碳及其吸附性能研究》由会员上传分享,免费在线阅读,更多相关内容在学术论文-天天文库。
1、万方数据AbstractIn恤study,cornstarchandshaddockpeelwereutilizedtopreparethecarbonmaterials.Themethodofpyrolysiscarbonizationwasadoptedinthestudyforitseasyoperationandcausinglittlepollution.Andtheresearchesaboutusingstarch。basedcarbonandshaddockpeel—basedcarbontoremov
2、eheavymetalionspollutantsincludingCu2+,Pb2+andCd2+fromsimulatedw硒tewaterwereca玎iedoutpreliminarily.Theas-preparedcarbonmaterialswerecharacterizedbyusingscanningelectronmicroscope,X-raypowerdiffractometerandFouriertransforminginfraredspectrum.ItWasfoundthatthemic
3、rostructureandsurfacefunctionalgroupsofthebiomasscarbonwerechangedwiththesynthesizingconditions.AlargenumberofporesinthebiomasscarbonandsomeoxygenfunctionalgroupsCancontributetotheadsorptionperformances.Thestructuresandtheadsorptionperformanceforas-preparedcarbo
4、natdifferentsynthesizingconditionswereexplored,suchastheconcentrationofstarch,thecontentofepoxychloropropane,thereactiontimeandthemaximumcarbonizationtemperature.Hi曲carbonizationtemperatureandmoderatecontentofepoxychloropropaneCanimprovepollutantremovalcapabilit
5、yforthebiomasscarbon.Theoptimalpreparationconditionsofstarch,basedcarbonwerethattheconcentrationofstarchWas3%,thecontentofepoxychloropropaneWas20%,thereactiontimeWas16handthemaximumcarbonizationtemperatureWas800。C.Theoptimalpreparationconditionofshaddockpeel—bas
6、edcarbonWasthatthemaximumcarbonizationtemperatureWas800℃.TheinfluencesofseveralexperimentalparametersincludinginitialpH,themassofbiomasscarbon,adsorptiontimeandinitialconcentrationofheavymetalionontheremovalofCu2+,Pff+andCd2+fromsimulatedwastewaterbythebiom舔sc孙o
7、nwerestudied.TheresultsshowedthattheoptimalinitialpHvalueforremovingCu2+,Pb什andCd2十withstarch-basedcarbonwere7.0,6.0and8.0,respectively.AndtheoptimalinitialpHvaluesforremovingCu2+,ab:+andCd2+withshaddockpeel.basedcarbonwere6.0.TheadsorptionequilibriumWasreachedi
8、n4h.TheabsorptionefficiencyforCu2+WasbetterthanforPb2+andCd2+,andtheabsorptionefficiencvfor万方数据Cd2+wastheworstamongCu2+.pb2+andCd2+.Theresultsshowedthattheadsorptionc
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