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1、学兔兔www.xuetutu.com第19卷第1期粉末冶金材料科学与工程2014年2月Vol.19No.1MaterialsScienceandEngineeringofPowderMetallurgyFeb.2014核阀密封面FCo-5合金粉末激光熔覆层的组织与性能1,21,22李必文,张春良,金坤文(1.南华大学核科学技术学院,衡阳421001;2.南华大学机械工程学院,衡阳421001)摘要:以FCo-5自熔性钴基合金粉末为堆焊材料,在0Cr18Ni12Mo3Ti核阀试样表面制备厚度为2.04mm、横截面单圆弧拟合半径为2.69mm的密封面激光熔覆
2、层。利用SEM和XRD分析熔覆层的微观结构和物相,测试熔覆层的显微硬度及最小厚度处的高温硬度。结果表明:熔覆层从界面到表层的结晶形态依次由平面晶向胞状树枝晶、多方向生长树枝晶、细小树枝晶过渡;中、上部组织主要由γ-Co奥氏体枝晶、枝晶间层片状共晶组织以及弥散分布的Cr23C6硬质颗粒组成;在距界面1.52~1.60mm的区域,密封带宽度为2.95~3.18mm,常温硬度阈值为44.3~45HRC;在650℃以下时,熔覆层最小厚度处具有优异的抗蠕变性能和高温硬度特性,经720℃以上回火处理后有较强的二次硬化效应。关键词:FCo-5钴基合金粉末;核阀密封面;
3、激光熔覆层;组织;硬度中图分类号:TG174.44文献标识码:A文章编号:1673-0224(2014)1-159-06MicrostructureandperformanceoflasercladdinglayerofFCo-5alloypowderonnuclearvalvesealingsurface1,21,22LIBi-wen,ZHANGChun-liang,JINKun-wen(1.SchoolofNuclearScienceandTechnology,UniversityofSouthChina,Hengyang421001,China;2
4、.SchoolofMechanicalEngineering,UniversityofSouthChina,Hengyang421001,China)Abstract:Asealingsurfacelasercladdinglayerwiththicknessof2.04mmandcrosssectionofcirculararchavingafittingradiusof2.69mmwaspreparedona0Cr18Ni12Mo3TinuclearvalvesamplesurfaceusingFCo-5fluxedcobalt-basealloyp
5、owderasoverlayingweldingmaterial.ThemicrostructureandphasecompositionofthecladdinglayerwereanalyzedusingSEMandXRD.Themicrohardnessofthecladdinglayerandhightemperaturehardnessatthepositionwithminimumthicknessweremeasured.Theresultsshowthatthecrystalmorphologyofcoatingalteredinturn
6、asplanecrystalcellulardendrites,multi-directionalgrowthdendritesandfinedendritesfromtheinterfacetosurface.Themidanduppermicrostructuremainlyconsistsofγ-Coaustenitedendrite,interdendriticlayerlamellareutecticorganizationanddispersedCr23C6hardparticlephase.Thesealbeltwidthvariesfro
7、m2.95mmto3.18mm,hardnessthresholdundernormaltemperatureis44.3~45HRCintheregionawayfromtheinterface1.52~1.60mm.Theminimumthicknesslocalizedcladdinglayerhasthecharacteristicofgoodcreepresistanceandhightemperaturehardnessbelow650℃,aswellascangeneratestrongsecondaryhardeningeffectaft
8、ertemperingabove720℃.Keywords:FCo-5cobal