【5套合集】2022届大连市名校高一第二学期化学期末质量跟踪监视模拟试题

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G7NaOH
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ᐸḄabCAN0⏚ᱏNaOH2BsoCu⏚ឋKMnO,2

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⏚CaC0⏚23DNHᮞᮞ3A.AB.BC.CD.D19.(6ᑖ)ᑡ!Ḅ"#$᪀ᡂ'ᵯ)Ḅ20.(6ᑖ)⌮+,Hz(g)+I(g)02Hl(g)-ᑮ/⊝Ḅ᪗2()2A.4ஹLஹHIḄ678B.HzஹLஹHIḄ69ᢝ;

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⏣ᑖᨵᱯḄḄᓄHHII:⏚᝘ᨵ⏚⏚ᙠ!"#$%⁐Ḅ'()ᜧḄ+,஺.9.0g⏚/01ḄNaᙠ᪗345"6ᦈ8ᑮ2.24L:,;<.9.0g⏚/01ḄNaHCOs=+>ᡂḄCO?:,ᙠ᪗345",@2.24L஺AB⏚ᑖᨵᵬDEFG"ᑡI⚪K(1)⏚ḄLMᑖN1K;(2)ᙠPQ⏚RᙠḄᩩT"Uᑖ⏚LV>ᡂW4XYᓄᔠᱥEᑏ]^ḄᓄKᐸY`K.bὃGᫀஹᓫ⌱⚪(i⚪ᒹk20l⚪ml⚪3ᑖᐳ60ᑖ.ml⚪oᨵ⌱⚗qᔠ⚪r)1.Dூu᪆௃ூᑖ᪆௃ᑨyᐗ{|}~ឋᡈ}~ឋḄ6ᐗ{ᙠᓄᜫᵯḄ᧕#ᜫᵯḄᩭᑨy஺ூu௃A.ᱥᳮឋNᐗ{Ḅ|}~ឋA⚗┯;B.=ឋ#ᱥᳮឋN}~Ḅ|}~ឋB⚗┯;C.QḄ|}~ឋḄ6ᐸ/:Ḅ᧕(>ᡂḄ:᝱ᓄᱥḄឋᩭᑨyᓄᔠḄᓄ¡ᑨy᪗3C⚗┯;D.ᐗ{Ḅᵯ¢£|}~ឋ¤£ᓽᓫN¦ᓄឋ£/ᐗ{§¨᧕©ᐸ¦ᓄᡂª᝱D⚗«¬;Gᫀ⌱D஺2.Bூu᪆௃ூᑖ᪆௃

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ᕈឋᦑC┯D.᪷ᵯḄ᩽ᵯ᩽CH4+4CO3"-8e-=5CO2+2HzO,ᨵ1.6gCH«ᓽO.lmolᵬᨵ0.8molᵯ!"▢᩽Ḅᵯ᩽$%2H*+2e-=Hz&▢᩽'()44.8L(᪗-./)ᓽ2moiḄ12'(ᡠ4!"ᵯḄᱥ6Ḅ7$4mol,ᑣCᵯ᩽ᳮ:;(ᡂ2=ᙠ᪗-./?$8.96L,ᦑD┯;ᦑ⌱A஺5.CூD᪆௃ூᑖ᪆௃2SO2+O2=2SO3H⌮ᱥJKLᐰ!ᓄ$(ᡂᱥ(ᡂᱥJKLᐰ!ᓄ$ᱥ᪷ḄᱯPᩭRS஺ூTD௃2so2+O2U±2SO3H⌮ᐭ2.0molSO2VLOmolOz
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ᨵஹᵬZᨵᱥ6ᐹᨵᢵ¢ឋ£¤¥¦ᐸḄZᔾᐭ©ª«¬᠒ឋ®ᓽHDS஺TD%A.⏣H°$ᨵ±ᑺ³ᐹᨵᢵ¢ឋ´⏣µA┯B.£¤¥H°$ᨵ±ᑺ³ᐹᨵᢵ¢ឋᔾᐭ©ª«¬᠒ឋB`¶C.⏚H°$ᨵ±ᑺ³ᐹᨵᢵ¢ឋ´⏚µC┯D.¸Jᨵ±ᑺµD┯஺Sᫀ⌱B஺Pr%s⚪ὃv)ᨵ±ᑺḄឋ6º¶ᱥ6ḄឋD⚪Ḅᐵ⚪»¼½Jᜧx~¿ᐵẠ|}ḄÁÂ஺8.BூD᪆௃ூᑖ᪆௃ூTD௃A.¤ᓄÃ
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(ᡂÔᓄÓVỚÆdÇÈ$%Br+2f=2Br+l,ᦑCJÉᔠ⚪;22D.Õ⏚Öᙠ×ᮞ×;(ᡂ¤ᓄ┛V£mᓄÚV¸ÆdÇÈ$%CaCO3+2H+=Ca2++CO2&+H2O,ᦑDJÉᔠ⚪ᦑ⌱B»9.CூD᪆௃ூTD௃

8A.᝞ÝÆdÇÈ$H++OH-=HzO,
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▢᩽Ḅᵯ᩽È$%2H2O+Mg2++2e--å&+Mg(0H)2஺ᦑC`¶D.Fe?+ḄáâឋᜧBr',ᑣᔣFeB%
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11ᓄᑮ⊝᝱⌮᳛ᔜᱥ#Ḅ%&'(ᵫ*+,Ḅ-.ᱥᳮ01'(,3456ᱥḄᓄ70ᦪ9:;,ᡂᱥḄᓄ70ᦪḄᱯ>஺@ஹ7B⚪(E⚪ᒹGIHI⚪ᐳ10ᑖ)21.0.1mol/(L•min)0.6mol/L33.3%ூM᪆௃ூᑖ᪆௃PQᓄRSTUᔠWXTᑡT7B஺ூZM௃A+2B=3C[\0(mo/L)1.01.20(ᓄ0(mol/L)0.20.40.62min](mol/L)0.80.80.60.2mol/Lপ_ᓫabᑁAḄ%&ḄdIᩭ⊤g2mMᑁ5Ḅᙳ᳛=0^ol/(L.n),ᦑjᫀmil0.1mol/(L>min)(2)2minmCḄ%&l0.6mol/L,ᦑjᫀl0.6mol/L0.4mol/L(3)2minmᱥ#BḄnᓄ᳛l—ߟxl00%=33.3%,ᦑjᫀl33.3%஺Wஹop⚪(E⚪ᒹGIHI⚪ᐳ10ᑖ)22.0+Br,s1C>Br+HBr◀vwᓄxyz6Ḅ{|y},~⁐⏚ឋ⏚@ᵬூM᪆௃ᑖ᪆:ᙠᓄᵨ,,ᡂw:ᓄxO,10-Br+HBrᵫ:ᙳ᧕ᢵ¢£ᡠ¥'¦§¨ᓄ+Brx᧕©ᵯ«¬Hᓱ:BrQ*ᑖ᪆Mj஺0ZM(1)ᙠᓄᑺḄᵨ¯sḄx°±²°±ᡠ,ᡂ³´ᨵ{ᓄx,ᡂḄRSTl+B¶2FeBr3-Br+HBrᦑjᫀl+Brᙶ%Br+HBr2ফ᪷Q½°ᳮ᧕¾¿ᓄÀᵨ¾¿ᓄÀÁ_◀vwᓄxyz6ḄÂ|yᦑjᫀl◀v{ᓄxyz6Ḅ|y¨ব᝞Å,,ᡂ³ᓄx{ᓄx᧕©ᵯ«¬4:Br,{ᓄx;Æ⏚Ç,ᡂ~⁐ᦑjᫀl},~⁐¨(4)Ḅ´ÈᱥÉʲ═⏚ÌᓄÍ*Îᵨ⏚ឋÏ⏚␺Ñ:ᵬᦑjᫀl⏚ឋ═⏚¨

12(5)Eᱥᑖ¾¿eg%஺D[ḄlÀÁᱥÂᨵlÃᑣEH3c(>CH3,ÄÅÆEᵬᦑ!ᫀÇÆEᵬ஺ÈÉÇ@⚪ὃgḄ¦ḄឋʾḄËB@⚪Ḅ᧕┯ÈÍÀᓄḄOᵨÎÏÐᦟᩞÓÔhÕ-⃓ABØ⚪Ù᧕%⚪!Ú஺ÍஹÛ¥⚪(@⚪ᒹÞ1oa⚪ᐳ10ᑖ)23.6ᐗâAl3+cHO+2H++2Fe2+=2Fe3++2HO51:56(102112)222ூ%᪆௃ூᑖ᪆௃ᵫᓄ©äåæ¡Yçᔣèé6êḄ᮱ìᐭî4⏚᮱ìFezO3ஹFe஺ïAI2O3(î4⏚ᡂ4⏚ஹ4⏚ðï4⏚ñ⏚ឋFᓄᱥSiOz.%òóᔣó/ᐭô±Fõ⏚ឋᩩ<=FõFᓄðʾᡂʾöᐭò±Ḅ÷Fᓄø./4⏚ï4⏚ñ(÷Fᓄø./ᡂ÷Fᓄùúïûñ⏚ø./òó:ü¯÷Fᓄý:ᑖ%ᡂFᓄ஺ூ%௃(1)þCuFeSzḄFeᐗâḄᓄᔠÿ+2
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13{⚪ὃ~ᓄoᳮḄᳮ:ᱥsḄᓄᐵd&'Ḅᓄo!?@ḄYZX)⚪Ḅᐵ஺ஹᔠ⚪({⚪ᒹ1⚪ᐳ10ᑖ)24.2cH3cH20H+O^g-*2CHCHO+2HOᔾᦈᢵ&ᩭḄ⏚*⏣;$%⏚ḄD¡2cH3cH20H232+2NaT2cH3cHzONa+h902cH3cH(OH)COOH¢£¤CHL+2"0¥¦!ᡈᓄ!/CH-CH,Oூ᪆௃ூ௃I:ᵫ¨©lh&'Eᡂ!'ᡂ⏣⏣ᓄ'ᡂªªᓄ'ᡂ⏚«©ᓄ'ᡂª©ᓄ'ᡂ⏚⏣ஹ⏚&'ᓄ!'ᡂ⏚஺(1)!ট⏣ᓄᓄ'ᡂªᓄo2cH3cH2OH+O2®f2cH3cH0+2ᓃ0,ᦑ,ᫀ:2cH3cH20H+0>2CHCHO+2HO232(2)ᙠ±Z²ᑴᜓ⏚µ⛳*Ḅ·⏚HD<:ᔾᦈᢵ&ᩭḄ⏚*⏣/$%⏚ḄD¡ᦑ,ᫀ.ᔾᦈᢵ&ᩭḄ⏚*⏣/$%⏚ḄD¡IIII(3)⏣Ḅ¸᪀º»»¼O-H,ᐸ¾ᑖ¿᪀ÀḄ¸᪀H-^—0»¼H:ÁÂlÃÄHHHHHḄ!Å⏣ᑖ@ᨵ¼ᱯÇG@!Ḅᓄo2cH3CHzOH+2Na-»2CH3cH2஺▬+ᦑ,ᫀ.2cH3cHzOH+2Na92cH3cH20Na+Hz/D(1)9.0gÊ⏚lÂpḄÃÄH!ËÌ'ᡂḄÀÀÍ2.24L(ÀÀÍÎᣚÐ᪗ÒÓÔkÀÍ)ᑣÊ⏚ᑖ@3ᨵÕ]Ö)⏣×ØᡈÙØ'ᡂGḄᱥsḄp-TÚ==0.1moLᑣ᪷2-0H(-COOH)
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15

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20OHO|@RC=CH+I_____./ᩩk___).Rc=c—CR2ORl—C-RRiHOK(CH2)COOCH(CH)CHOiH4222ঠPBAḄ%᪀mn0opqᑡr⚪HপᵫADᡂBḄFGvwo(2)ᵫBDᡂCḄᓄxyzno(3)EḄ%᪀mn.(4)ᵫD9FDᡂPBAḄᓄxyzn;ஹ|ᔠ⚪(}⚪ᒹ1⚪ᐳ10ᑖ)24.(10ᑖ)ᙠC᛻r⚪:ᜓᐵ᝞xὅẆḄyᔣ஺Iஹ¡¢£ᙠ<ᓄ¤ᓄᘤᑁḄ¦>ab(1)§ᑴᩩk©FGᙠឤNLMNᘤP«¬᝞FGO2NO(g)+2CO(g)=N2(g)+2COz(g),ᵨ®ᘤVW\+¯°NO9COḄ±_᝞⊤H¯°/S012345c(NO)(10'4mol/L)10.04.502.501.501.001.00c(CO)(10-3mol/L)3.603.052.852.752.702.70³2sᑁḄXᙳFG᳛V(N)=2(2)ᵨ¶<ᓄ·ᓄ¸)¹ῃ»(NOx)জ᪷¾d(¿ᙶ᪗ῃ»ᦔ᳛ஹÃᙶ᪗¶ÄᱥḄRS2)ᑨÆÇÈῃ»ᦔ᳛ḄᨬÊᩩkHঝÌÍHNz(g)+O2(g)=2NO(g)AH=+ak஻molN(g)+3H(g)=2NH3(g)AH=-bk/mol222H(g)+O(g)=2HO(g)AH=-ckJ/molᐸPaஹbஹcᙳᜧÐ0,222ᑣÒÓFGO4NO(g)+4NH3(g)+O2(g)^±4N(g)+6HO(g)AH=஺22nஹᵬ⏣ÔÕḄÖᧇ(1)ᙠ]3O.IMPaᩩkamolC஺(3amolᵯḄZᔠJᙠ<ᓄᑺ>ᵨØCFGDᡂᵬ⏣HCO(g)+2H(g)UCH30H(I)AH<0஺Ùᔠᡂᵬ⏣Ḅ〉Û_9]3Ü+xÝÞßàá2âᑖáâᩩkÌãäᙠ☢ḄáâÝÞ⊤P.

21áâæçT(࠷)n(CO)/n(H)P(MPa)2জ180230.1ঝn235ঞ350m5⊤PᒕêḄáâᦪ¾Hn=,m=.2
CH30HÖᧇᵯëì³íCᨬᡂîḄÖᧇᵯëSïÖᧇᵯëᵫᵬ⏣ஹðñ·òஹK0Hñᵯóôõò᪀ᡂ஺ᑡö¹Ḅñä÷çò஺জᵯëÒᵯ¯øᐭðḄᵯ᩽ú᩽ঝᵯëÒᵯ¯ᵯóôõḄûឋ⌲ýþঞᵯëÒᵯ¯ÿὑ6.4gCH0H1.2molᵯ3ট᩽CHOH+8OH--6e-=CO2+6H0332ὃᫀஹᓫ⌱⚪⚪ᒹ20⚪⚪3ᑖᐳ60ᑖ.⚪"ᨵ⌱⚗%ᔠ⚪'(1.Aூ᪆௃ூ௃জ┯+᝞“02-.᪀0H-O-O-H,1ᨵ0—0,2᩽ឋ45ঝ7892:;ᐗ=>ᔾ@ᵯḄBCD8᪵ḄᡠG2:;ᐗ=>HIJᡂḄ4LD᩽ឋ45ঞ┯NazOz-ḄNO42᩽ឋ4PDQᓄᔠᱥ5ট┯ᐳTᓄᔠᱥ-ᨵUᑖ᪀ᡂ>ᨔWᐸᰚZ+Qᓄᔠᱥ[5ঠ┯]ᨵ^W>_`ᑮᵯb᧕ᜫeᵯ8᧕Jᡂ▢Q5ড┯᝞Hz-1ᨵH—H4hᙠᓄj45ঢ7QᓄᔠᱥL1ᨵQ4lBᨵᐳT4஺noঝঢA⚗pq஺⚪ᫀ⌱A஺2.Cூ᪆௃ᑖ᪆0জsᵬuvᐭxḄyzᓄ{|}-85ঝu~^ᙠᓄᑺᵨᡂ;vᡂ5ঞs^Wᐭᑮ⏚ឋKMnO4|}-5Oᓄ>5টᑴᜓ⏣;;ঠᵬuᑴTNT;஺0জsᵬuvᐭḄyzᓄ{|}-8Bᓄjᦑ8⌱5ঝu~^ᙠᓄᑺᵨᡂ;vᡂ5ঞs^Wᐭᑮ⏚ឋKMnO|}-5Oᓄ5টᙠឋᩩ

22¡ᑴᜓ⏣;5ঠᵬu¢£⏚ᡂ¤£¥ᵬuᓽTNT;஺᪷¨©ªᑖ᪆«টঠ⌱⚗%ᔠ⚪'஺ᦑᫀC஺3.Cூ᪆௃ூᑖ᪆௃᪷¨l®¯ᡂ>ᵯ°ḄᓄjD±²³ḄOᓄ>²³ᑖ᪆஺ூ௃A.C(s)+H0(g)=C0()+H(g)AH>08B±²³ᡠG8B®¯ᡂ>ᵯ°ḄᦑA8%ᔠ⚪'52g2B.Ba(OH)•8H0(S)+2NHC1(S)=BaCl(aq)+2NH+10H0(1)AH>0D2Oᓄ>ᡠG8B®¯ᡂ>224232ᵯ°ḄᦑB8%ᔠ⚪'5C.CH4(g)+20(g)-C0(g)+2H0(1)AHVOlG±²³ḄOᓄ>lG®¯ᡂ>ᵯ°5222ᦑCpq5D.MN(s)+6H0(1)=3Mg(OH)(s)+2NH3(g)AH<0D2Oᓄ>ᡠG8B®¯ᡂ>ᵯ°Ḅᦑg3222D8%ᔠ⚪'5ᡠG⚪ᫀ0C«ூZ´௃µ¨>ᵯ°᪀ᡂ>ᳮ²³ᑨ¸஺᪀ᡂ>ᵯ°Ḅ>ᳮDB±²³ḄOᓄ>஺4.Dூ᪆௃¹⚪ᑖ᪆0AஹºᱥḄᐝᔠᵨD¼½□BᓄᓄjBApq5Bஹ᯿ÀDsᵯBᓄÁᐝBBpq5CஹᱥWᑁḄᓄjÃᓄNᙠBÄᓄ©ÅᔠᳮஹᨵᦔCpq5DஹÇÈDᒓÊḄᐝËÌḄOᓄ>N-ᓄjBᓄÁÌBஹᐝBÍD┯Î஺ᫀ⌱D஺ὃZ0ὃÏBÄḄÐÑᓄ5.Bூ᪆௃Aஹ⍳ÓÔÄÕឤ×ØÙÚÔÄÛDÕឤḄᦑA┯Î5Bஹ᪷¨ᓄjÜ⊝ḄLÞßàᑖḄáâ8ãᦋÃåÀæᑮÜ⊝ᦑBpq5Cஹ¸çImolN¤N4Ḅ9Ù¸ç31noiH-H4ÛDᔣpᔣ²³8%ᔠᓄjÜ⊝ḄLÞᦑC┯Î5Dஹ8«⍝êëᐭìíḄN2¢H2,no8Bᑨ¸DᔲæᑮÜ⊝ᦑD┯Î஺Z´0ᑨ¸DᔲæᑮᓄjÜ⊝⌕᪷¨ᓄjÜ⊝ð᝱ḄLÞGòLÞḄóôᱯöDC⌱⚗Ḅᑖ᪆L÷'ᔣDp⌮஺6.Bூ᪆௃A.NOᓄùDQᓄᔠᱥ▢□Q◤⌕᪗üᡠýᵯ₹NOᓄùpqḄᵯ0Na[O0O0O]O-Na.ᦑA┯Î5B.ᐗ=%ÿ
ᦪ⊤ᦪஹᦪ⊤ᦪᦪ35ஹᦪ45ḄḄᦪ=35+45=80,⊤803Br,ᦑBC.Ḅ5

23!""#$%᪀'(CH=CH,ᦑC┯*D.+,ᵬ./,ᵬ.Ḅ%22᪀'(ᑁ,ᦑD┯*ᦑ⌱B஺7.Aூ᪆௃ூᑖ᪆௃ூ௃ᵯ᩽ᩞᧇFeஹCu,ᵯ89:FeCb9:;Ḅ<=ឋᜧ@ABCD2Fe3++Fe=3Fe2+ᵯ᩽ᩞᧇEFஹCu,ᵯ89:Fez(SC)4)39:BCD2Fe3++Cu=2FeCu"ᵯ᩽ᩞᧇPtஹCu,ᵯ89:FeCb9:A<=ឋᜧ@Pt,BCD2Fe3ஹCu=2Fe2++Cu2+ᵯ᩽ᩞᧇAgஹCu,ᵯ89:Fe4SOR9:A<=ឋᜧ@Ag,BCD2Fe3++Cu=2Fe2++Cu2+,ᦑ⌱A஺8.Aூ᪆௃ᑖ᪆I⚪ὃLNHsḄ%᪀Mឋ஺NᵨPQRSTᑖ᪆஺UNHsVNH4clḄWᡂYZ[\஺]8A.^N᜜`ᨵ5bN-H$cdᐸᨬ᜜gᓽᨵ10bᵯiNḄᨬ᜜gᨬjkᨵ8bᵯᦑA┯*B.ᵫ@m+VITobḄᨬ᜜gpqᔠ[DsᨵtuḄᨬ᜜ᵯg%᪀vwNHᵫNHJ5VH-xᡂNHsyᨵᐳ{$|ᨵ}$ᦑBC.᪷□+VH-Ḅᵯ(ᦑCD᪷N%Ḅᵯ(NH5H.{᝱᧕ᓄvwCDNH+H,O=NH,.HO+Hf,,ᦑD⚗522;I⚪ᫀA஺9.Dூ᪆௃ᑖ᪆AஹᐝᵯᣚḄIᳮ!ᐝᵯᦔDB.tᜧḄᱥ!ᨵ¡¢ᙠᐝ¤ᵨ
ᑖ8ᡂtMtC.tu¥¦§MN¨©ᐸᓄª᝱᧕¦§MN¨DஹᓄEᧇᒹ¬᯼ஹE®Mᜩᯠt±²i!²Ḅ³஺]8A.ᐝᵯᣚḄI´µ¶!·□ᵯ¸¹ḄIᳮ!ᐝᵯᦔDDᵨ[º»¼⌱⚗ABஹtᜧḄᱥ!ᨵ¡¢ᡠt!21¾¿᩽ᨵÀ⌶ḄÂóÄÅÆᑭᵨÈÉÊËËÌᱥMÍᱥᙠ□ᐝ¤ᵨ
Îᑖ8tÏiᑭᵨ⌱⚗BC.tu¥¦§MN¨©ᐸᓄª᝱᧕¦§MN¨ᡠ¦ᔠÐḄDᵨ!8Ñt¦§ஹN¨¥⚪ḄÂ⌶Ò⌱⚗CDஹᓄEᧇᒹ¬᯼ஹE®Mᜩᯠt±²i!²Ḅ³⌱⚗D±஺ᫀ⌱D஺10.Dூ᪆௃ூ௃᪷ᐗÔᙠᕜÖ⊤Ḅ[+×µᐵÙXஹYஹZஹWஹRᑖÚNஹSஹBrஹPஹAr஺

24A.BrzᙠÛÜ
ᕈ:᝱A⚗┯*B.YSᐗÔᐸS”,ᵯg%᪀VAr[Þ஺B)ḄᵯgQArjßgB⚗┯*C.NḄàÐáឋQPḄàÐáâᑣ1\1ḄäឋQPMâC⚗┯*D.ÞᕜÖᐗÔàÐáᐗÔḄàÐáឋÏᑮæçèéâᑣSḄàÐáឋQPḄàÐáឋâD⚗I⚪ᫀ⌱Do11.Cூ8᪆௃A.ᵫìᓣîÜïCH30HḄuðᑖᦪñòó⊝⌮ᔣ÷øᑣCDḄHVO,A┯*BஹCMDùú+DÜï[Þó⊝ÛᦪûVÜïᨵᐵÙvwó⊝ÛᦪK(C)=K(D),B┯*Cஹ300࠷üéᜧýâó⊝ᔣ÷øCH30HḄuðᑖᦪéᜧᡠPi>P2,CDஹBú+DḄÜïMýâᙳᜧ@AúÜïᓣîஹéᜧýâᙳÎCDḄᓄÅCDÿ᳛
VAVVBD┯ᫀ⌱C஺12.Bூ᪆௃ᑖ᪆᪷3Cu+8H++2NO=3Cu2++2NOT+H2஺஺ᨵHNO3"#3Cu+8H++2NO=3Cu2++2NOt+HO,H*$%&'(ᒕ*NO+32ᨵ8moiHN03,,ឋᡂ2molNO,/ὑ8mol12ᐜ
ᐭ5ᐸ789Ḅ;<⏚&'(<⏚>?@#ᡂ4moiN஺᪷3Cu+8H++2NO=3Cu2++2NOT+HzOAB/ὑ16molH+,ᡠDE⏚5<⏚&'(H*ḄᱥGḄHI7ᑣ;E⏚5;<⏚ḄᱥGḄHK21,;E⏚5;<⏚ḄᱥGḄHLMNOK21஺ᫀ⌱B஺13.Dூ᪆௃ூᑖ᪆௃ூ௃AஹQ⏚Ḅ⏚ឋRST⏚⛳VT⏚WᔾᦈQ⏚Z[Q⏚Q\Ḅ&M]N᪆1ᯠ_ᑖ'ᦑabᑮdeQ⏚Q\AfgBஹ#hᮞajᔾᦈkᯠ_ᑭᵨQ⏣opq[rᵨstḄuv>dQ⏣BfgCஹwᓫGVNaOH"##ᡂA&SkḄyz{|V}~ᓄWw|$&SkḄ'8rᵨᑖ'Ḅuv>d{|CfgDஹQ⏚ᵯ1H+ᜧSQ⏣Naᐜ5Q⏚Q⏚/ὑuv$AD┯ᦑ⌱D.14.Aூ᪆௃ூᑖ᪆௃

25ூ௃Q⏚V}~ᓄWᨵḄ஺Q⏣V}~ᓄW$}~ᓄW&'$a␺Q⏚VQ⏣Q⏚ᐗ⏚aV}~ᓄஹh'DT⏚WAD␺ᫀ⌱A஺ூp௃ᱥGḄ⌕¢ᱥGḄᱯ¤ឋGVᱯ¥⌱¦〉¨ḄᑺVuvªg«¬(Ḅ᝞®⁐Ḅ°ᓄஹ±²Ḅ#ᡂV&ஹ³8Ḅ´#V³ᕡஹ¶ᯚḄ®⁐7ᑨ¹ஹºᳮஹ¼ᓽA஺15.Bூ᪆௃ூᑖ᪆௃ூ௃A.ᩈ¿ᡂÀᱥGÁÂḄ°ᓄᨵÃḄᱥG#ᡂᑣᨵÄᓄÅ°ᓄᦑA┯B.∑ÇᡂᮞᨵÃḄᱥG#ᡂSᓄÅ°ᓄTஹ~ᐗÈḄᓄᔠÊ"#°ᓄᑣS~ᓄËÌᦑBfgC.Í᩷ᡂ┐ᱥGÁÂḄ°ᓄᨵÃḄᱥG#ᡂᑣᨵÄᓄÅ°ᓄᦑC┯D.ÐkᡂÑᱥGÁÂḄ°ᓄᨵÃḄᱥG#ᡂᑣᨵÄᓄÅ°ᓄᦑD┯ᦑ⌱B஺16.Bூ᪆௃ூ௃A.kÓḄÔ⌕ᡂᑖKấ⏚Ö┛ஹấ⏚Ø┛ஹÙ⏚Ø┛ấ⏚yᩞᧇÜᨵấᐗÈᦑA$Ýᔠ⚪ßB.àáâḄÔ⌕ᡂᑖKãᓄ┛Väã⏚┛$ÜấᐗÈᦑBÝᔠ⚪ßC.ᐝæçèḄÔ⌕ᡂᑖKÖ~ᓄấÜᨵấᐗÈᦑC$Ýᔠ⚪ßD.éᴻḄÔ⌕ᡂᑖKấ⏚Wஹấ⏚ấVÖ~ᓄấấ⏚yᩞᧇᦑD$Ýᔠ⚪ßᦑ⌱B„17.Bூ᪆௃ூ௃A.ᵫSQḄìí³8Ḅ89Iîï³8ðᘤḄð9$°òMóô$°õᔠ³8òM$°övᑨ¹Qᔲøᑮù⊝Â᝱ᦑA┯B.ᓄÅüýþḼ
Ḅᓄᢝ⌮᳛ᑮ⊝᝱ᦑB!C.ᔜ#$ᡂ&ᑨ(ᔜ$ᑖḄ&*ᔲ,-.ᑮ⊝᝱ᦑC┯0!

26D.2Ḅ34#Ḅ5678*#9:;<ᡠ>9:,-ᑨ(2*ᔲᑮ⊝᝱ᦑD┯0!?ᫀ⌱B஺ூDE௃GHᓄI⊝ḄᱯKL⚪ḄᐵO஺P⚪Ḅ᧕┯DRA,⌕TU⚪U⌕V“⊤ᵬஹ2[ᘤᑁḄ”8ᑮ⊝᝱஺18.CூL᪆௃A.`abᨵỚᑭᵨgᓄhij>kᑮᓫmỚAnᔠ⚪U!B.pqᑖ✂j>kᑮsqBnᔠ⚪U!Ctum*ᵫwx⏚z{|}kᑮqᾦj>ᑴᜓḂtumḂ,Cnᔠ⚪U!D.`ᓄj>kᑮDnᔠ⚪U?ᫀ⌱C஺19.CூL᪆௃ᑖ᪆iᵯḄ᪀ᡂᩩᙢgᓄhi!ᵯLmᡈᰚḄᵯLm᪀ᡂᵯᡈ!ᵫhiᑺ᪀ᡂ᩽ᵫgᓄᑺ᪀ᡂ᩽!¡ᡂ¢ᔠ£3ᵯ᩽¤¥ᡈᵨ¦§¤஺¨L©ᓄIªᓄRᵯḄ«¬®ᙳR°±⏚*iᵯ஺ᑣAஹᵯ᩽ᙳ*³¡ᡂiᵯA┯0!Bஹᵯ᩽ᙳ*´¡ᡂiᵯB┯0!Cஹµ¶ឋ´:¸³¹°±⏚º»᪀ᡂiᵯᐸ´*᩽³*᩽C!Dஹ½ᨵ¡ᡂ¢ᔠ£¡ᡂiᵯD┯0஺?ᫀ⌱CoDEiᵯḄ¾¿ᑨÀÁ-জÃÄᵯ᩽——3᩽R7ÆᙠÈÉឋÊËÌᧇᵯḄᵯ᩽ºÎRÏឋᵯ᩽!ঝÃĺº3᩽Ñᐭ!ঞÃÄ£——¡ᡂ¢ᔠ£ᡈ3᩽Ô¤¤¥!টÃÄPm——iᵯ*Ḅgᓄhi஺20.AூL᪆௃A.ℍ⃔Ø*ᓫØLA!B.qᾦ¶¸ÙÚj>L!C.ÛÜ*ÝØj>LC┯0!D.tumLᨬ<ᡂwx⏚D┯0?ᫀ⌱A஺ßஹàá⚪P⚪ᒹã1¿ä⚪ᐳ10ᑖ21.14.0mol/L21N0:80%,NO20%2ூL᪆௃ூᑖ᪆௃1æçḄèmm
ᑖᦪVᐸᱥmḄ
&zëìḄ5R1L,íᓄàá஺

27(2)ᵨî⚪ïḄm
ᦪðᑡÁò$Vá஺(3)ᐜᵨîkᜫᵯõöឤVøNO?ù஺4ḄᱥmḄ
úVᐸ5ᑖᦪ஺ூ¨L௃—ஹ1.40e/mLx1000mLx63%63p/molপìüý&þ⏚Ḅ5R1L,ᑣᐸᱥmḄ
&R——------------------------------=14.0mol/LÔ1Lt(2)
ḄᱥḄn(Cu),╅ḄᱥḄn(Mg),ᵨ2.54gᔠᑮOH1.02g,ᐸᱥḄ0.06molÔ╅ᙳ+2ᑣ╅ḄᱥḄ0.03moL64n(Cu)+24n(Mg)=1.52জn(Cu)+n(Mg)=0.03ঝὶn(Cu)=0Q2mol,n(Mg)=0.01mol,ᑣ╅ḄᱥḄ!"2O1Ôব᪗%&'(1.12L)*ᐸᑖ,ḄᱥḄ0.05moL
NO2ஹ.஺4ḄᱥḄn(NOz)ஹn(NO),24ᑣᨵn(N0)+n(N0)=0.05®Ô1᦮*34Ḅᜫᵯ,7ឤᨵ9224n(N0)xl+n(N0)x2=0.03x2ঝ;<=ὶn(NOz)=0.04mol,n(N0)=0.01mol,ᡠ?NO2)*Ḅ*@22424ᑖᦪ80%஺ூCD௃F⚪ḄH2IJᵨᑭᵨḄ╅ḄᑡMNOPQ964n(Cu)+24n(Mg)=1.52,ᯠSᑭᵨCuCu(OH)s2MgMg(OH)2ḄᱥḄTᐵVᑡMWNPQ9n(Cu)X98+n(Mg)X58=2.54,<=ὶᡂPQYZ[\஺]ஹ^_⚪(F⚪ᒹb1Oc⚪ᐳ10ᑖ)22.NO2NHCl+Ca(0H)2-CaC12+2NH3t+2H0DEf▲NOᙳᒴiᔠ(ᡈk3lmD4no42pḄ)qrᑴNHsN0Ḅtu;fNHsN0ᢥNw"xyz{)B4NH+6N05N+6H0322Aூ᪆௃ூᑖ᪆௃(1)}~⏚ᐹᨵᓄឋᓄyzᡂ~⏚ஹNO;(2)⌱Cᑴ)yz^_ᑴᜓ)Ḅyzᑭᵨᓄᓄ┛yzᡂ)ஹᓄ┛;(3)᪷1^_Ḅ^_ᳮ⌱ᘤḄ[;(4)᪷1^_ᳮᑖ᪆;(5)3Ḅ)◤⌕◀;(6)E4N஺)yzᡂ¤)஺ூ¥௃(1)A4Ḅyz}~⏚yzᡂᱥ~⏚ஹNOyz4ᐗ§ᓄᔠ¨+5©ªᑮ+2~⏚ᓄᑺ¬ᱥNOÔ(2)⌱Cᑴ)ᓄᓄ┛yzᡂ)ஹᓄ┛yzḄᓄPQ=2NHCI+Ca(OH)CaCI+2NHt+2HOÔ42232

28(3)®yzḄ◀¯°±)4Ḅ¤ᓄᔠᱥAᡂḄNOCᡂḄ)kᐭDf)*iᔠᙳᒴஹ³⁚)tuµF¶·)*¸kᐭEyz¹ºyzyzSḄ)*kᐭB¶·ᨬSᦈ½)*;(4)᪷1?¾ᑖ᪆¿DḄNÀÁᵨfNKN஺ᙳᒴiᔠ(ᡈk3lmD4nopḄ)qrᑴNH3NOḄtu;fNH3NOᢥNw"xyz{)஺(5)ᵫÃ3Ḅ)◤⌕◀)Äឋ)*ÅÆÇÈ⏚}ÉᑣBḄÁᵨᔾᦈ)Ëᫀ⌱B(6)E4NO)ᓄyzᡂ¤)yzḄPQ=4NH3+6N஺᦮AூCD௃F⚪k3ÍÎ)*ḄឋÏᑴᜓὃÑÒᱥឋ^_PᫀḄ
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31

32at¿À-ÁÁᓄ-ÂÃÄᔁtஹᓫ⌱⚪¿J⚪ᒹL20MN⚪
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tBßàáâḄ#ᵬÚÞA.N02S02BaCLB.HC1C0ãᮞå2C.CO2SO2ãᮞåD.C02NH3CaChA.AB.BC.CD.D3.ᑡÍΰḄ#A.xæçèéêᐗìḄ>ᓫ▢Ḅîïឋð
ᐸᐗìèéêឋðB.IAçVIIAçᐗìÓ9ñᡂᐳ¦ᓄᔠᱥᡈᓄᔠᱥC.ᐗìïḄᨬ᜜óᵯᦪ×ôᐗìḄᨬaᓄᔠ¦D.ᐰöᵫèéêᐗìÛᡂḄᓄᔠᱥq÷ᐳ¦ø4.pôNaஹNa?஺ஹNaOH;Na2cO3ùúᱥT
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ᐸ⌴IJKḄA.IALMWALᐗGN)OᡂᐳRᓄᔠᱥᡈTUᓄᔠᱥB.V0ᕜXᐗGYZᑮ\ᨬ5RY+1⌴^ᑮ+7C.`LᐗGḄaᓫ▢TU./ឋYdᑮ>efgh

33D.`ᕜXijᐗGḄᓄᔠRk5ᐸ/UᜫᵯU?nko7.>ᑡᓄpᵨqrstḄ⊤"ḄA.vM$BCḄTUwxy42Na+2H0==2Na+20H-+H122B.ᵨzឋᵯ᩽ᵯ|}⏚~#ḄTUwxy44Agt+2H0_±!L4Ag+01+4IT22C.ᵯ|Ḅ▢᩽BCy4Cu2e-=CußcàD.ᔠBCḄᓄpwxy:CH=CH——8.@&ᔠᡂNftḄ?Iᓄ᝞ᡠBCḄᓄpwxyImolN+3molH能h量AE=akJEE=bkJ增加.mo1N2(g)+AE=ckJ1(1)N2(g)+3H2(g)=2NH3(g)ÔAH2(b—a)kj/molB.N2(g)+3H2(g)=2NH3(1)ÔAH2(a—b—c)kj/molC.N(g)+3H(g)=2NH(1)ÔAH(b+c—a)kj/mol223D.N(g)+3H(g)=2NH(g)ÔAH(a+b)kj/mol2239.⌕Ḅᓄ/ᧇ஺>ᑡᨵᐵḄ┯ḄM$ᔠ)2ᡂBCB.?⏚ឋ5═⏚¢#£⁐M¥ᓄ¦ᔠ2§¨BCD.ᙠ©ᓄᑺ«ᙠ>)*ᑴ¬10.ᐰ¯°±ᱥ
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3412.ᑖUyºCsH^O)MijvBCÁ¦ÃḄᨵÄᓄᔠᱥᨵ("ὃ⇋ÈÉ᪀)A.5ÌB.6ÌC.7ÌD.8Ì13.1830ÍÎᓄpÏᑴ⌼ᖪÑÒÓÔÕÂÖ?×1ÃᙠØ©ᓄ>BC2ᡂ}⏚@$ᐸV:ÙBCº44NH+50=4N0+6H0,ÚBCÛ᳛ᑖÝᵨÞ(□)ஹv(0)>v(H0)>v(N0)⊈0á1/1^ᨌã⊤ᑣ32222Ḅᐵä()A.4v(NH)-v(0)B.5v(O2)=6v(H0)322C.2V(NH3)=3V(H0)D.4V(0)=5V(N0)2214.ᙠå7ឤ6ஹឤçḄèéçᘤëì>ᑡå7)⌮BC4(ᵬ)2X(g)=Y(g)+Z(s)()A(s)+2B(g)=C(g)+D(g),ï>ᑡðG"ñ2Iᓄò)*⊤óᵬ@ᙳõᑮö⊝ø᝱Ḅ()জᔠÃè³ঝBCçᘤ2ᡂᱥḄüᑖýঞBCᱥḄ¶ὑÛ᳛M2ᡂᱥḄ¶ὑÛ᳛ÿ
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36᝞$:(1)╅ᙠᐗëᕜí⊤2ïðñᕜíñò஺(2)dóMgS04ôᐰöᓄdMg(0H)2÷øùᑺজ⌱ᵨ(Rᓄ?)¤sᐭùᑺজḄ______________(⌱R"ü"ᡈ"þ")஺(3)6⌕
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37(4)DḄᨬè&{ᓄᱥḄyᓄᱥḄᓄÉ>஺(5)ᵫA஺(6)ᓫEy./Ḅ-ï1É>oñஹòᔠ⚪(Ò⚪ᒹÔ1_Õ⚪2ᐳ10ᑖ)24.(10ᑖ)j᯼<¤¾'ôâõgᓄöᧇA?@;(3)G%ABᑖ!ᓄᔠᱥDEᵨᩭᑴ⌼JᵨↈLᩞᧇOᐸP᪀R@;(4)ᙠTUᢈW0XYZᕒ\ᾙ^_ᡈa_bcdefgᓽiᐸj_klmnᱥF(pq12.27C)rs;ញᜐᳮ஺ᑏ9ᵫAᑴᜓFḄᓄ=>?@/x(5)#ᑡᐵyBḄAz.ᱥᵬ⏣Ḅ}~Ḅ%()஺a.ᵬ⏣ḄP᪀R@CH3OH,34A0Hb.ᵬ⏣ᐰḄᱥCO20c.Bᵬ⏣᩽᧕y%ᑖ!*ᡂd.ᵬ⏣:;DEfᡠEᵬ⏣⏚ឋ(6)OḄAஹHᐰbὑḄᱥḄ_______(“A>Hஹᵨᡈ”)஺ὃ¢ᫀAஹᓫ⌱⚪(§⚪ᒹ©20ª«⚪¬«⚪3ᑖᐳ60ᑖ.¬«⚪¯ᨵAª⌱⚗±ᔠ⚪²)1.Cூ´᪆௃ூ·´௃A.D⌮:;ᐰ+ᓄᙠA¹ᩩ»#X⌮:;¼᳛Ob¾ᑮ:;▲ÁᡠEÂÃD⌮:;

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஺NaO>NaOHNa2cO3ᱥᑖᓄᱥஹᓄᔠᱥNaᓫA;2⌱⚗A.5.Dூ᪆௃ூᑖ᪆௃ூ௃A⚗ấ$%Ḅ'()ᩞᧇ,ᑴ⌼ᐝ0Ḅ1⌕ᩞᧇ3ᓄấᦑA⚗┯6B⚗SiO?789,3ᓄấ:;HF<=>?=ᡂSiὡ9ᦑB⚗┯6C⚗:;ᵨᯖDEF3ᓄấ=GấSiO,+2CHISi+2coJ,ᦑC⚗┯6

39D⚗SiOz⏚ឋᓄᱥᙠPQᩩSTUᓄ┛>?=ᡂấ⏚┛D⚗;W⚪⌱Doூ᪆௃ூᑖ᪆௃ூ௃AஹYP1Zᒹ\Hᐗ^ᡠ;H`YVIIAZabcᡂᐳeᓄᔠᱥf`YVIIAZabcᡂghᓄᔠᱥBஹY3ᕜjkFᐗ^Ḅᨬ᜜n7Jᵯh,Fᐗ^pe┯6Cஹq1Zᐗ^ḄrfឋstᑮT⌲wxyᑣᐸ▢ghḄEFឋ⌲w}~┯6Dஹqᕜjfᐗ^ḄᓄᔠeHᨬ᜜nᵯhᦪᑣ7᧕ᜫᵯh┯6஺
ᫀ⌱A஺ூ᪆௃ᑖ᪆:A.3ὅ>?=ᡂᓄB.ឋᵯ᩽ᵯgh9kḄ᪷ghᵯC.fḄᵯk▢᩽tghᵯhD.<=>?=ᡂ஺:A.`9>?gh2Na+2H2O=2Na++2OfT+H2t,ᦑAB.ᵨឋᵯ᩽ᵯ¡⏚8¢Ḅgh>?4Ag++2H2O£l^4Ag+O2T+4H+,ᦑBC.fḄᵯk▢᩽tghᵯh=ᡂCu,ᐸᵯ᩽>?Cu2++2d=Cu,ᦑC;D.<=>?=ᡂḄᓄ¤oAnᡠ;D⌱⚗┯6Ḅᡠ;W⚪⌱D஺¥¦W⚪ὃ¨©ghḄªᑏ>?¬⚪ᐵ®¯°gh>?⍳²³´µ¬ஹ⍳²FhJᦪஹᵯ₹·ឤ¹º¯°ᓄ¤Ḅ»ᑖ⚪¼½¾7ᜧ஺ூ᪆௃ᑖ᪆sÀÁÂÃᓄ¤জÅ2(g)+3H2(g)(1);AH=-(b+c-a)kJ/molᡈঝN(g)+7H2(g)È=NH3(g)H=(a-b)kJ/mol,AH`ᓄ¤ÊËᦪᡂÌ;Íᑖ᪆஺

40sÀÁÂÃᓄ¤জ᝞2(g)+Ð2(g)==NH3(1)H=-(b+c-a)kJ/molᡈঝN2(g)+7H2(g)Ñ=NH3(g);H=(a-b)kJ/mol,AH`ᓄ¤ÊËᦪᡂÌজX2:N(g)2+3H(g)=2NH(1)H=2(a-b-c)kJ/mol,ঝx2:N(g)+3H(g)=2NH(g)AH=2(a-b)23223kJ/mol,
ᫀ⌱B஺¥¦W⚪ὃ¨Ãᓄ¤Ḅªᑏ⚪¼½¾7ᜧÒÓᦪÔᑖ᪆ÕᓄUÖḄ×د°ªᑏÃᓄ¤Ḅ¯°µ⚗;>?ÃḄÊÙÚ஺9.Cூ᪆௃A.Û`Ü9ÝᔠÞ:<=ᡂ>?=ᡂ1,2-3àÛá⌱⚗AB.Ûkâᨵääå®Uæ⏚ឋH═⏚è8¢ᓄéᐸê⁐⌱⚗BC.Û`ìᓄÝᔠ<=ᡂ>?=ᡂ1-íÛáᡈ2-îÛá⌱⚗C┯6D.ᙠïᓄᑺñᙠT:;<=>?ᑴÛ⌱⚗D஺
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□᩽ᜫᵯᨵᐸᜫᵯ▢᩽ᨵᵯ᪷ᵯ!ឤ#□᩽Ḅ%&▢᩽᪆(Ḅᡠ*ᵯ+,-.%ᦑA┯12B.3#Fe4Cu56Fe7ᵯ8Ḅ9᩽:;Ḅ<=>?Fe+2Fe3+=3Fe2+,ᦑB@A2C.BCD᜜FᵯGḄ▢᩽HIJKLMN᜜OᵯGḄ9᩽PQᵯGRSᵯT■VWXYᓄ[\□᩽>]ឋᵯ᩽ᦑC@A2D.,_⏚ᐹᨵᔾcឋᙠefḄᩩhiW┑᧕Xῖ⇨ᦑD@A2ᦑ⌱A஺ூqr௃ᵯ8+ᵯG@᩽QO□᩽□᩽ᜫtᵯ:;Yᓄ=>ᵯG9᩽QO▢᩽▢᩽ᑮᵯ:;7=>஺12.D

41ூ᪆௃w⚪ᑖ᪆?ᑖzc5H12஺Ḅᨵ{ᱥ}~NNa=>(⊤ᑖ+ᨵ஺ᨵ@ஹஹCH3cH2CH2CH2cH3ᑖ+ᨵ3H7X-0Hᑮ3⏣2CHCHCH(CH)3232ᑖ+ᨵ4H7X-0Hᑮ4⏣2C(CH)4ᑖ+ᨵ1H7X-0Hᑮ1⏣;3ᡠ*Bᨵ{ᱥḄ}᪀ᨵ8ᦑ⌱D஺ὃq?ὃᑖ᪀ḄPᐵ#஺13.Dூ᪆௃ᑖ᪆?᪷ᓄ=>+᳛4&ᓄ¡¢ᦪ4¤¥¡¦ᑨ¨஺©?Aஹª&=>41\1(+5஺2=41\1஺+6c0,᳛4&ᓄ¡¢ᦪ4ᦑ5V(NH3)=4V(C)2)ᦑA┯1;Bஹª&=>4NH3+5O2=4NO+6H2஺᳛4&ᓄ¡¢ᦪ4ᦑ6V(஺2)=5®0),ᦑB┯12Cஹª&=>4NH3+5O2=4NO+6H2஺᳛4&ᓄ¡¢ᦪ4ᦑ6V(1\1%)=T¯2஺)ᦑC┯12Dஹª&=>41\1(+502=41\1஺+640,᳛4&ᓄ¡¢ᦪ4ᦑ4V(C)2)=5v(NO),ᦑD@A2ᦑ⌱D஺14.Bூ᪆௃w⚪ᑖ᪆?জᵬ³ᙳᵫ¶·N=>¸ᔠḄº-»}¼½⊝¿᝱Ḅ᪗Âᦑ⌱2ঝ=>Äᘤ+;ᡂᱥḄÇᑖ¢ÈᔜÊᑖḄ¢»˽⊝¿᝱ᦑ⌱2ঞ=>ᱥḄÍὑ᳛N;ᡂᱥḄÍὑ᳛4&Ïᦪ4È@⌮=>᳛Pᦑ⌱?ট³¸ᔠḄÒÓÔÕ»ᦑ⌱2ঠ¶¢»Èᐸ®ᱥḄᱥ»}¼½⊝¿᝱Ḅ᪗Âᦑ⌱2ড³¸ᔠḄ<ᱥḄ¢ÔÕ»ᦑ⌱2ᦑ⌱B஺ூὃqØÙ௃ὃᓄ½⊝¿᝱Ḅᑨ¨ூÚÛqᨒ௃Ý⚪ὃᓄ½⊝¿᝱Ḅᑨ¨Þßà=>Ëᑮ½⊝¿᝱@⌮=>᳛Pá0,᪷ᓄ½⊝¿᝱Ḅᱯãäà=>Ëᑮ½⊝¿᝱@⌮=>᳛PᔜᱥḄ,-ஹÇᑖ¢»*åᵫæç;Ḅè¢é:;»ᓄ⚪⌕Þß⌱ëᑨ¨Ḅᱥᳮ¢íḼ=>Ḅ¤¥:;»ᓄàBᱥᳮ¢ᵫ»ᓄᑮØïÈ⌮=>ᑮ˽⊝¿᝱஺15.Cூ᪆௃ூ©௃AஹᐰñòᐳôõḄᓄᔠᱥòᐳôᓄᔠᱥ@A2Bஹ⌕ᨵõḄᓄᔠᱥöòᓄᔠᱥ@A2CஹᐰñòᐳôõḄ÷òᐳôᓄᔠᱥᓄᔠᱥé}ᨵᐳôõ┯12Dஹᓄ=>ḄÝòøõḄ¨ùúõḄûᡂ@A2ᦑäᫀ⌱C஺16.C

42ூ᪆௃ூ©௃AஹᕒúDzòᵫḄÙþ᪀ᡂḄᓫ

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47

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49D.ᓄM5¤ᓄ/ᵯ5¤ᓄ/¦§51COூXᫀ௃Aூ᪆௃Aஹ¬□ᐝ᯿¯°±/ᐝ5¤ᓄ/ᓄM5⌱⚗A=>1Bஹ²³ᩩµF±¶·¸¹ºᓣ¼ᓄM5¤ᓄ/¸5⌱⚗B┯¾1Cஹ±³ᧇᵯÀtᓄM5¤ᓄ/ᵯ5⌱⚗C┯¾1Dஹ¢%⊤ÂÃ5¤ᓄ/¸5¸5¤ᓄ/ᵯ5ᵯ5¤ᓄ/ᓄM5⌱⚗D┯¾஺Xᫀ⌱A஺²ÄÅ⚪ὃÇ5Ḅ¤ᓄᑨÉ5Ḅ¤ᓄᡃËÌ⌕ÍÎ⌕ÏὑÑÒ5ᑮÑÒ5Ó/Ô!ÏὑḄ5¤ᓄ/ᑮḄ5⚪ÕÖ×ᓫ஺4./^ØᓄMÙ᳛EḄÛÜ!A.ÝᱥÞᙠßà%B.ᙠᨴâᒹäᑁÞῃᑺC.³᯼vᵯèᵨ᯼éêë᯼ᙽD.íîᑴð%ñ^ᢓᑴᑺூXᫀ௃Cூ᪆௃A⚗ÝᱥÞᙠßà%óôõᓄᑖ+Ḅöᑖᦪø,Ù᳛ø,A┯¾1B⚗ᙠᨴâᒹäᑁÞῃᑺÏὑóôwø᠒ᨴâúᓄḄÙ᳛B┯¾1C⚗ûᜧüᱥḄ⊤☢þÿ☢ᜧ᳛CD⚗ᑴᢓᑴᑺ᠒ὁᓄ᳛D┯஺!"#⚪ὃ&'(ᓄ)᳛᜜+,-./'(᳛Ḅ᜜+12⚪ᐵ45᝞ᱥḄ8☢ஹḄ:;ஹᱥḄ<;ஹ=ᓄᑺ>?@A'(ᓄ)᳛஺5.BCᱥDEḄFGHᓄI@JKLGMNḄ1A.S-S02fsOsB.A1-A1O-A1(OH)233C.FefFeChfFe(0H)2D.NH^N0-N032ூPᫀ௃Bூ2᪆௃ூᑖ᪆௃ூU2௃A.VWXYZᡂ\XᓄV\XᓄVWXYZᡂ]XᓄV?@LGMNᦑAB._WXYZᡂXᓄ_Xᓄ_I@LGᑮaXᓄ_ᦑB┯C.bWc⏚ZᡂeᓄfbeᓄfbWgZᡂaXᓄfb?@LGZᡂᦑCD.hYWXYZᡂLXᓄiLXᓄiWXYZᡂ\Xᓄi?@LGMNᦑDᦑ⌱B,

506.lN“mnopq.ᦪḄsCᑡuvḄ1A.2.4gMgᙠxYyᐰ{|H}ᵯᦪLm0.2N4B.᪗C2.24LHFᡠᦪLm0.2N*C.5.6gFeᙠ⏚yᐰ2H}ᵯᦪLm0.2N.D.12.0gᰚḄNaHSO,,□ḄᦪLm0.2NAூPᫀ௃Aூ2᪆௃Aஹ2.4g╅ḄᱥDḄmO.lmol,yᐰᜫ0.2molᵯᜫḄᵯᦪmO.2NA⌱⚗AB.᪗CᓄaI1Y⚪ᩩv22.4LᓄaḄᱥDḄ⌱⚗B┯Cஹ5.6gbḄᱥDḄmO.lmol,bW⏚m+3ᦑO.lmolbᜫ0.3molᵯᓽO,3NA¡⌱⚗C┯Dஹ12.0gNaHSO,mO.lmol,O.lmolᰚḄV⏚a¢ᨵḄ□1¢ᦪmO.INA⌱⚗D┯஺Pᫀ⌱A஺7.CᑡᱥD¤¥¦ᵯ2DḄ1A.\Xᓄ§B.©C.aXᓄ┛D.§⏚a¢ூPᫀ௃Bூ2᪆௃A.\Xᓄ§«¬ᙠᑖᨵ®ᵫ}°Ḅ\Xᓄ§¥©@W©Zᡂ§⏚§⏚@ᵯ±®ᵫ}°Ḅ▢□³ᵯ±▢□Ḅ1§⏚I1\Xᓄ§ᡠB\Xᓄ§1´ᵯ2D⌱⚗A┯B.©«ᨵµᑖᵯ¶0?=4+0KᡠB1¦ᵯ2D⌱⚗B"C.aXᓄ┛ᙠ©·@yᐰᵯ±®ᵫ}°Ḅ┛WaX᪷¹1ᓄᔠᱥ¤¥»ᵯ2D⌱⚗C┯D.§⏚a¢ᙠ©·@yᐰᵯ±®ᵫ}°Ḅ¢W§⏚a᪷¹1ᓄᔠᱥ¤¥»ᵯ2D⌱⚗D┯Pᫀ⌱Bo8.᪷¼C⊤µᑖ¾ᕜÀᐗÂÃÄᑨÆBCÇÈḄ1ᐗ÷øLMQRTùúm0.1600.1450.1120.1040.066B⌕ᓄᔠg+2+3+2ûஹ-2-2A.aᓄᱥḄÉmHzTVHzRB.ᓫDËc⏚ḄᒓÍÎ;LVQC.MËTÏᡂḄᓄᔠᱥᐹᨵÑឋD.I3+ËR2-Ḅ᪶᜜ᵯᦪÖ>ூPᫀ௃Cூ2᪆௃¾ᕜÀᐗÂᵫᐗÂḄᓄᔠ×ØT«ᨵ-2ᑣTm0ᐗÂ×ØRmSᐗÂLஹMஹQ«ᨵ,

51ÚÛL>Q,ᑣLmMgᐗÂQmBeᐗÂÚÛMḄã¥LஹQäEᑣMmA1ᐗÂ஺Aஹ4RmHS,H2TmHzO,©ᑖäE¬ᙠa4ᰚÉïð0>ò5,ᓽHzRVHzT,ᦑA┯;Bஹö¤ឋMg÷Be2»ᑣ᝛Ë⏚ùᒓÍᑣÖúᩩCᓫDËc⏚᳛mL>Q,ᦑB┯CஹMËTÏᡂḄᓄᔠᱥ1Xᓄ_1ÑឋXᓄᱥᦑCDஹI?Ḅ᪶᜜ᵯᦪm12-2=10,Q2Ḅ᪶᜜ᵯᦪ16-(-2)=18,ᦑD┯ᦑ⌱C஺9.!"#$ᙠ2L'ᘤ)3+ᱥ-./012XஹYஹZḄᱥ-Ḅ789.Ḅ:ᓄ<=᝞?஺ᐸ)XஹYஹZABC12ᙠ3min9ᑮHI⊝᝞?ᡠL$ᑡNOPQḄR()兽的fiwA.T12ḄᓄUVWXR2X=3Y+ZB.[\1molX_ᐰ12⌕ᔾᦈ46kJḄg7ᑣitmin9T12ᔾᦈḄg736.8kJ•mol'C.ᙠmJmin9.ᑁᵨY⊤L12ḄIᙳr᳛v(Y)0.6mol/(L•min)D.ᙠvw᝱$12yḄz{R12|Ḅ0.75ூᫀ௃Dூ᪆௃ூ௃A.ᙠ0~timin9XஹYஹZὅ:ᓄḄᱥ-Ḅ70.8molஹ1.2molஹ0.4mol,XR12ᱥYஹZRᡂᱥὅḄᱥ-Ḅ72:3:1,timin912HᑮI⊝ᑣm12ḄᓄUVWX2X(g)=3Y(g)+Z(g),ᦑA┯B.HᑮI⊝9XḄ:ᓄ70.8mol,ᑣ12)ᔾᦈḄg746kJx=36.8kJ,ᓫ┯ᦑB┯;Imol1.2mol0.6C.HᑮI⊝W)YḄIᙳ12r᳛——=——mol/(L-min)ᦑC┯(D.ᙠឤ"ឤ'ᩩ$BCḄz{¡ᱥ-Ḅ7ᑣ12yḄz{R12|Ḅ2.4mol=0.75ᦑDPQ;1.6mol+1.2mol+0.4molᫀD஺10.$ᑡ¢£¤¥Ḅ12¦ᳮP¨ḄRA.©gO£ª«FeO3+2AI^.AIO+2Fe223B.°O£±«CuS+Cb,µ2Cu+S஺C.ᵯOᑴ·«2NaCI(ᰚ»)-12Na+Cl2¼D.ᵯOᑴ╅«2Mg஺(ᰚ»)"'w2Mg+5¼

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Ḅ'()ឋ+,ᐸ5᝱0ᓄᱥ÷+34.8A.ᵫÎøÚÛCnH2n+2wấÎḄÚÛSinH2n+2(41),ᦑA%&B.âấÎ(SiH3SiH3)ḄEäåᱥᨵæç0ᑣäåᱥᨵæçDᑖè᪀!ᦑB%&C.ᵬấÎ(SiH4)ḄÓnᑖ?ïðëᵬÎ(CH4)ᜧᑣᵬấÎ(SiH4)ê¥ëᵬÎ(CHQ®ᦑCi%&D.'()ឋSi

56A.⏚ÿ1
⏚ூᫀ௃Bூ!᪆௃ூᑖ᪆௃ᵯḄ᪀ᡂᩩ%&'(Ḅ)*+ᓄ-./,ᨵ234567ឋ9:Ḅᵯ᩽<ᐭᵯ!>?@A᪀ᡂBᔠCDEF3ᩩ%GH:IᐹᜓLM9N஺ூO!௃A⚗ஹA23ᵯ᩽ᩞᧇT:9Uᡂᵯ/V2W67ឋ9:Ḅ45ᦑA┯Z[B⚗ஹA2ᵯ᩽ᩞᧇ9:\]^⏚_(`ᣚ./b᪀ᡂcBᔠCDdᔠᵯḄ᪀ᡂᩩ%,ᦑBef[C⚗ஹAⅅh&iᵯ!>ᐸ?@9kᵯ9UᡂᵯᦑC┯Z[D⚗ஹlmᨵUᡂBᔠCDᦑD┯Z஺ᦑ⌱Boூno௃⚪ὃqᵯḄrsᳮufᵯḄ᪀ᡂᩩ%&!⚪ᐵw஺20.Nᵨyᵯz{|Ḅ}M~ᧇᵯ
NaCI?@ᡈNaOH?@Vᵯ!>?@}ᔠ4V᩽,~ᵯ᩽Ve᩽஺ᑡefḄ&()A.
NaCI?@ᡈNaOH?@Vᵯ!@Ie᩽./VO+2HO+4e===40H22B.
NaOH?@Vᵯ!@I᩽./VAI+3OH--3e===AI(OH)^3C.
NaOH?@Vᵯ!@IᵯᙠrsAᵯ!>?@Ḅឋᢝ9D.ᵯrsIᵯ᜜ᵯDe᩽ᔣ᩽ூᫀ௃Aூ!᪆௃ூO!௃

57A.
NaCI?@ᡈNaOH?@Vᵯ!@Ie᩽+ᵯ`ᡂ+᪷ᵯ᩽./VO+2HO+224e-===4OH",ᦑAef[B.
NaOH?@Vᵯ!@IA1᧕ᜫ«ᵯs᩽ᵯ᩽./VAI+40K—3e=AK)2+2HQ,ᦑB┯Z;C.
NaOH?@Vᵯ!@I²./V4AI+4OH+30=4A10+2H0,+᪷³´./ᡠ
?@Ḅ222ឋ¶·ᦑC┯Z[D.¹ᵯIᵯ᩽ºk»ᔣe᩽ᦑD┯Zᦑ⌱Ao½ஹ¾¿⚪(⚪ᒹÁ13Â⚪ᐳ10ᑖ)21.ᙠMÄÅÆᙠÇÈV2LḄឤËÌBËᘤAÎM./AXஹYஹZÒWÇḄᱥ>ḄÔÕIÖᓄḄ×»᝞ÙᡠÚ(2)0ᑮtᑖÝᑁXḄßᙳ./á᳛Voூᫀ௃Z+3Y0.4/tmol•L_1•min-1ூ!᪆௃⚪ὃqᓄê./á᳛Ḅ¾¿(1):M3ËᘤAᓄê./á᳛ëìíyᓄê¾Ôᦪëìíyᱥ>ḄÔᓄëìᓽXஹYஹZḄðᦪëìV(2.4—1.6)1.20.4=231,òó./ôõV2X^^Z+3Y[(2)᪷÷ᓄê./á᳛Ḅᦪê⊤ùõv(X)=(2.4—1.6)/(2xt)mol/(L-min)=0.4/tmol/(Lmin)஺no⚪᧕┯n&ü⚪(2),ᓄê./á᳛&ᱥ>ḄÔýÆᓄþIÖḄìÿ
ᓫḄᑏ஺ஹ⚪(⚪ᒹ1⚪ᐳ10ᑖ)22.Ẇ!"#ᵬஹ%&'(ᑖ)*+,᝞./01ᵬ1|3ᓴ5678956:8;<=>I?@ᔠᱥCDEF᦮%1HIJজLMNO8ᓉ⎀RSTgg
UV,gg(1)ᵬஹ%&'(ᙠYZ▤\]ᑮ5!_O8Ḅᑭᵨ᳛cdḄe(f"ᵬ"ᡈ"%ije(2)ᵬ'(klটᡠopqrḄstu0vo(3)z{ᵬஹ%&/0ᨬᜧḄ~)ᙠz56Ḅᜐᳮu'ᐸ_ᔠ"p⌕Ḅe

58f"ᵬ"ᡈ"%"ᳮᵫe04᜜ᙠ"_Ḅ"#/0*+.ᡠᨵ¡ᑴ£ᙳ¥¦§¨ᜳᢝ¥ᶍ¬஺.ᑡ®┯°Ḅe஺a►*41bBLḄ⏚ឋ
BCA.A_LᐭḄa8²eCbB.³rᙠA_Lᐭa8²Z\³´µ¶·LᐭᦋLᐭ¹:8C.B_LᐭḄb8²eSO2D.CḄºᵨ»eᔾᦈ¾¿ḄSO28²ூÁᫀ௃ᵬ⏚ᓄÆ■·CbÈÉ0qrS0+Br+2HO===4H++SO2'+2Brᵬ5!_2224ÊḄËÌIÍSÎᡂdᵬ/0_ঞটঠk▭eÓḄÔÕM0ÆdÓḄËÖ×ØÙÚὑÜÌᡂDூÝ᪆௃ூßÝ௃1O8Lᐭᑮ_opqrpᡂà⏚ஹáO⏚âᵨã⏚⏚ᓄᑣåᜧæç_èstËéê⊝⌮ᔣîïðdO8Ḅᑭᵨ᳛ñ2klটᵨòóᓄãÈ6qrpᡂã⏚ôèõ⏚ᩭᔾᦈõS8qrḄstu0v1S0+Br+222H0=4H+S02+2Br-2t3"/0⌕✌ᐜzùᑺÔÕᜧᢇNpüÜÌᡂᑣᵬᔠñ"Sý³◤⌕ᜧNḄØÙüNÌñ4A.A_LᐭḄa8²eCk(ᑭᵨO8ÿ
ḄᓄᓫAB.ᙠAᐭ!ᐭᦋᐭ#$ᔲᑣᐭ#$'()Ḅᑭᵨ᳛-./ᩖBC.BᐭḄb1SO2(ᵨ2ᓄ3ᔾᦈ$Ḅᓫ67.8Ḅ9:CD.CḄ;ᵨᔾᦈ<=ḄS02>?@ḄAD┯CDᫀDFஹHI⚪KL⚪ᒹN1OP⚪ᐳ10ᑖS23.T☢1ᐗWᕜY⊤Ḅ[ᑖ\ᢥ⌕_`$a

59ABCDEFGH1K1AᐗWḄᨬdeᓄᱥḄᵯh஺K2ᐗWGᙠᕜY⊤Ḅj1஺K3CkDlᓫmnoᜧḄ1Kᵨqr⊤sS஺K4CkFḄ᝱uᓄᱥovw1Kᵨᓄxh⊤sS஺K5ᑏzGᓫkIḄᨬdeᓄᱥ{|ᓄᱥḄ
@Ḅᓄx}~h஺K6TᑡᡈH>IᐗWḄឋḄ10aoᐗWḄᓫḄᰚஹd)bᐗWḄᓫᑖk|@@Ḅᒓ~coᐗWḄᨬdeᓄᱥ{Ḅ|ᓄᱥḄឋூDᫀ௃a3aaCaa6aᕜYVIIA஺2-H02CI+2CaOH==CaCI+CaCIO+2HO222222aூ᪆௃ூᑖ᪆௃¢£ᐗWᙠᕜY⊤Ḅjᐵ¥¦§AஹBஹCஹDஹEஹFஹGஹH>Iᑖ1CஹNஹ0ஹNaஹSiஹSஹClஹK>Ca,¨ᔠᐗWᕜYª>ᱥḄ¨᪀kឋᑖ᪆;D஺ூ¬௃K1SAᐗWḄᨬdeᓄᱥC02,ᐳeᓄᔠᱥCk0®ᐳᵨ2{ᵯ{¯ᔜ±ᑮ³8ᵯvw¨᪀ᐸᵯha'6aacaa8aK2ᐗWGCI,µᦪ17,ᙠᕜY⊤j·ᕜYVDAK3ᵯ¸ᦪ¹ᜧlᓫḄmn¹ᜧᵯ¸ᦪº»µᦪ¹Plᓫmn¹ᜧᑣCkDlᓫmnoᜧḄ10ஹK4»¼ᐗWḄ½ឋ¾¿ᑮT¢ÀÁᑣCkFḄ᝱Âᓄᱥovw1H02K5GᓫCkIḄᨬdeᓄᱥ{|ᓄᱥÂᓄ┛ὅÅk@/ᡂᓄ┛ஹÀ⏚┛>|ᐸ@Ḅᓄx}~h2cl2+2CaOHS2==CaCl2+CaCIOS2+2H2஺6a.ᐗWḄᓫḄᰚஹd)ᢣḄ1ᱥᳮឋkᐗWḄ½ឋÊᐵqᔠ⚪Ëa⚗b.ᐗWḄᓫᑖk|@@Ḅᒓ~Ík|@¹ᒓᑣᓫḄឋ¹,b⚗┯Cc.oᐗWḄᨬdeᓄᱥ{Ḅ|ᓄᱥḄឋឋ¹ᑣឋ¹c⚗┯C

60Dᫀ⌱a஺ÐஹÑᔠ⚪KL⚪ᒹN1OP⚪ᐳ10ᑖS24.ÒA1Óᱥ/ÔḄÕ⁚ᑺA67TØᡠsḄÚᓄ¦ᑴÜᨵÞ✏ᕡḄ
EC4H8஺2஺\áDTᑡâ⚪a1AḄᵯh,DᑖᡠãäåḄæç஺2টḄ@éê1஺3AᙠwᩩìT¦íî/ᡂïðᛛᧇᑏzóᛛᧇḄ¨᪀lh஺4\ᑏzᨵôᱥEkNaOH
@Ḅᓄx}~h஺5õz@টᑴᜓᨵôᱥEḄ᝞TØÔøùḄ;ᵨ1ø>┵ûüýþḄ
1_____________ூᫀ௃11HᓄFHLCH?CH3cOOCH2cH3+NaOHfCH3coONa+CH3cH20H⛳Na2c஺3ூ᪆௃ᑖ᪆A!"#$ᱥ&'Ḅ)⁚ᑺ,ᑖ-./C2H4,ᑣA/CH2=CHz,12345&6ᡂ&ᡂB/CH3cH20H,1⏣5&9ᓄ:ᓄ&ᡂC/CH3cH0,1;<"=:ᓄ&ᡂD/C^COOH,1⏚31⏣5&ᓄ&ᡂE/CH3coOCH2cH3?@Aᑖ᪆஺B1᪷?@Aᑖ᪆DE,AḄF᪀H./CH2=CH"ᵯ-./11HᨵKᱥD/CFhCOOH,HHᡠMNOP/QRSTᫀR஺21⏚31⏣5&ᓄ&ᡂE/CH3C00CH2cH3UV!ᓄSTᫀᓄ஺312OW5&6X&ᡂX12,YᛛᧇḄF᪀H."£CH2—CH2\RSTᫀ:£CH-CHi஺224ᨵKᱥE/CIbCOOCH2cH3,ᙠ_ឋa᛻c5&4,ᓄdef./CH3coOCH2cH3+NaOH—CH3coONa+CH3cH20HSTᫀ

61CH3coOCH2cH3+NaOH—CH3coONa+CH3cH20H஺(5)ghiᵨ1⏣1⏚ᑴᜓ1⏚1,'mnḄoᵨ!mpR1⏚1qrᨵ1⏚1⏣,ᵨ⛳s⏚t

62

63()ᓄᔁ"ஹᓫ⌱⚪(~⚪ᒹ20⚪,⚪3ᑖ,ᐳ60ᑖ.⚪ᨵ"⌱⚗ᔠ⚪)1."ᩩc,3molAp1molBprᔠ/2LḄᘤq,5&3A(g)+B(g)C(g)+2D(s)»2minªY«ᑮ⊝,&ᡂDḄᱥ¯Ḅ°±²³Ḅ´ᓄµ¶᝞¸ᡠ¹஺cᑡᑨ¼STḄ!()A.½rᔠpḄ¾¿Àᦋ´²,Y¿"«ᑮ⊝Â᝱B.2minÄ,6ÅÆÇSÈ᳛6Ê,⌮È᳛´᠒C.ÍfqABḄÎᓄ᳛ÏÐ/31D.ÑÒᑮ⊝,ᵨA⊤¹ḄᓄdÈ᳛/0.3moÔL'minTூᫀ௃Dூ᪆௃ூB௃A.×/&ᡂᱥD/,ᡠ@p¯°pØ5&´ᓄ,½rᔠpḄ¾¿Àᦋ´²,Y"«ᑮ⊝Â᝱,ᦑA┯ÛRB.2minÄ6ÅÆÇSஹ⌮È᳛Ø6Ê,⊝SᔣÝÞ,ᦑB┯ÛRC.3molAp1molBprᔠ/2LḄᘤq,×/6ᐭḄᱥÏÐef.qᓄdà°ᦪâã,ᡠ@ÍfqABḄÎᓄ᳛âäᓽ/11,ᦑC┯ÛRD.᪷?ef.DE2minᑁ&ᡂ0.8molD,éὑAḄᱥ¯Ḅ°/1.2mol,ᦑ2minᑁAḄÈ[2mmo]᳛v(A)=c/t=---O---=0.3mol,L-1•min-1,ᦑD⌱⚗!STḄR2?xᡠ@STᫀ/D஺ூóô௃⚪õ?᪷?ᓄdÈ᳛ö÷×ø

64ூIᫀ௃BூL᪆௃ூᑖ᪆௃=AḄᓄPQRNH,SḄᡠᨵḄᨬ᜜ᔠᨵḄᨬ᜜ᵯ᪀RNHH,54TG(ᓄᔠᱥVWBXYNH4H+H2O=NH3H2O+H2Zᨵ[Eᡂ]^LI஺ூ`L௃A.NHsRNH4H,aᓄᔠᱥ&╄᪷(de(fghᙠ()ஹk᪷(&N-Hfghᙠᐳ,)ᡠlaᓄᔠᱥ&2ᨵ()dᐳ,)AmB.ᓄPQNH4H&2ᨵ4ZN-H)ᡠl:LmolNHs&2ᨵ4moiN-H)B┯pmC.NH4H&2ᨵ()R(ᓄᔠᱥ(glqḄ()ᔠᰚ78r9sN;&thᙠᐳ,)Rᐳ,ᓄᔠᱥᑖgluvḄᑖgwᵨyᔠᡠlNHsḄᰚ789:NH3,CmD.NH5VdBzEXNH4H+H2O=NH3H2

65Bஹᓣ9À¿Xº᳛ÕÖᓄP¼⊝T|ᔣḼᔾÙÚᔣÛÜÝÀ¿Xº᳛Þ᠒¼⊝ᔣÙXÚᔣÊËᦑBmCஹÎ:àᨵáÕḄXᡈÏXÁqᦋµ¶ÒÓ¼⊝ḄÊËᦑC┯pmDஹÉᵨÂᓄᑺtVÏпᦋµᓄPXḄº᳛¶ÒÓᓄP¼⊝ḄÊËᦑD┯p஺ᦑIᫀRYB,8Y⚪ὃE¸¹ᓄPXº᳛dᓄP¼⊝ÊËḄãäåZãäḄÎᓄP¼⊝Ḅ¸¹LIḄᐵ)À¿ḄᦋµT|Vɼ⊝zEÊË஺5.æᨵçஹ¾¿ᙳROQlmol/LḄ⏚dè⏚ᑡ&┯pḄA.éᑖW¾¿NaOH¥¦ាëìᐰXᑣ¨ὑNaOH¥¦ḄçY⏚=è⏚B.éᑖW¾¿NaOH¥¦XïpH=7,ᑣ¨ὑNaOH¥¦ḄçY⏚ீè⏚C.éᑖW¡AḄNa2c஺3XDEḄCO2ḄAY⏚=è⏚D.éᑖWÏAḄNa2c஺3ñòXTóôDEḄº᳛Y⏚ுè⏚ூIᫀ௃BூL᪆௃ூᑖ᪆௃ூ`L௃A.⏚dè⏚Tᐗ⏚çஹ¾¿ᙳROQlmol/LḄ⏚dè⏚ᑖW¾¿NaOH¥¦ាëìᐰXᑣ¨ὑNaOH¥¦ḄçY⏚=è⏚ᦑAmB.éÏçḄF¥¦ᑖW¾¿ḄNaOH¥¦ាë&d⏚XEᡂªᓄ¤¥¦pH=7,è⏚XEᡂè⏚¤¥¦pH>7,ᡠlX÷&ឋ·è⏚VìᐰXᦑ⏚¨ὑḄNaOH¥¦çᜧᦑB┯pmC.çஹ¾¿ᙳR0.01mol/LḄ⏚dè⏚ᑖW¡AḄNazCO3XFὅìᐰXᑣEᡂḄ82ḄAÏᦑCYD.0.01mol/LḄ⏚dè⏚¥¦&⏚&Ḅe(¾¿ᜧ:è⏚&e(¾¿ᑣTóôDEḄº᳛Y⏚ுè⏚ᦑDmᦑ⌱Bo6.Tûឋ⚶ᐹþÿᨬᨵḄA.ᘤ⚶ᐹB.⚶ᐹC.ᛛᧇ⚶ᐹD.ᩈ⚶ᐹூᫀ௃Bூ᪆௃A.ᘤ⚶ᐹឋᵨ!"#ᱥấ⏚'()*ᦑA┯-.B.⚶ᐹឋᵨ!"#ᱥ/0123456ᦑB789C.ᛛᧇ⚶ᐹឋᵨ!"#ᱥᛛᧇ()*:ᕜ<Ḅ=᛻⌼ᡂ1ABCḄẚEᦑC┯-.D.ᩈ⚶ᐹ◤⌕HὑᜧKḄᩈᩞẚE=᛻ᦑD┯-.ᦑ⌱B஺

667.ᙠ1LTCU0.2molL1Fe(NO)b1.5mol-L1HSOhᡂḄiᔠklmnᐭ39.2grᐸᐙᑖvw஺3324xᑡᨵᐵ{|78ḄA.vw!34᪗xḄ11.2LB.vw!Ḅklmc(Fe2+)9c(Fe3+)=291C.vw!Ḅkl)k16.8grD.vw!Ḅkl)k19.2gூᫀ௃Dூ᪆௃ூᑖFe+4If+N03=Fe3+N0t+2H0,Fe+2Fe"=3Fe",Fe+2I1=Fe2++Ht.39.2grU0.7mol,k22lm⏚᪷0.6moL3mol,ᓄឋ:⏚Fe"ுH’,4ᡂNOHὑ0.6molr2.4mol;ᒕ¡Ḅ0.Imolr4Fe+2Fe"=3Fe2',4ᡂ0.3moiFe*.ூ¥௃A.ᑖ᪆¦vw!134A┯-.B.ᑖ᪆¦,4ᡂ0.3molFe4ᒕ¡ḄFe”U0.6mol,klmc(Fe")9c(Fe")=O.390.6=192,B┯-;Cvw!Ḅkl,¨ᨵ0.!ḄFe”,0.6molH')k0.6molrᓽ33.6g,C┯-.D.vw!Ḅkl¨ᨵ06moiFe,)k0.3molCu,ᓽ19.2g,D78.ᫀUD.ூ«¬௃᪷ᓄឋḄ®¯9⏚ுFe»H,8±vw²B³´µ¶·஺8.xᑡᔜhᱥ¹Ḅᨔ»mᓄ¼½¾¿ÀAᨔ»¾¿ÁÀAḄ()A.SO2bSiO2B.CO2bH2OC.NaCIbHCID.NaOHbNa2஺ூᫀ௃Bூ᪆௃ூ¥௃A.SOzbSiO2ᙳÅᨵ᩽ឋᐳȽÉᑖÊUᑖᨔ»ஹÌᨔ»A⚗┯-.B.C02bWOᙳŨ᩽ឋᐳȽᙳÏÐᑖᨔ»B⚗78.C.NaCImŨ½Uᨔ».HCImŨ᩽ឋᐳȽUᑖᨔ».C⚗┯-.D.NaOHm¨½b᩽ឋᐳȽNa2஺mŨ½ÑὅᙳUᨔ»D⚗┯-.ᫀ⌱B஺ூ«¬௃Óᩭ{ÕÖ×ÏØÙ×ÏÚÛÜᡂ½Ù×ÏÚÛÜᡂᐳȽ.ᵫ᪀ᡂḄᨔ»Uᨔ»ᵫᑖ᪀ᡂḄᨔ»Uᑖᨔ»ᵫÌ᪀ᡂßàᙠáÛâã᪀Ḅᨔ»UÌᨔ»஺

679.xᑡᱥ¹hᡂḄiᔠᱥwᵨäåæ´µᑖḄA.0Øç⏣B.KNO3ØNaCIC.CaCOØH032D.ç⏚çéØ⛳bNazC03klூᫀ௃Aூ᪆௃ூᑖ᪆௃äUëìḄíîÌᳮᑭᵨl»iᔠᱥmᔜhᑖñ«Ḅòól»iᔠᱥôᑖᓄᯠ!öë÷ôᑖøùúûüýᐸᡠ¨hᑖḄᑖ஺ூ¥௃A.ëìÿ᧕ᢵᢵḄᱥᑖ⏀⏀Ḅ78.2Ḅ100ᜧᵨ⏀ᑖᦑA"ᔠ$B.KNO3NaCIḄ%&'(ᓄ*ᜧᑖ+,-.ᨔ01ᑺ34ᵫ⛳(7⛳89:ᒕḄ<=ᕈᨔ?᪆AᐜᑖANaCI,CᑖAKNO3,ᦑB"ᔠ$C.CaC”A஺ᵨ:EḄ+,FGᦑC"ᔠ$D.H⏚HJᙠ⛳Na2c஺34LḄ%MN=ᑖOᵨᑖ4ḄPQᦑD"ᔠ$Rᫀ⌱A஺ூV௃10.XḄYZ[\]^জ`ᓄabYZ$ঝdYZ$ঞf1YZA.জঝঞB.জঝC.ঝঞD.জঞூRᫀ௃Aூ%᪆௃XḄYZgᡂNaOHH2,ᨵᓄᔠj(ᓄ[\`ᓄabYZ$ᨵNa+OHkgᡂ[\dYZ$YZ:lLm[XᰚᓄᡂNᳫpq-f1YZ஺ᦑ⌱A஺11.ᙠ0.01mol/Lr⏚Lsᙠtᑡv⊝:CKCOOHH++CHCOO\y⌕34ḄpHcCH3coe

ᙳ|3N}Ḅ~-A.〉ᓣ'B.0ᐭ⏚C.0ᐭCH3coONa?D.0ᐭ

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74kj©ªøùজᐵûkiஹkᡭk”ᔣAᐭCL,ᐙᑖ:!,ঝCk,ᐵkz,ᡭLஹkk.”ᔣAᐭ!"#$ᔣCᐭSO”3ᐙᑖ'ঞ!)"ᐵkiஹ*஺-1/aḄ345o-2/89জ;⌕Ḅ=>?@A5஺-3/89ঝᐭ!ḄBᵨ5஺CDEFGHḄ"IᓄᑺLMNᑺḄᱥPḄQR5;T▭VWḄSOzḄᱥPḄᜧYᳮ[\";⌕N]5-ᵨᓄ^?@A⊤`/஺II.ᑴᜓH'FGdḄe@fgh"ijᔣCᐭCl,ᐙᑖhlm஺2-4/oᑡlmqrḄs-t⌱⚗wx/஺-5/AWᐭVmL|Br-Ḅ5cmol•Ḅ"lᡠᓫPḄP5mg,ᑣTᓫPḄ᳛5oூᫀ௃⚠2Br-+Cl=Br+2Cl-EᡂḄBmᔿᐭC1:12SO+O+2HO=2HSO.,222222d£¤500%eVூ¨᪆௃-1/aḄ345⚠஺-2/89জ;⌕sª!Iᓄ=>"Ḅ=>?@A52Br-+Cl=Br+2Cl\-3/H᧕ᢵD"]®89ঝᐭ!ḄBᵨ5EᡂḄBr2ᔿᐭC஺C22DEFGḄ'S0+Bn+2H0=HS0+2HBr,ᐸSO?sMNᑺ"²sIᓄᑺ"ᡠ³IᓄᑺLMNᑺḄ22alᱥPḄQR51:1;ᵫYS0?ᙠ¶·᧕¸!Iᓄ"ᡠ³T▭VWḄSO?ḄᱥPḄᜧYᳮ[\"

75Ḅᓄ^?@A52so2+02+2HQ=2H2s0"4lms¹º»ᳫ½ᙠ¾¿ÀÁᜐ"5■·)ÄᶇᙠÆÇ¿"ᵨÈÉÆÇ¿"ᫀ⌱d5AWᐭVmL|B1Ḅ5cmol-L-1Ḅ"lmᡠᓫPḄP5mg,]®TdᓫPḄ᳛5ÊஹËÌ⚪-Î⚪ᒹÐ1ÑÒ⚪"ᐳ10ᑖ/23.ÔᕜÖᐗØḄᓫPXஹYஹZᙠÙÚÛoᙳ5!᝱"Þᨵ᝞áâᓄᐵã-ᩩåᶍç/஺èéXஹYஹZᙳ5êN>ᓫP"Xs!|ᨬìḄ!)"ᵬîïðñḄò⏒ôõö÷"ø¶Yᓽú⏚஺üýᡂoᑡþ⚪'ÿNgᐳᓄᔠᱥᵬᓫYTᓄᔠᱥᐳᓄᔠᱥᓫZ1XḄᵯO2ᑏᵬḄᓄ஺3!"#$ᵨ᝞'ᡠ)Ḅ*+,-ᦈ/*+0ᜳᢝ34*+ᶍ67ᑴᜓ:ᦈ/ᵬ஺taᨵ!⏚"জᙠ'=᪾ᑁ@ᦈ/ᵬḄAᘤ*+C'஺ঝEF=ḄEᑺHᑏᓄ7஺ঞJK=LMᵫO⁐QRS⁐0ᐸUVᵨᵯW⊤)7ூZᫀ௃:NiiN^NH+HCI=NHCI(ᔠᳮaᑖ)Ca(0H)2NH4aNH«HO^NH++OH-34324ூd᪆௃ூᑖ᪆௃fgXஹYஹZᙳRjUᓫ0Xkl=mnᨬpḄlq0ᑣXRsltᵬ$uvwḄx⏦EzQS,ᑣᵬR|ltL}~ᓽ⏚0ᑣRHCItᓫYRltᓫZRl஺ூd௃17XRsl0ᐸᵯR:NWN^t2ᵬᑖR|lHCI,ᔠᡂᓄ╄0ᓄRNH3+HCI=NH4஺t

76(3)জᵬR|l0kl0᩽᧕L}~0ᑣᵨᔣ᣸klᦈ/0ᑣ*+Rঝ!"#ᵨᓄᮞᔠ¡ᑴ¢|l0EᑺRCa(0H)2NHCIt4ঞ|L}~0ᡂª~ᔠ|0ᐸR«¬0uxLMQS0ᵯW®╆᪷W±᪷W0ᵯWRNH»HO#NH++OH-,,324²ஹ³ᔠ⚪(µ⚪ᒹ·1¹⚪0ᐳ10ᑖ)24.I.᝞'ᡠ)0fgᨵ¼ᱥAḄ¾¿ᑖn28,ÁḄ®n⊝nª¹ÃÄÅᓄÆ~ÇḄ᪗É0BDÌÍÎÏÐ=ÑḄᨵ¼ᱥ0EᐹᨵÔÕ✏ᕡஹØ᧕L}~ḄÅÙMq0FªÛÜÝᱥ0Î=ᵨ}ᑴ⌼Ïᱥßàá஺âH9ãᑺäCuஹå^æä0çèéI□(1)êᑏAḄë᪀CஹCḄë᪀t(2)êᑏB=íîḄᵯஹD=íîḄïðt(3)êᑏᑡḄòó^জ,ঝ,ট஺(4)êᑏᑡᱥõᓄḄᓄ^A-FtB-CtB+D-EH.ᙠ!"#$øᵨ᝞'ᡠ)Ḅ*+ùúBDḄ0êûZᑡü⚪^(1)*+=ýlḄþF⌕ᙠḄ☢ᐭḄḄᵨo(2)⌕ᑴḄ⏚"ᑖ$%ᩭ'(ᵨḄ)*+»III./0123ᵫ/05⏗ᡂḄ⏚ឋ9:ᐹᨵ=>ஹ@ᾦBCᦔ஺/0⏚/01ḄF⌕ᡂᑖᐸH᪀JK᝞MᡠOPQRSᑡU⚪WHOOCCHCHCOOH2OH(1)/0⏚Ḅᑖ\K஺(2)1mol/0⏚_`abcde'fᡂ᪗hijSḄklߟL,(3)ᙠ2qᩩsS/0⏚t_Sᑡuvᱥx5fe'y

77A.k{ᓄdB.⏚C.~⏚kdD.⏣ூRᫀ௃CH=CHH—.Hᡂe'{ᓄe'"ᓄe'ᡈe22IHO'nCH=CH-#ᓄᑺ^CHCH2}222n2CH.CH—OH+o,J!^-2CH,-C-H+2HO⛳Na2cO3■᎔ᔾ"ᙠᐸḄCH,COH+CHJCHJOH-CH,COQH,+HQ=ᨵᑭ"ᑖ$ஹ◀¡¢:Ḅ⏚⏣ᑖCHOs33.6ABCDூ=᪆௃ூᑖ᪆௃᪷§⚪¨ᔜᨵªᱥḄឋx«ᵨ⌶HᔠMOḄ®ᓄᐵ°±²ᨵªᱥḄ3³´ᑖ᪆ᨵªᱥḄH᪀«e'³µ஺ூ¶=௃I.᪷§⚪¨·¸A¹ºᓄ»¼½Ḅ᪗¾ᑣAÀÁA_¼e'ᑮB,ᑣB⏣ÁB5fÃᓄ{ᓄe'ᑣCÄD⏚E⏚"ÁFᵨᑴ⌼ÈᱥÉÊËᑣFÌÀ;HO1ÀḄH᪀JKWCH2=CH2ஹÄḄH᪀KH—HQᦑRᫀCH=CH,H-c-l-uÁ22H2⏣ÏÐḄᵯ\KW.Hஹ⏚ÏÐḄÒÓWÁᦑRᫀWÔஹ○Á3e'জÀ¼Ḅᡂe'e'ঝ{ᓄe'e'ট"ᓄe'ᡈe';ᦑRᫀᡂe'{ᓄe'"ᓄe'ᡈe'ÁᏧÚᑺ4᪷§Ýᑖ᪆ᓄÞßKWA-*FWnCH=CH>{CH2cᔩnÁ22OB_a,PyæW2cHeH?—OH+OJL^-*2CH.-C-H+2HQ29OB+D-*EIèHJSO/Á4CHCOil-►CHJCHJOHfCH3cO6êᓝSÃìᑴOᦑRᫀnCH=CH*-fCHCH4ÁÃᓄîIIÁ22L2qnn2cHeH—OH+6ï-2CHa—C—H+2HQèH,SO4CH,COH4-CHJCHJOH-n.1ðñòóôõᵨᦈ÷⏚"ôõ⛳~⏚d■᎔ᔾᡠøᑮ☢ø

78SᵨW"ᙠᐸḄ=ᨵᑭ"ᑖ$ஹ◀¡¢:Ḅ⏚⏣ÁᦑRᫀ⛳NazCCh■᎔ᔾ"ᙠᐸḄ=ᨵᑭ"ᑖ$ஹ◀¡¢:Ḅ⏚⏣;(2)⏚"_⛳~⏚dᑖû'(ᵨḄ)*+ᑖÁᦑRᫀᑖÁIH.(1)᪷§/0⏚ḄH᪀JKᑖ\KCJLAÁᦑRᫀC¸஺5Á(2)1mol/0⏚þᨵ2moi
Imolᑣn(H)=2mol/2+lmol/2=l.5mol,V(H22=22.4L/molX1.5mol=33.6L,ᦑᫀ33.6!(3)"#⏚%&ᨵ()*+,-ᓄ/0123⏚,/01456)*+7⏣9:;ᓄ45!<="#⏚%&ᨵ)*+7⏚9:;ᓄ45ᦑᫀABCD»ூDE௃Gᑏ7IJ᪀LM=33NOPQḕᶍ!GᑏḄᵯVM=WXYᙠ[\]ᡂ_ᵯV!⚪X⌕bGᑏcQdḄefgPhJ᪀LMijkhl᧕n┯Ḅᙢq஺

79