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《烯唑醇铜和银配合物的水热合成与晶体结构.pdf》由会员上传分享,免费在线阅读,更多相关内容在行业资料-天天文库。
1、第28卷第12期无机化学学报V0I_28No.122012年12月CHINESEJ0URNAL0FIN0RGANICCHEMISTRY2593—2596烯唑醇铜和银配合物的水热合成与晶体结构聂旭亮熊辉涂勇刚2黄长干,1(江西农业大学理学院,南昌330045)(。江西农业大学食品科学与工程学院,南昌330045)摘要:合成了2个新的烯唑醇铜和银配合物:[CuL4CI2](1),[AgL2]NO,(2)(L=diniconazole)。通过元素分析、红外光谱和X-ray单晶衍射对其结构进行了表征。结构分析表明,1属三斜晶系,空间群,晶胞参数为O.88
2、23(7)nm,b=1.3705(10)nm,c=1.5164(11)nm,a=91.507(11)。,/3=97.356(9)。,y=107.683(9)。。2属单斜晶系,P2/c空间群,晶胞参数为a=1.2292(3)nm,b=1.2721(3)nm,c=2.4317(5)nm,/3=98.694(3)。。1和2都由分子间氢键连接成一维链结构。关键词:铜配合物;银配合物;烯唑醇;水热合成;晶体结构中图分类号:0614.121;O614.122文献标识码:A文章编号:1001.4861(2012)12.2593—04SynthesisandCr
3、ystalStructuresofComplexesofCopper,SilverAssembledbyDiniconazoleNIEXu—LiangXIONGHuiTUYong-GangHUANGChang—Gan,(CollegeofScience,JiangxiAgriculturalUniversity,Nanchang330045,China)(CollegeofFoodScienceandEngineering,JiangxiAgriculturalUniversity,Nanchang330045,China)Abstract:Tw
4、onewcomplexes[CuL4C12](1)and[AgL2]NO3(2)(L=diniconazole)weresynthesizedbysolvothermalconditionandstructurallycharacterizedbyelementanalysis,IRandsinglecrystalX—raydiffraction.Complex1istheTriclinicsystem,spacegroupP1witha=0.8823(7)nm,b=1.3705(10)nm,c=1.5164(11)nm,a=91.507(11)
5、。,/3=97.356(9)。,T=107.683(9)。.Complex2belongstotheMonoclinicsystem,spacegroupP21/cwitha=1.2292(3)nm,b=1.2721(3)nm,c=2.4317(5)nm,oz=90。,/3=98.694(3)。,y=90。.1and2arelinkedintoaonedimensionalchainbyintermolecularhydrogenbonds.CCDC:805738,1;818240,2.Keywords:coppercomplex;silverc
6、omplex;diniconazole;hydrothermalsynthesis;crystalstructureDinieonazoleisatriazole-typefungicidedevelopedapple[2-4[.byJapansSumitomoChemicalCompany.DiniconazoleCopperandcoppercomplexesareeffective((一-1一(2,4-dichloropheny1)-4,4-dimethyl一2-(1H一1,sterilizationofpesticidestoelimin
7、atepestsand2,4-triazol-1一y1)一pent一1一en一3一o1)isahighlyactivefun-diseasescausedbymoldorfungus.Copperfungicidesgieideandplantgrowthregulatorwithlowtoxicity[”.Itcankillmorethanthreehundredkindsofdiseasesofisaspecificinhibitorofthe14a-demethylationstepofhundredkindsofcrops.Meantim
8、e,copperisoneofergosterolbiosynthesisinfungi.Itshowsexcellenttheesse
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