以生物质为碳源制备多孔碳及其吸附性能研究

以生物质为碳源制备多孔碳及其吸附性能研究

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时间:2019-02-24

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1、万方数据AbstractIn恤study,cornstarchandshaddockpeelwereutilizedtopreparethecarbonmaterials.Themethodofpyrolysiscarbonizationwasadoptedinthestudyforitseasyoperationandcausinglittlepollution.Andtheresearchesaboutusingstarch。basedcarbonandshaddockpeel—basedcarbontoremov

2、eheavymetalionspollutantsincludingCu2+,Pb2+andCd2+fromsimulatedw硒tewaterwereca玎iedoutpreliminarily.Theas-preparedcarbonmaterialswerecharacterizedbyusingscanningelectronmicroscope,X-raypowerdiffractometerandFouriertransforminginfraredspectrum.ItWasfoundthatthemic

3、rostructureandsurfacefunctionalgroupsofthebiomasscarbonwerechangedwiththesynthesizingconditions.AlargenumberofporesinthebiomasscarbonandsomeoxygenfunctionalgroupsCancontributetotheadsorptionperformances.Thestructuresandtheadsorptionperformanceforas-preparedcarbo

4、natdifferentsynthesizingconditionswereexplored,suchastheconcentrationofstarch,thecontentofepoxychloropropane,thereactiontimeandthemaximumcarbonizationtemperature.Hi曲carbonizationtemperatureandmoderatecontentofepoxychloropropaneCanimprovepollutantremovalcapabilit

5、yforthebiomasscarbon.Theoptimalpreparationconditionsofstarch,basedcarbonwerethattheconcentrationofstarchWas3%,thecontentofepoxychloropropaneWas20%,thereactiontimeWas16handthemaximumcarbonizationtemperatureWas800。C.Theoptimalpreparationconditionofshaddockpeel—bas

6、edcarbonWasthatthemaximumcarbonizationtemperatureWas800℃.TheinfluencesofseveralexperimentalparametersincludinginitialpH,themassofbiomasscarbon,adsorptiontimeandinitialconcentrationofheavymetalionontheremovalofCu2+,Pff+andCd2+fromsimulatedwastewaterbythebiom舔sc孙o

7、nwerestudied.TheresultsshowedthattheoptimalinitialpHvalueforremovingCu2+,Pb什andCd2十withstarch-basedcarbonwere7.0,6.0and8.0,respectively.AndtheoptimalinitialpHvaluesforremovingCu2+,ab:+andCd2+withshaddockpeel.basedcarbonwere6.0.TheadsorptionequilibriumWasreachedi

8、n4h.TheabsorptionefficiencyforCu2+WasbetterthanforPb2+andCd2+,andtheabsorptionefficiencvfor万方数据Cd2+wastheworstamongCu2+.pb2+andCd2+.Theresultsshowedthattheadsorptionc

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