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1、EnantioselectiveOrganocatalysisEditedbyPeterI.DalkoEnantioselectiveOrganocatalysisReactionsandExperimentalProceduresEditedbyPeterI.DalkoTheEditor9AllbookspublishedbyWiley-VCHarecarefullyproduced.Nevertheless,authors,Dr.PeterI.Dalkoeditors,andpublisherdonotwarranttheUniversite´Rene´Descartes
2、,ParisVinformationcontainedinthesebooks,CNRS,LaboratoiredeChimieetBiochimieincludingthisbook,tobefreeoferrors.PharmacologiquesetToxicologiquesReadersareadvisedtokeepinmindthat45,ruedesSaints-Pe`resstatements,data,illustrations,procedural75270Paris,Cedex06detailsorotheritemsmayinadvertentlyb
3、eFranceinaccurate.LibraryofCongressCardNo.:appliedforBritishLibraryCataloguing-in-PublicationDataAcataloguerecordforthisbookisavailablefromtheBritishLibrary.BibliographicinformationpublishedbytheDeutscheNationalbibliothekDieDeutscheNationalbibliothekliststhispublicationintheDeutscheNational
4、-bibliografie;detailedbibliographicdataareavailableintheInternetathttp://dnb.d-nb.de82007WILEY-VCHVerlagGmbH&Co.KGaA,WeinheimAllrightsreserved(includingthoseoftranslationintootherlanguages).Nopartofthisbookmaybereproducedinanyform–byphotoprinting,microfilm,oranyothermeans–nortransmittedortran
5、slatedintoamachinelanguagewithoutwrittenpermissionfromthepublishers.Registerednames,trademarks,etc.usedinthisbook,evenwhennotspecificallymarkedassuch,arenottobeconsideredunprotectedbylaw.PrintedintheFederalRepublicofGermanyPrintedonacid-freepaperCoverdesignSchulzGrafik-Design,Fußgo¨nheimTypes
6、ettingAscoTypesetters,HongKongPrintingbetz-druckGmbH,DarmstadtBookbindingLitges&DopfBuchbindereiGmbH,HeppenheimWileyBicentennialLogoRichardJ.PacificoISBN978-3-527-31522-2VContentsPrefaceXVListofContributorsXVIIListofAbbreviationsXXI1AsymmetricOrganocatalysis:ANewStreaminOrganicSynthesis1Pete
7、rI.Dalko1.1Introduction11.2HistoricalBackground21.3Catalysts61.3.1PrivilegedCatalysts91.3.1.1Proline91.3.1.2CinchonaAlkaloids101.3.1.3TADDOLsandDerivatives111.3.1.4BinaphtholDerivatives111.4ReactionTypes121.4.1CovalentCatalysis121.4.2Non-CovalentOrganoca
