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页数:97页
时间:2020-10-03
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1、3Micro-porestructureformationandmoisturetransportLuoMian2011.9.30Contents4Contents4Contents43.1Basicmodelingofmicro-porestructuredevelopmentGoal:predictthemicro-porestructurewithtimeOutlineoftheporestructuredevelopmentcomputationinterlayerGelporeCapill
2、aryporeMicro-porestructuresInterlayerporosityGelporositydistributionThetotalgelporosityCapillaryporositydistributionThetotalcapillaryporosityThetotalporositydistributionTheauthorssubdividetheoverallcementitiousmicro-porestructuresintothreebasiccomponent
3、s:R-Rdistributionfunction:Weneedtoknowthe5parametersMacroscopicvolumetricbalanceofhydrationproducts3.3Extendedmodelingoftemperature-dependentmoisturetransportequilibriumThepurposeofthispartistoquantifythetemperaturesensitivityofthestateandtransportofmoi
4、stureinnano-metertomicro-metertoscalepores,bothexperimentallyandtheoretically,andtoenhanceasystemforinternalmoistureinmotionthelawofmassconservationgoverningthebalanceinasystemthepotentialtermformoistureinaporousmaterialθwisthemassofmoistureinaunitvolum
5、eofconcreteJismoisturefluxQisthesinktermcorrespondingtowaterconsumptionduetohydration(a)densityofwater(b)surfacetension(c)viscosityofwaterEquilibriumbetweenliquidandvaporphaseofwaterunderarbitrarytemperatures(2736、conductivitywithrespecttotheporepresuregradientDtismoistureconductivitywithrespecttothetemperaturegradientMoistureforbothevaporandliquidwaterΩDisthecollisionintegeralattemperatureT1orT2(1)(2)CalculationofthedegreeofsaturationinaporoussystemMulti-scalemo7、delingofmoistureexistingincapillary,gelandinterlayerpores.thetotaldegreeofsaturationStotaliscalculatedasfollowφcpisthecapillaryporosityφglisthegelporosityφlristheinterlayerporosityScpisthedegreeofsaturationofcapillaryporesSglisthedegreeofsaturationofgel8、poresSlristhethedegreeofsaturationofinterlayerporesComputedmoistureisothermMoisturelossbehaviorsat20°Cand60°CThesersultsidicatethatthemostimportantissueforfutureconsiderationisanoppropriateexpressionofmoistureequilibriumbasedonam
6、conductivitywithrespecttotheporepresuregradientDtismoistureconductivitywithrespecttothetemperaturegradientMoistureforbothevaporandliquidwaterΩDisthecollisionintegeralattemperatureT1orT2(1)(2)CalculationofthedegreeofsaturationinaporoussystemMulti-scalemo
7、delingofmoistureexistingincapillary,gelandinterlayerpores.thetotaldegreeofsaturationStotaliscalculatedasfollowφcpisthecapillaryporosityφglisthegelporosityφlristheinterlayerporosityScpisthedegreeofsaturationofcapillaryporesSglisthedegreeofsaturationofgel
8、poresSlristhethedegreeofsaturationofinterlayerporesComputedmoistureisothermMoisturelossbehaviorsat20°Cand60°CThesersultsidicatethatthemostimportantissueforfutureconsiderationisanoppropriateexpressionofmoistureequilibriumbasedonam
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