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1、ReductionsbytheAlumino-andBorohydridesinOrganicSynthesisSecondEditionJacquelineSeyden-PenneWILEY-VCHNEWYORK/CHICHESTER/WEINHEIM/BRISBANE/SINGAPORE/TORONTOJacquelineSeyden-PenneLeVallatdeVermenoux84220GoultFranceEnglishLanguageEditorDennisP.CurranDepartmentofChemistryUniversity
2、ofPittsburghParkmanAvenue&UniversityDrivePittsburgh,PA15260Thisbookisprintedonacid-freepaper.@Copyright©1997byWiley-VCH,Inc.Allrightsreserved.PublishedsimultaneouslyinCanada.Nopartofthispublicationmaybereproduced,storedinaretrievalsystemortransmittedinanyformorbyanymeans,elect
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5、nPublicationData:Seyden-Penne,J.[Reductionsparlesaiumino-etborohydruresensynthesesorganique.English]Reductionsbytheaiumino-andborohydridesinorganicsynthesis/JacquelineSeyden-Penne.—2nded.p.cm.Includesbibliographicalreferencesandindex.ISBN0-471-19036-5(cloth:alk.paper)1.Reducti
6、on(Chemistry)2.Hydrides.3.Organiccompounds—Synthesis.I.Title.QD63.R4S49131997547'.23—dc2196-49776PrintedintheUnitedStatesofAmerica10987654321ContentsPrefaceixForewordxiAbbreviationsxiii1.DescriptionandCharacteristicsoftheMainReagents11.1LithiumandSodiumAluminohydrides:LiAlH4(L
7、AH),NaAlH4(SAH)/11.2LithiumandSodiumAlkoxy-andAminoaluminohydrides/21.3Sodiumbis(methoxyethoxy)aluminohydride:Na(OCH2CH2OCH3)2A1H2(Red-Al)/31.4DiisobutylAluminumHydride:;-Bu2AlH(DIBAH)/41.5AluminumHydride(A1H3),Aminohydrides,andAluminumChlorohydrides(A1H2C1,A1HC12)/41.6Sodiuma
8、ndPotassiumBorohydrides:NaBH4,KBH4/51.7LithiumBorohydride:LiB