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1、聚硅酸氯化铝絮凝剂的研制及性能研究摘要:聚硅酸氯化铝(PASC)是一种新型的无机高分子絮凝剂。其研究思路是,带负电的聚硅酸具有较高的相对分子质量,对水体中的胶体颗粒具有很强的吸附能力;而铝盐在水中可以水解形成系列带正电的荷的水解羟基铝离子,具有较强的电中和能力。将二者复合成一种产品,可使其成为同时具有电中和作用及吸附架桥能力的无机高分子混凝剂。关键词:聚硅酸氯化铝(PASC)COD絮凝剂印染废水;Determineditsbestpreparationsenateelementis:SiO2%=2.0%,AL/Si=1.
2、5,pH=4-5,thetemperature,thestirstimeandtheintensityrespectivelyis:70oC,60min,1000r/min.Toprintinganddyethetreatmentofthewastewater,theexperimentalresultindicates,themostsuitableoperationparameteris:Throwitwithmeasuring255mg/l,PH=8.100r/Minstirs5min.BestCODexceptr
3、ateis65.22%,thebestturbidityexceptrateis99.39%.Comparesthepolymerizationaluminumchloride(PAC)CODremoveingrateis54.54%,bestturbidityremoveingrateis99.12%,itsflocculationeffectfairlygood,thecostislowerthanPAC.HasthecertainsignificancetotheactualwatertreatmentStudyo
4、nthePreparationandFlocculatingPerformancePolysilicic-AluminumChlorideStudents:ZouWeiyangtzuniversityofchemistryandenvironmentalprojectinstitute,counselor:DaiJie,chemistryofuniversityoftheChangjiangRiverandenvironmentalprojectinstitute.Abstact:Polysilicic-Aluminum
5、chloride(PASC)isanewtypemacromoleculeofflocculants,Itsresearchmentalityis,beltnegativeelectricitygathersthesilicicacidtohavethehigherrelativemolecularmass,hastheverystrongadsorptivecapacitytointhewaterbodycolloidpellet;Butthealuminumsaltmaythehydrolisisformseries
6、beltpositiveelectricityHollandinthewaterthehydrolisishydroxy-aluminiumion,hasinastrongerelectricityandtheability.Duplicatesynthesizesonekindofproductthetwo,maycauseittobecomesimultaneouslyhastheelectricityneutralizationandtheadsorptionbridgingabilityinorganichigh
7、polymer29flocculatingagent.Thisexperimentappliesthesodiumsilicate,thealuminumchloridemakesunderthecertainconditiongathersthesilicicacidaluminumchloride(PASC).Andtoitsstability,SiO2%content,AL/ASimoleofratio,thePHvalue,stirthetimeandtheintensitycarriesontheresearc
8、hanalysis,carriesonthedecolorizationtotheprintingwastewater,eliminates,excepttheCODprocessing,theexperimentalresultindicated,mostissuitabletheoperationparamete