浙江七彩阳光联盟2022年高考化学考前最后一卷预测卷含解析

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2021-2022ὃᓄᔁ
⚗1.ὃᔁ⚪ᓱ.2.⚪Ḅஹὃ!"ᵨ0.5$%&⁐()Ḅ*+,-ᑏᙠᔁ0⚪ᓱḄ1234.3,56᪶89ὃᕒᙠ⚪ᓱ;ᡠ=>Ḅᩩ@ṹ;Ḅஹὃ!"BCDᔲFG.4.I⌱K⚪Lᵨ2BM,⚪ᓱ;8N⌱⚗ḄO᪾QRஹQ&S᝞◤ᦋWᵨXYZ[\]⌱Qᐸ_ᫀ.Ia⌱K⚪Lᵨ05$%&⁐()Ḅ*+,ᙠ⚪ᓱ;Ḅᢣ234Iᙠᐸ_34Icdᦔ.5.᝞◤IfLᵨ2BM,gஹᑏhijᩩஹG"kLl&ஹlm.ஹ⌱K⚪(o⚪pᨵr⌱⚗Gᔠ⚪
)1ஹuvwXxyᨵH+ஹNHஹNa\Mg2\Fe2\SO
ஹCl>Br>A1O?ஹSitV•HCO3ᴻ|xḄ}[~஺100mLvw᝞:⁐4.66g100mL0.6mol-L''100LvwXmNaOH^~w310૙►⁐⁐0.4gᑡḄDA.vwXx2ᨵA1O
ஹSiO2-,ᨵNa+ஹFe2+3B.vwXxlNaOHᡠḄᡂᑖᨵ~C.vwXxc(CD<0.2mol-L-1D.vwXDᵫNH4HSO4ஹMgCLᢥᱥ¤Ḅ¥¦§2:1¨ᔠ]v©)ªᑴ¬ᡂ2ஹᙠ2ᩩ®ᑡ⌱⚗ᡠ¯Ḅᱥ¤°±ᓄᙳ´ḄDNH>NO^->HNO323B.Mg(OH)HC1>MgCh(aq)—d)MgCL2CFeCLD.NaCl(aq)ᵯ¶)NaOH(aq)·¸>NaHCOj3ஹ⊤¯ᑡºNḄ»|ºNO¼½ḄDA.ᔣNaHSChvwx¿lBa(OH)2vwÀvwᕈxឋÃH++SO2+Ba2++OH=BaSO4i+HO42B.CLv©·¥NaOHvwxÃCl+2OH=Cl+CIO+HO22C.Ä⏚◀)ÇCaCO+2H+=Ca2++HO+CO2t32D.ᔣÈHNO3x¿lNa2sO3vwÃSO2+2H+=SO2t+HO324ஹÉÊᵨAgNChvwᑖË¿2ÌÍᙳÎ0.01mol/LḄKC1ஹK2c2O4vwᡠḄv¶Ï⊝fÑ᝞fᡠ¯(Ò

1ὃ⇋C2஺/Ḅ஺ᑡḄ4(♦二3g。Eg721______I!__________i_____I_-7.75-5.75-3.75-2.46igi^Lmol-L-1A.apAg2c2O4
Ḅᦪ10"B.n⊤AgClḄ⛳!"#C.ᔣCC1-
=CC2O4*
Ḅ%ᔠ#'(ᐭAgNCh"#*+ᐜ-ᡂAg2c2஺4/0D.Ag2czCh+ZCkZAgCl+CzCV-Ḅ1⊝3ᦪ4109M5ஹᑡ78Ḅ9:;<=>ᑏḄA.Na2cCh"#'(ᐭ@A⏚CCO2+2H+^COT+HO322B.DEFGH2sCh78C2Fe+6H+—2Fe3++3H2fC.CuOH2FGH2sCh78COH-+H+—H2OD.HIFJKᓄL"#78Cl+2OH->C1O+C1+HO226ஹᨬN“ᚗQᑖS”ᡂ4UV+ᜓXᐵZ஺ᑡᨵᐵ\]┯_ḄA.ᚗQ`┯ᙢ;Ḅbc+dᦈfgh4iB.hjkl᧕n-ᵯᓄῖ⇨+frsᜐᳮC.hj₯ᐝxyzᨵ{kl+lᨵ|ᚗQD.hjẈ~!◌ᚗQ+lấ⏚Aᩞ7ஹᑖ:=4C4H8BnḄᨵᱥᑖ᪀ὃ⇋᪀4A.9B.10C.11D.128ஹᙠ100mLḄ%ᔠ#'+⏚!⏚ḄᱥḄᑖ0.3mol/Lஹ0.15moVL,ᔣ%ᔠ#'ᐭ2.56gE,U+ᐙᑖ78+ᡠ"#'9:ḄᱥḄA.0.15mol/LB.0.225moVLC.0.30mol/LD.0.45mol/L9ஹ₝⏚ᔠᡂᶭ¡¢£ᱥ¤¥Ḅ¦ᧇ+¨⏚©ᙠª«ஹ-¬®ᱥ'஺ᨵᐵ\]Ḅ₝⏚¯⏚A.Ḅ°⏚ᐸ⏚ឋ³

2B.°⏚´µF¶n-ᡂ78C.·⏚ᑖ:F₝⏚ᑖ:³¸¹º°»¼¼½¾D.·⏚µFFe“n-¿⁐78+Á₝⏚µ10ஹ᝞ÃᡠḄXஹYஹZஹWÄÅᕜÇᐗÉḄ¦:ᨬ᜜Ëᵯ:ᦪÌ!422,ᑡ\]ḄXYZWA.XஹYஹWÍᐗÉᨬÎÏJᓄᱥḄÐÑÒᓣB.ZஹXஹWÍᐗÉKᓄᱥÔ8ᓄᱥḄ⏚ឋÑÒÕÖC.ᵫXஹW!JÍᐗÉØᡂḄᓄᔠᱥ'ÙzᐳϾD.XஹZØᡂḄÛᐗᓄᔠᱥÜÝÞßklᩞᧇ11ஹ3à+ᑡᨵᐵ"#'áâḄᱥḄᐵã┯_Ḅ()A.pH45ḄNaHSCh"#':C(HSO3-)>C(H2so3)>C(SO32)B.ᔣNH4cl"#'ᐭNaOHçèpH=7c(Cr)>c(NH4+)>c(Na+)=c(NH3.HO)>c(OH)=c(H+)2C.éêஹᱥḄḄCH3COONH4FNaCl"#%ᔠ+pH=7c(CH3COO)+c(Na+)=c(Cl)+c(NH4+)D.ZOmLO.lmol/LNHJISCh"#F30mL0.1mol/LNaOH"#%ᔠ+ëpH>7c(NH+)>c(NHyHO)>c(OH)>c(H+)4212ஹìᨵíᱥCজNaCl"#(2)CHCOOHঞNH3@BaSOঠⅅð@HO,ᐸ'lᵯḄ()342A.ঝঞটB.ঝটডC.ঞটঠD.জঝট13ஹᓄᙠ-ñ'ᨵḼóôḄ8ᵨ+ᑡ\]ḄA.■÷øµù■úÖû᜜üýþÿ
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ḄCM+ஹHg2+/01234D.ᑭᵨ6Ḃ-ᜐᳮ:;<=>?⌕ᑭᵨ6Ḃ-ḄABឋ14ஹCᑡᓄFᵨG⊤IJKḄA.
4ᦪ8ḄMN4ONB.34ḄQ᪀ISTOH1*C.U᪷34Ḅᵯ4XOD.YZ[ḄQ᪀\X]CHCH,-CH•,15ஹNA^_`abcᦪḄd>CᑡefJKḄA.12ggh[(ᓫkgh)
mᨵoᐗqḄrᦪ2NAB.᪗stC22.4LHF
mᨵḄuN4ᦪvN”C.wxyz
ImolNHs{ImolHCl|}~.ᑖ4ᦪ

3D.ᙠIL0.1mol/LḄᓄ
>▢34ᦪᜧ0.1NA16ஹCH2=CH-CH=CH2%&|}$ᑮḄᱥClC1A.IB.ICH—C=CH—CHQL—CH=CH—CH.33C.--CH—CH=CH—CH^D.CO2ஹ⌱⚪(⚪ᒹ5⚪)17ஹ(clopidogrel)ᵨᢓᑴ⊈Y¡Ḅ¢ᱥ.¤✏¦ᓄᔠᱥANᧇᔠᡂḄª«᝞C:®¯OজR-CHO°ঝR-CN--------------->RCOOHNHS(1)ᑏ²|}C-DḄᓄF³´X______________,|}·¸_____________o(2)ᑏ²Q᪀\X.B,Xo(3)A2¤✏¦ᓄᔠᱥḄ¹ᑖº᪀.(mA)ᐳᨵ>ᑏ²ᐸ
½A¹·¾Ḅ¹ᑖº᪀.ḄQ᪀\X(4)¿ᑖ4CÀᙠÁᩩÃC|}ÄᡂÅᱥ>ÆÅᱥᑖ4
mᨵ3roᐗq>ᑏ²Æ|}ḄᓄF³´Xম®¯OC8ÈXÃÃ,ÉÊᩩᵫÌ[ஹᵬ⏣ᨵÏNᧇᑴᜓᓄᔠᱥ
Ḅᔠᡂª«Ñ´T>ÒÏÓᑺÕ⌱____________஺(ᔠᡂª«cᵨḄ⊤|}ÓᑺA|}ᩩÃB…|}Óᑺ|}ᩩÃv᪗ÅᱥI³X|}Óᑺ|}Óᑺ:v᪗Åᱥ)|}ᩩÃ…|}ᩩÃ.18ஹMcᵨØÙÚᗞ/ÜÝÞßḄยᱥ>ᔠᡂª«᝞T:

4(1)ᓄᔠᱥDxìíḄîλ(2)ᓄᔠᱥCḄ᪀ñ½Î஺(3)জটḄºNôõᑖËÎ,o(4)ºNডḄᓄ÷O¼½Îo(5)ᑡḄD஺A.ᓄᔠᱥBøùúûºNB.ᓄᔠᱥHxrüýᐳÏ☢C.ImolᓄᔠᱥFᨬ5molNaOHD.MḄᑖCi3H”NC>3(6)ᔠᑡᩩḄᓄᔠᱥAḄᑖ᪀ᨵ(ᒹ᪀)!ᐸ#᪶%ᐳ'()ᨵ5*+Ḅ,᪀-oজFeCh/0123⁐ঝ126719ஹ9:;<⏚>(Na2s20,?@A◅C!DEFG⁐CH!᧕/JK!/JL⏣஺ᙠPQRᑴᜓ9:;<⏚>UV᝞:(1)IDᑴᜓSO,YZ[\ᑴ]^_`aḄSO22জᢥcUdᔣ9fᔜhᘤfj!klaf--f,Z[DḄmᵨD

5ঝâãA
|}ḄᓄF³´Xp2r|}IIᡠᵨåâã᝞TᡠIæÝᑖâãḕᶍé஺জ%SO2ëìᐜîïᤅñ>òó#{-ᑴᡂôõ>ᐸvḄ;÷ᑴ|}øùḄ³fঝ|}HḄ34³´Xp3r“ûü”þÿஹᑮ—ᓄᐭ〉⛳Ḅ!Ḅp4rNaSO4«2HO"#$%&᧕()ᓄᐸ)ᓄᱥ,ᑏ2஺22220ஹ/⏚1[La?pCO,ᵨ34ᶭ6789:;ὅḄ=>⏚⊈@ᑴᜓCDEᳮGH2LaCb+6NH4HCO3=La2pCO3r31+6NH4a+3CCM+3H2஺IᓄᐶKLMᑭᵨOᑡQ#RST&UVᑴᜓ/⏚1஺7p1rᑴᜓ/⏚1RSWX&YZ[\ᔣ^Ḅ_`abGHF--T-Tp2rY&cdCDḄᓄCDGp3rX&efḄgᑺ,ᐸjᵨG;p4rZ&DᐜmᐭNH3,nmᐭoḄCO?,EpG;[CepOHrjq⌕Ḅstu)ᓄᱥ,vᵫx/⏚yz{|⌕}CeFC஺~᝞OWX:sᗕஹ”WiaStMl{.Ḅ—►◀c—►ᑖߟ►}Ce3+s|1}Ce3+—►|CeOH
,|—►|c

6(8)¯ICe(OH%0.50g,Ê⏚ºnᵨ0.1000mol?TḄFeSOqËÌÈ6Í῁(ÏEᡂCe3+).(:Ce(OH)4ḄÑÒᑖªÓG208)জFeSOefᙠ_______(“⏚”ᡈ“×”)ËÌZ&;4ঝ᪷ÛO⊤RSᦪÛÝÞCe(OH)4Ḅ½¹FeSOàá(mL)4ËÌßᦪËÌâãᦪËÌnãᦪäß0.5023.60ä¥ß1.0026.30äåß1.2024.10ঞçᵨÊ⏚⏚ᓄnᦋᵨO.lOOOmol?tḄFeCl?ËÌ[êëÌCe(OH)4Ḅ½¹ᐸvìjíîïᑣëÌḄCe(OH)4Ḅ½¹(“ñ=”ஹ“ñò”ᡈ“óôõ”)஺21ஹ¥÷ᙠøùOGúû⁐ý7ᨵþᾯᕡᵨ⁚ஹஹᑺ஺ᵨᑡᔠᡂ:ᑡ⚪(1)!"#$"%&Ḅ()*ᙠ஺,-./0⌕2ᑮ!"#◤ᐜ6!"#"%&7%89:173-174*€(CA)jy---------2CA(
)25t(
)(174(41)জᑖ<2ᑮ!"#Ḅ=>(@=AB)஺ঝᵫ!"#FᡂCsHsKḄᓄHI)>oফLIMᡠ◤ḄFeCh-4HOOPᑡQRᑴ2஺2

7WWNMO,ᵨlft11TUᕜজᵨ⛳Na2cCh/0“”¢£Ḅ¤ḄDoঝ¥ᵨ“¦§¨©”!ᐸª«D»3
ᵨᵯ®¯ᑴᜓ:¢±জ²³ᐭᑘḄ¤ḄD»ঝNiᵯ᩽ᵯ·Ḅp¸“¹᩽”ᡈ“»᩽”r¼9!ᵯ®¨V#□᩽Ḅᵯ᩽!ᳮ¿ÀᵯÁ#ÂÃÄ1molᵯ!ÅᑮÇÈḄÉÊE஺XὃᫀEஹ⌱Ì⚪pÂ⚪ÎᨵEÏ⌱⚗ᔠ⚪Ñr1ஹDூ᪆௃A.ÒᐭEÓÊḄ(Ôᓄ>ÕÅᑮ#ឋ/0!×ت/0⏚ឋ!ᑣÚÛ⏚᪷Ýấ⏚᪷Ýß⏚(᪷Ýàáᙠ!Õâ/0#Òᐭã⏚6Ç2ä⁐åæ!×ØçèÝ஺ª/0áᙠḄ▢ÝÎD<⏚᪷ÝᡈêÝ஺ᡠì4.66íä⁐åæ<⏚îåæ!Ç2cïc!ᡠìª/0EÓçᨵ¢᪷Ý<⏚᪷Ý!ðᨵ;¢Ý!ᑣÒᐭ(Ôᓄ>2ᡂ(Ôᓄ;¢åæ!òóÕÅᑮôõ⁐Ôᓄ¢!ᦑEÓç;¢Ý!ᦑ┯øB.Òᐭ(Ôᓄ>Ç2ḄåæÎD(Ôᓄ╅åæ!ᦑ┯øC.ïcḄú448mL,ᱥÉḄÊ0.02moL×Øû᪷ÝᱥÉḄÊ0.02mol,,ᔠ(Ôᓄ>ḄᱥÉḄÊ0.02moL<⏚îåæ4.66í!<⏚᪷ÝᱥÉḄÊ0.02mol,Ôᓄ╅ÉÊ0.4í!╅ÝᱥÉḄÊO.OlmoL,ᔠḄ(Ôᓄ>ḄᱥÉḄÊ0.02mol,üEýþὑ0.06mol
ᓄᡠᨵᱥḄ0.06-0.02-0.02=0.02mol,᪷ᵯ₹ឤᑖ᪆ᙠᨵ▢!"#ᡠ#ḄᱥḄ0.01x2+0.02+0.02-0.02x2=0.02mol,$%&ᨵᑣ#ḄᱥḄᜧ)0.02moLᑣ#Ḅ*+ᨬ-.=0.2mol/L,ᦑ┯12D.%&ᨵ0.02mol3᪷0.02mol4⏚᪷O.Olmol╅0.02mol#ᱥḄᨬ-.

80.02mol,[ᵫ0.02molNH4HsO4\O.OlmolMgCLᢥᱥ_Ḅ`ab21cᔠdefghᑴiᡂᡈkᨵmᓄnᦑpq஺ᫀ⌱D஺ூtu௃wxyzPIM<{a|Ḅb}ᐵ`\ឋᑖ᪆Ḅឋ᝞ᐭᓄne>Mឋe>⏚ឋᑣ⏚᪷<{ᡈấ⏚᪷<{ᡈ⏚᪷<{*ᙠ஺᪷ᓄnḄὑ`ᑖ᪆eM*ᙠ<{d᪷eMḄᵯ₹¡ឤqeMḄm<{Ḅ*ᙠ$£ᦪW஺2ஹDூ7᪆௃A.N%8ᑺ:NO2Q¥ᓄ,§¨ᓄᓄ2ᑮNOi©ª2ᑮNO2,⌱⚗A┯®B.MgCh(aq)¯°gMgCL,mᓄ╅>²⏚³´µg7¶Fᓄ╅\µ⏚µ⏚᧕ᢵ¹ᨬ2ᑮḄᓄ╅»¼2ᑮᓄ╅iQ2ᑮ°gmᓄ╅⌱⚗B┯®C.Fe-^^FeCh,½ᙠmM¼Fᡂmᓄ½[Fᡂmᓄ¾½°Q¥ᓄFᡂmᓄ¾½⌱⚗C┯®D.NaCl(aq)ᵯ7¿NaOH(aq);8NaHCOj,ᵯ7mᓄne2ᑮᓄnᓄneMOᐭP`Ḅ"ᓄFᡂ⏚nyzᙳQ¥ᓄ⌱⚗Dpq஺ᫀ⌱D஺ூtu௃Á⚪ὃÂÃÄᐗÆᓫ_£ᐸᓄᔠᱥḄÉᔠzᵨ⚪ÊËÌMÍ⚪ÎÏfHFḄᑖ᪆ÐḄὃÂÑxᱥ_Ḅឋ_$£¥ᓄḄᱯtஹyzᩩÔÍ⚪ÕÖ×HFḄᑖ᪆УᮣÙzᵨÐ஺3ஹBூ7᪆௃A.ᔣNaHSCheMÛBa(OH)2eÜeᕈMឋpq<{I)>2H++SO4*+Ba2++2Oir=BaSO41+2H2O,A⚗┯®B.CLefP`NaOHeMFᡂmᓄnஹÞm⏚n\g:CI+2OH=CI+CIO+HO,B⚗pq;22C.à⏚>³⏚<{I)MáC⚗┯®D.âHNO3ᐹᨵ²ᓄឋ6Na2sthᓄ>Na2so4,D⚗┯®ᫀ⌱B஺ூtu௃Á⚪᧕┯tD,<{I)pqᑨåæ⌕ᱥ_Ḅឋ_ᨵ²ᓄᑺæçèkᑺ¹Fᓄkyz஺4ஹD

9ூ=᪆௃A.^(Ag2C2O4)=(10-4)2xl0^=10"-46,?@AᦪC⊤EFGHaxlO»,aHᜧ)1-)10ḄᦪᦑIḄᦪJKP)1042,A┯12B.nLFc(Ag+),M=N⊝PQRḄc(Ag+)ᜧᡠ⊤EAgClḄ;⛳TB┯12C.Uc(C1)=c(C2O42-)=amol/L,Vᔠ%XᐭAgNChFZᡂAg2c2஺4]^ᡠ◤c(Ag+)=Z10-9.75ᡂAgCl]^ᡠ◤c(Ag+)=--------`ᯠZᡂAgCl]^◤⌕Ḅc(Ag+)-ᐜdᡂAgCl]^C┯1;a10-2.46D.Ag2c2O4+2C1=2AgCl+C2O42-ḄN⊝fᦪ,h575ஹj᨟jDmn2(10)ᦑᔠᳮ⌱⚗HD஺5,Dூ=᪆௃Na2cCh%Xᐭrs⏚tCO32+H+=HCO,ᦑA┯12uvwxH2sChytFe+2H+=Fe2++HT,32ᦑB┯12Cu(OH)2wxH2sChytCU(OH)+2H+=CU2++2HO,ᦑC┯12#zw
ᓄyZᡂ#ᓄஹ22{#⏚T|CE+2OH-^CIO+C1+H2O,ᦑDmn஺L}t~ᑏF!ᨵឋᵯ=ᑏᡂᓫஹ
ᓄᱥஹzஹ]^ஹᵯ="ᑏᡂ஺6ஹBூ=᪆௃A.ᚗH┯ᙢḄᦈCᔠᳮᦑAmn2B.Ḅ᧕Zᵯᓄ@ῖ⇨ᜐᳮ¡᧕⌼ᡂ£¤ᦑB┯12C.₯ᐝ§¨%&ᨵ©)ᨵªᚗᦑCmn2D.Ẉ¬T◌®ᚗ)ấ⏚sᩞᦑDmn2ᦑ⌱B஺7ஹAூ=᪆௃ᑖC4H8B஺Ḅ±ᑖ²᪀ᨵ´µᨵ4¶·ḄtCHBr2cH2cH2cH3;ClhBrCHBrCH2cH3;CHzBrCHiCHBrCHj
CHzBrCH2cH2cHzBr
CBhCHBr2cH2cH3;CHjCHBrCHBrCHa
´µᨵ3¶·ḄtCHBr2cH(CH)2;CHBrCBr(CH)2;CHBrCHCHCH2Br
ᐳᨵ9¹º»32323¼ᫀ⌱A஺8ஹBூ=᪆௃%n(H+)=0.15mol/Lx2x0.1L+0.3moi/Lx0.1L=0.06mol,yA¾᝞À:

103Cu+8H++2NO3=3cli2++2NOf+4H2OO3x64g8mol2mol3mol2.56g0.06mol0.03molnSACuP`-P`êëᵨH+ìí஺2.56O.Otn=0.0225mol,c(Cu2+)=0.0225mol/0.1L=0.225mol/L,pqᫀB«tuᵫfCuèHNChyzFᡂCU(NO3)2,CU(NO)2ᵯ

11D.ZdXᡂḄgᐗᓄᔠᱥMᓄấᓄấP⌕Ḅ᪀◌ᩞᧇPᩞᧇD⚗CD'¡⚪Eᫀ⌱D஺11ஹAூ᪆௃A.pH=5ḄNaHSCh⏚ឋ£¤⏚᪷ᵯᜧe/X¦ᜧ§:C(HSO3-)>C(SO32->>C(H2SO3),ᦑA┯&'B.ᔣNH4cl=µᐭNaOH·¸¹pH=7,µᐭḄNaOHºeNH4CI,ᵫᵯ₹¼ឤ¾c(NH+)+c(Na+)=c(Cr),ᱥᧇ4¼ឤ:c(NH4+)+c(NHyHO)=c(Cl-),ᑣc(NHyH2O)=c(Na+),NHylfcOᵯᜧeNH4+/X,c(NH+)>c(NHyHO),ᡠ242q=¾c(Cr)>c(NH4+)>c(Na+)=c(NH3.H2O)>c(OH-)=c(H+),ᦑBCD'C.CH3COONH4=À⏚᪷d╆᪷Ḅ/X¦ÂTᕈ=ឋNaClÄᕈ=ឋc(Na+)=c(CÅ)C(NH4+)=C(CHCOO),c(CHCOOR)+c(Na+)=c(Cl')+c(NH+),ᦑCCD'334D.Æᐭ30mLNaOHÇ(pH>7),ᐸ=20mLᓄÈ-¤⏚É=Ḅ12=d56ᒕËḄ10mLᓄÈ-9᪷56ᑣ56ÌḄ=)ᨵO.OOlmol/ᔠÍஹ0.0005mol¤⏚ÉḄpH>7,ÎÏ/ᔠÍḄᵯ¦ᜧeÉ᪷Ḅ/X¦ÐÑIc(NHZ)>C(NH•H2O),c(OH)>c(H+),ᑣ=3ᜧ§M¾c(NH+)>C(NH•H2O)>c(OH")>c(H+),ᦑDCD'43ᦑ⌱A஺ூJK௃¡⚪ὃÓÔᜧ§ஹ⏚ÕÖᔠḄឋᑨØbÙX⚪ᐵ,¾ÏD56ÌÛÜᡂÝJÞẚ¾àáâãᵯ₹¼ឤஹᱥᧇ¼ឤஹäḄ/XjᳮᙠᑨØᜧ§=Ḅ6ᵨæç஺12ஹBூ᪆௃ᙠ/èᡈᰚëì᝱îïð
ñᵯḄᓄᔠᱥòóᵯXÛ஺জNaClPÖᔠᱥ(PᵯXÛ'ঝCH3COOHe/ñᵯPᵯXÛ'ঞN%e/562ᡂḄñᵯ,ô(Pïðñᵯ(PᵯXÛ'টBaSOõᰚëì᝱îᵯᡂñᵯPᵯXÛ'ঠⅅøe/(
ᵯ(ñᵯ(PᵯXÛ'ডÄ0úḄᵯd᪷ñᵯPᵯXÛ'Eᫀ⌱B஺ூJK௃û⚪⌕ᑭᵨᵯXÛḄᭆþX⚪ᙠ/èᡈᰚëì᝱îïð
ñᵯḄᓄᔠᱥòóᵯXÛ஺13ஹCூ᪆௃

12A.A᜜ÿ
ឋ■᧼ᦑAB.ᵨᧇῃᢈᓄḄ!"#$■%&'⏚)NO,Ḅ*ᓄ+ᓄ"ᡂ-./Ḅ012⏚),ᡠ᯼Ḅῃஹ7891:;᣸@ABCDEFG1HᦑBC.FeIPb2+ஹCu2\Hg2+J"KᣚM"ᡂNOᓫ$Qᳮ./Sᔾ▬ឋ-ᐵᦑC┯XD.YḂ[\]^ឋ_S⏚ឋᱥMabcdefgḄhijkᦑDᦑlᫀCC»14ஹCூo᪆௃A⚗NḄsᦪC7,Hᦪ=8+7=15,⊤vCA┯XB⚗wsxᨵ16zsᦪwsḄ<\\H1*@
288HtNiH{᪀v}Cߟ//,ᦑB┯XC⚗╆᪷wsḄᵯsCLCD⚗J"M"-fcEL—ᡂḄ{᪀C8H3,D┯X஺⚪ὃᓄᵨḄXᑨ⚪⌕ὃ"¡ᓄᵨḄ¢£¤¥Ḅᓄᵨ⌕ᒹ§ᐗ©ª«ஹᓄஹᓄᔠஹᵯsஹ®s{᪀v}ஹ{᪀ஹ{᪀¯°±Iᔜ³´µ¶,◤⌕¸¹஺15ஹDூo᪆௃A.l2gº»¼ᨵImol½®sᙠº»¿ÀzÁᐗ¼ᨵ6z½®sÃÀz½®sÄ3zÂᡠᐳᨵᡠÀzÂÆᙳᑖÉ2z½®sᡠ1z½®s¡0.5zÂᡠ12gº»\ᓫʺ»_¿xᨵÁᐗÂḄzᦪC0.5NA,ᦑAË⌱B.᪗>k¥ÍHFBÎÏᦑBË⌱C.N%IHC1M"ᡂḄNH4clËBᵫᑖs᪀ᡂḄBwsᓄᔠᱥᦑCË⌱D.1L0.1mol/LḄᓄÑÒο᝞ÔwsË[oᑣwsCO.lmoLÃwsÖJ"[o:S2-+H2OK^HS-+OH-,ᡠ▢wsᦪÙᨬÛ▢wsÜᦪᜧÞO.INA,ᦑD⌱஺ᦑ⌱D஺16ஹAூo᪆௃A.CH2=CH-CH=CH2J"1,4ᡂ"ᡂᡠËÉᑮàᱥAªᔠ⚪;B.CH2=CH-CH=CH2SHCIJ"1,4ᡂ"ᡂB˪ᔠ⚪C.CH2=CH-CH=CH2J"M"ᡂC˪ᔠ⚪D.CH2=CH-CH=CH2â"ᡂCO2,D˪ᔠ⚪

13ᦑᔠᳮ⌱⚗BA஺ஹã⌱ä⚪\⚪ᒹ§5å⚪_NH,NHNH1217ஹj^^COOH+CHOH^^.j0^COOCH.+HO32êᓄM(ᡈíîM)QU'4Q-LciQ\OOH^2L+2&஺CIH4—ߟߟ►CHiBrCH'BrB9>CH2OHCH2OH-CHsOH-Qu5.>HCHO-ூo᪆௃AᑖsCCiHsOCl,{ᔠ⚪æçèéA¿xᨵ-CHOஹ-ClஹðÂ᪷ñᱥMò±¿ᱥ{᪀ËéACNH,NH>BCN2Oa°^Q^ý⏚ᓄþM!"CCQ^COOH,cSᵬ⏣ᙠ⏚ᙠᩩNHiO?@ANH.(2)᪷./0ᑖ᪆B[[Y]CN,X(2

14(3)AÅ᪀Æ,AḄ±ᑖ²᪀(&A)%)È✏Êᓄᔠᱥᑣ&ᨵËÌÍ"ÎFᨵÏஹÐஹÑÒ¹$Í"ÎZᓄ,Óµ-COCLÔᔠᩩÖᡠᨵḄÅ᪀Æ×Ø0ᐳÙ¹±Ḅ±ᑖ²᪀ᐸ%wA±ÛÜḄݹ±ᑖ²᪀ḄÅ᪀Æ(4)ÞᑖCᙠÝßᩩÖÀyZᡂݹàᱥGàᱥᑖ%&ᨵ3¶áᐗÌHãäwåäæÐZῃ|y,ÞᑖCῃè2ᑖ|Zᡂ,Gy:4-211,0.OOHমêëwìZíᡂyàZClhBr.CHzBr,îZ|=yàZêï⏣tCHzOH-CHiOH,ᵬ⏣òᓄ
ᓄàZᵬóHCHO,ᨬôêï⏣wᵬóyZᡂᓄᔠᱥ¶ᦑGyõNaOHHzOJH4——ߟ►CHBrCH2Br>CH2OHCH2OH-ICHaOH♦-HCHOÝூL}௃ö⚪ὃùᨵúᱥḄᔠᡂwûüஹᨵúyÛýḄᑨüஹ±ᑖ²᪀~ᑏKÿ
ᳮ⌕ᐙᑖᑭᵨ⚪ஹᱥḄᑖ஺᪷
ᱥ᪀ᑖ᪆!"#$Ḅὃ&'(ᑖ᪆!ᳮ)*+,ᨵ.ᓄ'0ẠḄ2ᔠὃ&஺018ஹ40ஹ50ஹ60C1CH.;ᡂ
=>
78ᩩ:->'+HBrBD13H>CCH,CHOூ@᪆௃

150HCHOᡂᡂB,BHC1?@ᡂCCI?@ᡂM஺ூ௃ᐸFGHḄIJ4KஹLKஹMKᦑOᫀ4KஹLKஹQK;HCHOᡂᡂBHC1?@ᡂC

16rO(4)ডḄᓄT:;:+HBr(5)A.ᓄᔠᱥB,UGVWA┯Y;,Z[\]Gᐳ_☢Bab;C.ᓄᔠᱥFc+ᡂḄ᷊KஹeLKfHBrGfNaOHᑣImolᓄᔠᱥFᨬiG4moiNaOHC┯Y;D.MḄ᪀,ᐸᑖCl3H19NO3,DabAᦑOᫀBD
(6)ᓄᔠᱥA,জGFeCbmno⁐ᵫeLKঝGstᵫuKvwxOHᔠᩩvᑖy᪀zᨵ:|}~ᨵ106-CHLCH஺|}~ᨵ3ᐳᨵ13ᐸ᪶ᐳᨵOHᦑOᫀ13
/5jkḄ᪀:CHJCHOCHJCHOூ௃\]/ᵫZ[?@KḄvᑖy᪀zᨵ3ஹᨵZ[v?@Kf[Uv?@KḄvᑖy᪀zᨵ6ஹᨵ[Uv?@KḄvᑖy᪀zᨵ10஺19ஹdfefcfb■᎔ᔾCU+2HSO4(^)=SOt+CuSO+2HOSO2ZnḄ᳛c224235c2SO+Zn+2OHZn(OH)+S2O42ZnONa2s2O4Ḅm+Na2s஺3ஹNaHSChஹNa2sO4ᡈ22

17NaHSOMᑏ2)ூ+᪆௃(Dজf⏚ᙠᩩᑴ?ᓄᡂḄᓄᨵc¡¢◤⌕¥¦AᓄḄ§¨©¢ᜧ«c¬ᵨᔣ/᣸©¢°ᦈ²ᦈ²w¢z³´µ¶ᓄᨵ·UG᣸¸ᑮ©¢◤⌕º¢ᜐᳮᔾᦈº¢w◤⌕½¾■᎔ᔾ¾¿ᑣᢥ¢Á:ᔣÂÃᔜÅᘤÃÇÈÉa-dfe-c-b-f
ᓄÊᓄËᔾᦈ¬¾¿ᑁÍ᧕᎔ᔾᑣD■᎔ᔾ¾¿Aঝf⏚ᙠᩩᡂᓄஹ⏚fcᓄT:;Cu+2112so)ÏSO2t+C11SO4+2H2O;(2)জSO2ZnÐÑÃÃÒÃÒ☢ÓÔÕSO2Ö×ᐜÙÚᤅÜÝÞÐfcᑴᡂßànáᜧSO2ZnÐwḄÃÒ☢ÓâãS02ZnḄ᳛AᵫÁ;äåDḄæ35࠷,çᯚæÔéU᧕êᑴUGᵨ⏀ìíÑìᵨcḄ:°ᩭêᑴæA35࠷ঝᓄÞÐfᓄËᡂᓄÞfNa2s2஺4,ï:;2SO+Zn+2OHZn(OH)+SO2'
2224(3)ᵫ(2)ঝðñòðᑮḄ“òô”ᓄÞö÷ஹøùᓄÞᑖ+ᓄÞ(ZnO)
Na2s2O4᧕m>cúᓾᨔñ;ᐭ〉ÿ⛳
ᐸᨔ(4)Na2s2஺420Ḅᓄᔠ+3ᓄḄᓄᔠᓣ"#$+4ᡈ+6ᑣ#ḄᱥᨵNa2sChஹNaHSthஹNa2sO4ᡈNaHSOK+ᑏ2-)஺20ஹABDECNH"H2O(/)+CaO=Ca(OH”+NH3TNaHCO30ᔾᦈᢵ4ḄHC1ஹ56ᡂC஺8NH3ᙠᜧCO?ᙠ;ᜧ<ឋ0ᔾᦈCO?,>"C஺?ᑭᵨ᳛2CeO+HO+6H+==2Ce3-+0+4HOCᔠ0⏚EFGHI/JᜧK⊝ᔣ6ᡂCe"0NᔣO22222P9⏚Q95.68%Rூ᪆௃(W)᪷YᑴᜓḄ\]^ᳮ`2LaC13+6NH4HCO3=La2(CO3)31+6NH4Cl+3c(M+3H20,ᔠabcdWᑴᜓeᓄfYᑴᜓghXi◀keᓄfHCLᙠZᑴᜓf⏚lᔠghḄឋmᑖ᪆o(1)(4)
(e)ᵫqrstduf⏚┶wx(y⌕{CeFCCh)ᓄᯏ}6ᡂCeCh,⏚462CeO2+HO2+6H+=2Ce3++O2T+4HO,~ᑖH;ᱥ{Ce+Ḅ0⃓ᑖHᑮ/0<\]6ᡂ22Ce(OH)3,Ce(OH)3ᓄ6ᡂCe(OH)4஺Yᔠᓄ^\]Ḅஹ
Ḅᑖ᪆o(5)(8)஺ூ௃(W)(1)ᵫabdWᑴᜓeᓄfX◀kHCLYᑴᜓghᙠZᑴᜓf⏚ᑣᑴᜓf⏚qrstEᔣḄ`FTATB—DTETC,ᦑoᫀA
B
D
E
C

18(2)Y46\]Ḅᓄ\]QNHyHO(^)+CaO=Ca(OH)+NH3T,ᦑoᫀNHHO(^)+CaO=Ca(OH)2+NH3T;2232(3)Xi◀keᓄfḄᓄG◤⌕¡¢Ḅ£ᑺiNaHCCh0ᐸ¥ᵨᔾᦈᢵ4ḄHCIஹ56ᡂC(h,ᦑoᫀNaHCCh0ᔾᦈᢵ4ḄHC1ஹ56ᡂCCh;(4)Z]ᐜ§ᐭNH3,©§ᐭ~ªḄC(h,«N%ᙠᜧeᓄfᙠ;ᜧ<ឋ0ᑭᵨᔾᦈeᓄf>"C஺2ᑭᵨ᳛ᦑoᫀNH3ᙠᜧCO2ᙠ;ᜧ<ឋ0ᔾᦈCO?,>"C஺2ᑭᵨ᳛;(e)(5)ᓄᯏ}6ᡂḄᓄᔠᱥeᓄ®(CeCh),ᐸᙠ⏚¯46HI\]2CeO2+H2O2+6H+=2Ce3++O2f+4H2O,ᦑoᫀ2CeO2+H2O2+6H+=2Ce3++O2t+4HO2(6)ᔣCeTKᨵ°±)ᐭH2s04²³´Ḅ{Ce3+Ḅ0Ḅ^«iCᔠ0⏚EFGHI/Jᜧ,K⊝ᔣ6ᡂCe3+0NᔣOPᦑoᫀCᔠ0⏚EFGHI/JᜧK⊝ᔣ6ᡂCe-+0NᔣOPIx10-20·¸d298KKsp[Ce(OH)]=lxlO-20,¹º0Ce3+»¼½ᐰc(OH)=J=1x105moi/L,ᵫK“d3V1x10-5c(H+)=lxl09mol/L,pH=-lgc(H+)=9,ᦑoᫀ9
(8)জFeSO4¿ÀÁ⏚Â<©0Ã⏚ឋᑣFeSO40¡¢ᙠ⏚QÄÅᦑoᫀ⏚Q;ঝᵫ⊤ÈᦪYdÊeË25.30mL,Ìͳᜧ]ÎÏFeSO4ḄᱥmḄª23.1OmL+22.90mLO.lOOOmobL'xx0.001L/mL=0.0023mol,᪷YᵯIᜫÒឤᐵÕQCe(hFeSCh,ᵫ^I20.4784gÒឤdCe(OH)4Ḅmª0.0023x208g=0.4784g,ᑣCe(OH)4Ḅ´Wxl00%=95.68%,ᦑoᫀ95.68%;ঞᦋᵨO.lOOOmoM/iḄFeCL0ÄÅØÙÅCe(OH)4Ḅ´,Ce,+ᨵÁᓄឋ,46ᓄ^\],ᵫᵯIÒឤḄCe(OH),ḄᱥmḄªÚmªRÛᑣÙÅḄCe(OH)4Ḅ´RᦑoᫀR஺21ஹÜÝGH6+KOHeᵬßC5H5K+H2Oàá⊤☢Ḅãä◀k■æçè~FeCh•40ᨔ᪆Øéᜫºᵯᙠêᩩìí■æFe2+ᓄî᩽Fe-2e=Fe2+93gூ᪆௃(1)জñḄᨵ°ᱥ᪷Yòó;5ᑭᵨÜôḄNõᑖHঝstcö÷ø¥o(2)ᑴᜓêFeCL,ᵨùNa2cO30¯úiᑭᵨf⏚û0Ḅ<ឋ◀kà⊤☢Ḅãä~ᑮàáüýஹþÿ
⏚ḄFe-"ᡂᓄᓄ᪆

19!"#ᨔFeCL4H2O,ᓄ%&⏚'(
)*◤ᙠᓄ-Ḅ./ῃ)1ᑮ3)ᓄ43
জ68+29᧕;<.=.=ᓄ>ᐭ@.᣸BCD<.Eᵯ*ᙠ3=ᩩHIJK■MFe2+;=ᓄ4ঝOP/QRSTUFeVᵯ*WḄ□᩽ᜫᵯ[\=ᓄNiᵯ᩽]^ᵯ_Ḅ`᩽a▢᩽cOPᵯ*dᳮᑖ᪆Vg஺ூj*௃1
জ᪷P⚪nopSqrs6t6uvwx%174C
ஹrs6tvwx%41C
,ᑖz1ᑮrs6tSᑭᵨ}ὅḄwxᜧᵨḄJKᑖzᦑgᫀ%✄4ঝ/QRSTUᵫrs6tᡂC5H5KḄᓄQ%CH+KOH6ᵬC5H5K+H2O
562
জᙠ(ឋᩩHI)*ᵨNa2c038ᑭᵨ⏚Ḅ(ឋ◀⊤☢Ḅ4ঝ¡I*¢£¤¢Ḅᓣ¦§¨ᜧ©ªS■M«¤¬FeCh-4HO#ᨔ᪆§ᜫ423
জ68+29᧕;<.=.=ᓄ>ᐭ@.᣸BCD<.■M®¯Qz[;=ᓄᦑgᫀ%᣸BCDᑁ<.4ঝFeVᵯ*WḄ□᩽ᜫᵯ[\=ᓄᐸᵯ᩽%Fe-2e=Fe2+,Niaᵯ*WḄ▢᩽]^ᵯ_Ḅ`᩽ᙠᵯ*Qᳮ²³ᵯ´µ¶·1molᵯ[,ᡂḄFe?+ḄᱥºḄ%0.5moLᑣ1ᑮḄ6ḄᱥºḄ%0.5mol,ᐸº%0.5molx186g/mol=93go