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1、硼氢化钠催化水解制氢研究进展梁艳戴洪斌**王平(中国科学院金属研究所沈阳材料科学国家（联合）实验室沈阳110016)摘要硼氢化钠（NaBH4）催化水解制氢是一项具备车载氢源应用前景的储氢/制氢一体化技术，该技术具有储氢效率高、安全、方便、对环境友好等特点，目前，它已成为各种储氢/制氢技术研究的热点。介绍了NaBH4催化水解制氢的原理，综述了制氢催化剂、反应动力学、反应机理、反应装置的设计和反应副产物偏硼酸钠(NaBO2)的再生最新研究进展，并对该技术的应用前景进行了展望。关键词硼氢化钠储氢/制氢催化剂反应动力学制氢
2、装置中图分类号:TM911.4;TQ116.2文献标识码：A文章编号：1005-281X(2008)-0000-00ProgressinStudyofHydrogenGenerationfromCatalyticHydrolysisofSodiumBorohydrideSolutionLiangYanDaiHongbin**WangPing(ShenyangNationalLaboratoryforMaterialsScience,InstituteofMetalResearch,ChineseAcademyofS
3、cience,Shenyan110016,China)AbstractHydrogengeneration(HG)fromcatalytichydrolysisofsodiumborohydride(NaBH4)solutionisapromisingon-boardhydrogenstorage/generationintegratedtechnologyinthepracticalapplication.Currently,attentionisbeingextensivelypaidtoNaBH4-based
4、catalytichydrolysissystemduetoitsadvantagesofhighhydrogencapacity,safety,convenience,theenvironmentallybenignhydrolysisproductionandsoforth.ThisperspectivepresentstheprincipleofHGfromNaBH4solution,andreviewsthecurrentprogressesinHGsystemofthehydrolysisofthecat
5、alyst,reactionkinetics,reactionmechanism,designofreactiongeneratorandrecycleofhydrolysisproduction,aimingatprovidinganoutlineofforefrontofthetechnologyforthepracticalapplication.KeywordsSodiumborohydride;Hydrogenstorage/generation;Catalyst;Reactionkinetics;Hyd
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