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1、学院系班级学号姓名-----------------------------------------------------------------------------------------装--------------------------------订-------------------------------线-------------------------------------------------------------------扬州大学试题纸（2004—2005学年第一学期）化学化工学院班（年）级课程有机化学（A）卷学号姓名题号一二三四五六七八九十总分得分一
2、、MultipleChoice(共10题,20分)1.1分(7539)7539Thecorrectnameofaboveconfigurationis:（A）(1)R,(2)R,(3)S（B）(1)R,(2)S,(3)S（C）(1)S,(2)S,(3)S（D）(1)R,(2)R,(3)R3.1分(0092)0092TheIUPACnameis:(A)(2Z,4E)-4-tert-butyl-2,4-hexadiene(B)(2E,4Z)-3-tert-butyl-2,4-hexadiene(C)(2Z,4E)-3-tert-butyl-2,4-hexadiene(D)(2E,4Z)-4-
3、tert-butyl-2,4-hexadiene4.1分(9415)9415Thereagentwhichbecommonusedtodistinguishthestructureofalcoholis：（A）Grinardreagent（B）lindlarcatalyst（C）Sorraletreagent（D）Locasreagent5.1分(0066)0066Themainproductofthereactionof1-methylcyclohexenewithHBris:(A)1-bromo-1-methylcyclohexane(B)cis-1-bromo-2-methylcy
4、clohexane(C)trans-1-bromo-2-methylcyclohexane(D)1-bromo-3-methylcyclohexane126.1分(8613)8613Thebestreagentsforthefollowingreactionis？7.1分(9322)9322Conversionof2-methyl-1-butanolfirstlytotosylatebythereactionwithTsCl,thentoitsbromidebythereactionwithNaBr.Intwosteps,whichiscorrectinthefollowingstate
5、ments.（A）Retentionofconfigurationinfirststep,inversioninsecondstep（B）Retentionofconfigurationinbothfirstandsecondsteps（C）Inversionofconfigurationinfirststep，Retentioninsecondstep（D）Inversionofconfigurationinbothfirstandsecondsteps8.1分(0064)0064AcompoundwithmolecularformulaC6H12wasreactedfirstlywi
6、thO3,thenwithMe2StogiveCH3CHOandCH3COCH2CH3,Thestructureofthiscompoundis:9.1分(7544)7544(A)Thesamecompound(B)diastereomer(C)enantiomer(D)cis-transisomer10.1分(0032)0032Thegeometricconfigurationofcarbonatominalkaneis:(A)tetrahedron(B)cubic(C)Line(D)pyramid11.1分(9314)9314Arrangethefollowingionsasthed
7、ecreasesequenceofbasicity12A.(2)>(3)>(4)>(1)B.(3)>(2)>(4)>(1)C.(4)>(2)>(3)>(1)D.(2)>(4)>(3)>(1)12.1分(7506)7506Inthefollowingcompoundswhichoneisthemostquicklytohydrationbyacidcatalyst：(A)CH3CH=CH2(B)CH3CH2CH=CH2(C)(CH3)
