河北省衡水市联考卷2021-2022学年高三3月份模拟考试化学试题含解析

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12ᙠ᩽^ᵯZ¡(RS,-ᵯ᩽,-2X6Li++N2+6e=2Li3N,ᐙᵯL£ᵯḄ⌮1¥¦§஺ூ%&௃A.¨©ª┞ᵯ᩽ᜫᵯZ¡(Uᓄ,-ᦑA┯¯°B.ῃ©ª┑³ᔠᵯ᩽Ḅᵯ᩽,-X᩽,-Ḅ⌮,-92Li3N-6e=6Li++N2TᦑBµ°C.¨©ª᜜ᵯ¸ᵯZᵫ┞ᵯ᩽7ᔣ┑³ᔠᵯ᩽ᦑC┯¯°D.ῃ©ªLi+ᔣ┞ᵯ᩽»¼ᦑD┯¯°ᫀ9Bூ¾௃ÀµSᵯÁÂ᩽9ᓣᜫU°᩽9Ä^Rᐙᵯ:Â᩽⌮,-X▢᩽,-᩽⌮,-X□᩽,-L§}⚪ᐵÉ⚪JÊËfÌÍÎÏop┞ḄÐÑឋ஺3ஹAூ&᪆௃A.ᔣËᙳX0.10molLrḄKC1ÔKIÕᔠHIÖ!AgNChHI*×Ø⁐ÙÚÛÀÜnᩩÞ8AglᐜàAgClÙÚáὅXnâãäÙÚåH§ËåÜnᩩÞ8åᐜÙÚᡠç&p(AgCl)>Ksp(AgI),ᦑAµ°B.ᓽêët⏚ìᨵíVᐜᐭBa(NO3)2HIîᐭïð⏚ñ⏚᪷óôët⏚᪷UᓄÙt⏚᪷ᦑB┯¯°C.ᔣõᨵNH4A1(SO4)2HIḄköÖ!NaOHHIᐜ¡(AF++3OH-=A1(OH)31÷a(ᡂù&ᦑC┯¯°D.úûfᱥVḄ!ËḄNa2cChÔNaClOḄpHüNa2c()3>NaClO`çÛÀHCOj-Ḅ⏚ឋþàHC1O,ÿ⌕
H2c஺3HC1OḄ⏚ឋ◤⌕ᱥḄNaHCOjNaClOḄpHᦑD┯ᦑᫀA஺4ஹCூ&᪆௃A.⏚ឋḄ⏚▢!ᔠ#$%&'⏚(ᨬḄ⏚ᡠ+CKT!ᔠ#$%ᨬᓽB!ᔠ#$%ᨬᦑA┯B.AஹBஹCஹDஹE-A$ᨬ.ᡠ+ᨬ/ᦑB┯C.C-B+D,᪷123ᵯ5ឤ789:;<=2C1O2-=C1O3-+C1(T,9:>=(64kJ/mol+60kJ/mol)-2x100kJ/mol=-76kJ/mol,ᑣ89:@>ᡠ+9:ᱥḄAB$CDEᡂᱥḄAB$ᦑCGHD.᪷123ᵯ5ឤ7B-A+DḄ9:;<=3ClO-=CKK+2Cr,9:>=(64kJ/mol+2x0kJ/mol)-3x60kJ/mol=-116kJ/mol,ᡠ+8>ᓄJ9:;<=

133ClO(aq)=ClO3(aq)+2Ci(aq)AH=-116kJ/mol,ᦑD┯ᦑ⌱C஺ூNO௃Q⚪Ḅ᧕┯NCD,⌕TUVWXB$ḄᐵZAH=9:ᱥḄAB$-EᡂᱥḄAB$஺5ஹBூ\᪆௃Q⚪ὃ_ᓄJ`aUᙠὃ_c`adQefḄᳮ\஺ூh\௃A.NH4NO3ijk>ᡈmn᧕ᰦpqrsᵨijNH4NO3uvfw⌕xᦑy⌱AB.z{|}~⏣Ḅ`a-:ᳫDz{ᜐᦑ⌱BC.ஹᑖᧅḄᘤᙠᵨᦑy⌱CD.⌕s5.2mL⏚¡¢:⌱£10mL¤¥Ḅ¦ᔣ¦ᑁ©uᐜᵨ«᎔©ᑮ¯°±²³ᦋᵨµᜮ©ᑮ±²ᦑᵨᑮḄᘤ(10mL¦µᜮᦑy⌱Dᫀ·B6,Dூ\᪆௃A.CL¢D¸E9:H2O+C12==HC1+HC1O,(w¹º⌮9:O.lmoICb¢D23Ḅᵯᦪ½CDO.INA,A┯B.᪗¿ÀÁÂ2.24LNO2.24LO2Ãᔠ¸EḄ9:ᨵ·2NO+Ch==2NO2,2NO^=iN2O4,ᡠ+ÃᔠÅḄÆj2ᑖᦪCD0.15NA,B┯C.©>ᩩÈÂFeXÉḄ⏚9:Eᡂ+3ÊḄË23Ḅᵯᦪ3moL᪷17ᜫᵯ5ឤ:Eᡂ‘NA2¹SO2ᑖC┯D.O.lmolNazChXÉḄÍÎḄÏÐᓄÑ9:EᡂÑ⏚ÒÐÆÓÐᓄÒ-ÐᐗÕᓽÖÐᓄ×ÖØÙᡠ+23ḄᵯᦪO.INA,DGHᫀ⌱D஺7,Dூ\᪆௃᪷1⏚Ḅᔾឋ+ÛÆjÜÓ⏚ÝÆÞßÃᔠᑖ᪆஺ூh\௃àÆ-áᨵzÆ⏚ᐹᨵᔾឋ$◀äàÆ-ḄzÆàÆ#ÆÜÓ⏚³åᩭºçèÆjÃᔠéuºÜÓçèÆjᑈåÆëḄìíîÆjḄïì

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'25ஹSO(g)^^S0(aq)SCh+lhO^^H2so3;HSO^^H++HSO-HSO3-^^H++SOj2-22233ᓄᡈ⏚ᙊSO+HO2=H2SO4ᐭᓄ₩0.32⏚Ḅᢵ!22⌼ᡂḄ᡾ூ&᪆௃(1))SO2*ᐭ+,ᡂSO2—⛳/H2sCh012345236ᙠḄ8⊝ᨵ;SO(g)SO2(aq)SO+22H2Oߟ2sO3;HSO^=iH++HSOj-HSO3-^^H++SO2-,ᦑ=ᫀ?SCh(g)(aq)SO+23322sO3;H2so3^^H++HSO3-HSO-^^H++SO2-33(2)᪷ABCDE4ℍ⃔⏀IᐭJK014K⁐MNO4PQRℍ⃔⏀ḄᓄḄḄSᦑ4ᦑ=ᫀ?ᓄᡈ⏚n.(3)᪷ATUV4WᘤARᙊ4ᦑ=ᫀ?ᙊY(4)H2O2ᐹᨵ[ᓄឋ4)ᓄᓄ?⏚4ᓄ]^_`?SO2+H2()2=f12so4,ᦑ=ᫀ?SO2+H2()2=I12so4(5)aᓄbᙠcᓄᑺeᵨgh᧕ᑖ&4◀OH2O2,PlᙠmnoḄ01ᐭᓄ═₩4ᦑ=ᫀ?ᐭᓄ═₩Y(6)᪷Amn^_`4ᨵSO2~H2sO4~2NaOH,n(SO)=-n(NaOH)=-x0.04000moVLx0.025L=0.0005mol,q?222

230.0005molx64g/mol=0.032g,¢'ILI0ᨵᓄ¤Ḅ¥¦.0.032gx§~=0.32g,¨ℍ⃔⏀ISChḄ0¦.0.32g/L,¬[®I
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¼Å¦þÿ᡽ᦣটᓾḄᑮঠ᪷Ḅ⌕ᩭᑖ᪆(2)᪷!"⏚$%ᩭᑖ᪆(3)᪷c=",'ᔠ)Ḅᱥ)Ḅn+Ḅ,-VḄ.ᓄᩭ0123ᑖ᪆஺ூ67௃1000P31000x1.84P/mlx98%(1)জ!"⏚Ḅᱥ)Ḅ!=>c=-------------=-------A~~:-------=18.4mol/L,D◤!&S0,Ḅ,->Vml,M98g/niol᪷FG)"⏚Ḅᱥ)ḄH.C*VMC«V18.4mol/LXVml=500mLX0.5mol/L,7LV=13.6mLSঝ◤⌕!"⏚Ḅ,-13.6mL᪷“ᜧPQ”ḄSᑣUV⌱ᵨ20mlḄYঞ!Ḅᘤ\]!"⏚$%Uᵨ^ᴻ`ᤅbḄcḄdeᔠᙳᒴUd%hi᡽ᦣU■k,lm;টᓾḄᑮ500mlঠḄopqrstuUtuvwx=1y2cmᜐUᦋᵨ|ᜮ~⌲~tuUdḄ☢ᨬᜐx=(2)!"⏚$%UᦑVGḄᓾvᯠG01U┯2টᓾvv(3)জঝYHUᵨuGqr!"⏚UᡠḄ"⏚Ḅᱥ)Ḅ¡Uᡠ¢!=ঝ£⚪(2)Ḅ┯2ᓾvvUᡠLḄ,-¡Uᡠ¢!=¥஺27ஹ§%ᙳᒴஹ¨©ªᑴ=B2NaBr+2H2sCM!)==Na2sO4+Br2+2H2O+SO2T3Br+3CO2==5Br+3COT+BrO3cb60.2%232ூ7᪆௃

24(1)rstPluvḄwᑴyzYফt|}ᡠ122?}hḄ?ᨬYব᪷AᨵK⁐Bn4P⏚NaBr!ᓄmn4A5PlᑏmnḄᓄ]^_`஺(4)জB஺⏚01mn|4B஺!ᓄmn4A5ᑏmnḄ^_`஺ঝ⏣mn4ᮞᔾ+¡¢£¤¥4¦Ẇ¡¨ᔾ+YঞªeH?ᤊYম᪷A᳛=¯°5x100%±²³´஺ᳮ¶ூ·&௃প¹ᵨrstḄº»?¼tᙳᒴஹh᧕wᑴyz4ᦑ=ᫀ?;¼tᙳᒴஹ¿ÀwᑴyzY12g(2)12gÁÂ⏣Ḅ2?"=15mL,ᐳᐭ1215mL+20mL+25mL=60mL,ᡠl⌱ᵨl()()mLÅᔠ〉4ᦑu.og«cm=ᫀ?;B(3)᪷AᨵK⁐Bn4Pmna_⏚)ÈᓄᡂÉᓫq4⏚Ëᡂᓄ4᪷AᵯÍឤ/ᐗÐÍឤPᑏ^_`4ᦑ=ᫀ?;2NaBr+2H2SO4ᾱ)==Na2SO4+Br2+2H2O+SOzT;(4)জBn⏚01mn|4Br2!ᓄmn4᪷AmnᱥᓄᱥḄᱥqḄÔC?5:1Pᱥ?Br-/BrO;ᦑ=ᫀ?;3Br+3CO32==5Br+3COT+BrOi22ঝ⏣mn4ᮞᔾ+¡¢£¤¥4¦Õ¡¨ᔾ+4¡+⏚Ö⍗+ØÙ4ᦑ=ᫀ?;cঞÚ|yz³+ÛᳫnÝᙠÞßàᜐ4âãäåßnÝ⌱æç,äåß4ᦑ=ᫀ?;bA(5)Ýᑴᜓa_Ḅmn^_`?;H2s04)+NaBr-NaHSCh+HBrfY12gCH3cH2cH2OH+HBrCH3cH2cH2Br+H2O,12gÁÂ⏣ḄᱥqḄ?âép=0.2mol,ᑣëᐰmnÁÂ⏣ᡠ◤M(NaBr)=0.2mol,m(NaBr)=0.2molxl03g/mol=2().6g<24gᡠ◤n(H2SO4)=0.2mol<18.4mol/Lx0.025LᡠlÝa_14.8஺ÁÂ⏣a4ᑣᳮ¶ᡂ1-ÈÂï0.2moLq?().2molxl23g/mol=24.6g,ᡠl᳛?ð100%=60.2%,ᦑ=ᫀ?;60.2%oூ»ñ௃ᳫ,äåßç,äåß〉ᵨóMô4ç,äåßõ〉ᔠäåö÷ø〉ᔠÚḄäåᦈú4âᳫ,äåßû〉ᔠäåö÷஺

2528ஹüᓄmnýþÿ
ஹ+H913ூ&᪆௃AᓄᓄᡂB,ᔠAᑖACH3CHO,B
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+45:+2NaOH+HO2OON«OHOH(4)Eg°CH,ᐸ8ᑖ9᪀;<=ᩩ?@জ$1BᓄCDEF⁐
HI
0+ঝ$KL
HI"ᨵ-CHO᪀+ঞ$)*
HI"ᨵ,᝞OHCOO-ஹ-OHஹ-CM,ᨵ10P;᝞OHCOOCH2-ஹ-OH,ᨵQRS3P,ᑣUᔠᩩ?Ḅᨵ13P;ᐸ&+᪶XᐳZ2[5\]+^]☢`a22211Ḅ᪀bHO
5A.c[dᑖefgh88ijḄdᘤ+ᦑAh⌱;B.ᐗjᑖ᪆dpqPrstuvdᘤ+w8xSᨵyḄz;ஹ{ᢵឋ~ឋᱥc&CஹHஹOஹNஹCRBrᐗjḄ"ᑖ᪆g+8ᑖ9᪀;ᡠ"ᐗjPᦪ8+ᦑB⌱C.᜜ᐝ[dᑭᵨᱥcSh8Ḅ᜜Ḅᔾᦈᱯឋ+ᑖ᪀ᓄ\ᡂᑖ᪆Ḅdᘤ+8ᑖ9᪀;,R᪀h8+ᦑCh⌱D.᪶XᐳZdwg᪶Ḅ+᝞H᪶XᐳZ+wgᨵyᱥ&HḄ+ᦑDh⌱

26ᡠ+⌱B(6)0ஹᵬᧇᑴwᵫ0ᵬ⏒B
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ðBᐗjBeñᡂᐭDE+òᵨó⏚⏚ᓄ+ᨬ-ᵨó⏚KDEfsBe+ᦑrstfsBᡠᵨḄõᑺ@NaOH)DEஹó⏚ஹó⏚KDE(6)÷✏ùᓄᔠᱥMFḄ8ᑖ9᪀;+^Uᔠúᑡᩩ?@ঞ$1FeCbDEF⁐
+HI"ᨵ0+ঝImolM1=Naᐙᑖ
$ᡂlmolH2,HIᑖ&ᨵ2-OH,জÏÔᨵ2+ᐸ&1-OH,ýqCH3cH2cH20Hᡈ?H
ᣵ1HᡂḄὅᨵ3ஹὅᨵ2ᙳᨵH3C-CH-CH3ஹஹ3᪀ᦑᔠᩩ#Ḅᐳᨵ%3x(3+2)=15ᐸ
᪶(ᐳ)*+,5-./ᑖ1᪀2Ḅ᪀34,:0HIH3C-C-CH36°I0H