2011年暨南大学818有机化学考研试题

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1、2011年招收攻读硕士学位研究生入学考试试题（A卷）********************************************************************************************818//B1.C7H16102202.(E)-3,4--3-3.R-2-4.6.-1--4-CH2CH2NHCH35.7.-H2NCH2COOH8.HCCCH3HCH(CH3)29.NNO2NH2OH10.HOHOOOHOCH31.()15230A.C6H5C

2、O-B.–CH2COOHC.–CH=CH2D.–OCH32.A.CH3CH=CHCH2CH3C.CH2=CH-CH2CH3()B.CH2=CHC≡CHD.C6H5CH33.240°,()A.1B.2C.3D.44.()A.C.5.A.C.6.-SN2()()B.D.B.D.A.B.C.D.NaOH,7.()OOHA.CHOB.HC.8.OHOCH3()D.CH3CHCOOHOHA.CH3COCH2COOC2H5C.CH3COCH2COCH39.B.CH3COCH2CH3D.CH2(CO2C

3、2H5)2A.C.>>>>B.D.>>>>10.A.B.C.,()D.NaOH,11.CO2()A.12.A.13.A.14.A.15.A.B.B.B.B.B.C.C.C.C.C.(19)()D.D.â-D-D.()D.D.250()hõ1.2.CH2CH3+OHBr2H2SO43.OCH3+CH3OHH+CH34.5.HO+HBrNH2NaNO2/HClOHOH6.CH3CH2CH2CHOBrKOH/EtOHKMnO47.CH3H+8.BrCH2Br1.CN-2

4、.H3O+SOCl29.CH3CH=CHCHOO10.CHOHOCH2CH2OHNaOHOsO4H3CCH31.O311.HCH3CH32.Zn/H2OH2SO412.13.O+NH2H+-H2OH3COCHOAg2OHCl/H2O14.HO15.CO2EtCO2Et+ONH2NH21.EtONa2.H2ONaOH16.NCH3+PhCHO17.HHCH3PhCH3CH3IAg2ON(CH3)2NaOHHCHO18.CHO+HCHONaOHOHOAl[OCH(CH3)2]31

5、9.1.3+30102400ml40g0.5molKMnO49.2g0.1mol1233hr7.3g200ml2.12C13H20N2O2IR1700cm-1NMRä(ppm)1.5((3.8,6H),2.6(,4H)A,4H),2.75(,2H),4.2(NMRB,2H),4.35(ä4.2ppm,2H),6.5-7.8ClMeOMeOOBnOCO3HMeOMeOOBnHOOMeOHMeO4A20B1.2.44HOHHCH2CH3,CH3,H3COOCH2CH2C

6、H3CH33.(6)OO4.6tosufluoxacinOCOOH6--2-CH(OC2H5)3H3CNNC2H5Tosufloxacin,