Unsaturated Polyester Resins Chemistry and Technology.pdf

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1、AdvPolymSci(2005)184:1–95DOI10.1007/b136243©Springer-VerlagBerlinHeidelberg2005Publishedonline:26July2005UnsaturatedPolyesterResins:ChemistryandTechnologyPiotrPenczek1(
)·PiotrCzub2·JanPielichowski21IndustrialChemistryResearchInstitute,ul.Rydygiera8,01-793Warsaw,Polandpiotr.penczek@i

2、chp.pl2CracowUniversityofTechnology,ul.Warszawska24,31-155Cracow,Polandpczub@usk.pk.edu.pl,pielich@usk.pk.edu.pl1Introduction...................................52MajorRawMaterials..............................52.1DicarboxylicAcidsandAcidAnhydrides...................62.2GlycolsandOthe

3、rPolyhydricAlcohols....................142.3CrosslinkingMonomers.............................192.4Dicyclopentadiene................................222.5ManufactureofUPRsUsingPETScrap....................283VinylEsterResins................................304Flexibilization.............

4、.....................354.1IncorporationofSegmentalModifiersintotheUPMolecules........354.1.1TerminalPoly(oxyethylene)SegmentsintheUPs...............354.1.2UPswithIncorporatedPerfluoropolyetherSegments.............354.1.3CopolymerizableRubberFlexibilizers.....................364.2Interp

5、enetratingPolymerNetworks......................385DecreaseinStyreneEmission.........................415.1WithLow-VolatilityMonomers.........................415.2WithWax-LikeAdditives............................426DecreaseinFlammabilityandSmokeEmission...............437ChemicalandAlka

6、liResistance........................468ThermalDegradation..............................499ChemicalAnalysisandStructuralInvestigationofCrosslinkedPolyesters509.1Spectrometry..................................519.2OtherMethods..................................5910CuringofUnsaturatedPoly

7、estersandVinylEther..............6210.1Initiators:Peroxides...............................6210.2Promoters....................................6310.2.1CobaltAccelerators...............................6410.2.2AromaticAmines................................6410.3Photopolymerization:Maleim

8、idesandVinyl