2022年高三冲刺模拟化学试卷含解析

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2021-2022ὃᓄᔁ⚗1.ᔁὃḄஹὃஹὃ!ᑏᙠ⚪ᔁ⚪ᓱ&஺ᵨ2B)*ᔁ+,B!-ᙠ⚪ᓱ./0&஺ᩩ2ṹ45ᙠ⚪ᓱ6&7"ᩩ2ṹ45ᜐ"o2.<⌱>⚪?⌱@AB⚪ᫀDᵨ2B)*E⚪ᓱ&F/⚪G⌱⚗ḄᫀHIJ-KL᝞◤ᦋPᵨQRSTUDV⌱-ᐸXᫀ஺ᫀYZᙠ⚪ᔁ&஺3.[⌱>⚪\ᵨK⁐^_Ḅ`*ᡈb^*<ᫀ\ᑏᙠ⚪ᓱᔜ⚪Gᢣefgᑁ./0&L᝞◤ᦋPᐜᑜᣵlᩭḄᫀᯠDVᑏ&oᫀLYpᵨ)*-ᦋq஺Yᢥs&⌕u⚪ᐳᒹ22B⚪஺AB⚪ᙳᨵᔠ⚪Ḅ⌱⚗1ஹNA⊤ᦪḄ஺ᑡḄA.2.4gMg¡¢£⏚¥/ᡂNONO2Ḅ§ᔠ¨©ᜫ«Ḅᵯᦪ®0.25NAB.1molᵬ°ᑖ²ᡠ´ᓫ¶ᦪG®12NAC.lLpH=lḄNaHSO4·q²ᵫ¹ᵯº@ḄH+ᦪGe10“3»D.4.4gCO,N2஺C3H§Ḅ§ᔠ¨©²ᡠ´ᑖᦪ®O.INA22ஹᑡᨵᐵ½ᐗ¿ÀᐸᓄᔠᱥḄ⊤ÂᡈḄA.½lḄl{᪀ÂÄ@7
B.ÅÆḄ{᪀ÇO-HC.ᵨᵯÇ⊤ÂNazOḄ2ᡂÈÉ2Na.—*Na[O:]NaD.Êᡂ®C2H60Ḅᑖ²ËZÌᙠ᩽ឋ¶3ஹÏÐѨ´Ò½ᓄᱥNOxஹÓÔᓄᔠᱥCXHY
ஹÓÕÖ×᣸ÙÚ᧕⌼ᡂ“Þß”஺áâYãÏÐäåæѨUᓄæ0UᓄᜐᳮÈÉ᝞Ä஺ᑡᨵᐵèé┯ëḄA.Ѩ⌼ᡂ“Þß”ÏìíᐙᑖïðᨵᐵB.ѨᜐᳮÈÉÒ½ᓄᱥNOxñòlC.Pt-RhóᓄᑺËõѨUᓄ¥/Ḅö⊝øᓄ᳛D.pᵨÔ½ïᧇᵯû<ÏÐPüZᨵᦔýᑴÞß4ஹᨵÿᓄᔠᱥᙠஹᱥஹᩞᧇ⚞ᢵḼḄᵨ஺ᑡḄA.ᵬ"#$%ᵬ"Ḅ&'(ᱥᙳᨵ4+

1B.ᢥ./012ᓄᔠᱥCH3”COH
CCH33Ḅ1342,2,3-5ᵬ6-3-8⏣C.2-8:ᑖ<=Ḅ>?@A<ᙠB&CDED.F⏚ᵬHᑖ<ᙠ᪶JᐳLMN=OPQR&ST5ஹᙠUVᩩX2ᑡ⌱⚗ᡠ\Ḅᱥ]$^ᓄᙳP&_`RḄA.S-^^SOJWHSO4342B.N%aᐁc23HNO3C.CU2
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s
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6ஹᨬhijkRlᵫnA<᪀ᡂḄqnqnḄnA<%rs᪀᝞uvwx:yzḄ{|%r}~ᩞᧇ.ᑡḄA.wx::B.wx:=@A<ᵨsp3ᩖᓄC.qnn4BD.qnᙠ=Vᙠ7ஹBB2]ḄSO2#SO3v2ᑡ=ḄA.v44:5B.ᱥ]Ḅv44:5C.v41:1D.A<ᦪv43:48ஹᑡᱥ]eef¡ᵯ£¤ᕈ⏚ឋḄA.KC1B.NaOC.NaHSOD.FeCh249ஹᑡ`§=Ḅ¨⁐ªᓄ2«ᓄ¬A®¯ᐵḄABCDNaOHef±ᐭFeSONa2sef±ᐭAgClµ4`§w³ef±ᐭ´=¶·¸¹ᐭº»⏚=ef=f=½¾⁐¿À2ÁªefªÂ2ÁÄÅÆ¿Àᵫ⁐⌲Ȫ4½¾¯⁐2ÁªR¼4Â⋎⁐⁐q⁐4ÂÉ⁐A.AB.BC.CD.D10ஹᨵ&+Dឋᑖ<2s᪀᝞uᡠ\஺

2HUoOHHoo—n—3-ChnHIcoCoet一-C—-——C-I-L—HUnHCH:UntᑡᨵᐵḄA.Êᑖ<ᵫ4+ᓫÌᔠᡂᑖ<ḄÍᓫÎᑖ<Ï̤ᡂB.᪀ᡂÊᑖ<ḄÐ+Ñ⏚ᓫ4B.ᱥC.Eᓫ=ḄF%⏣2Ò02Óᓄ«ᓄ¾ᡂᓫ&Ḅ₝⏚D.Êᑖ<ᨵÕVᰚஹ×Ø2ImolEÙ⁚ÛᐰÝ◤⌕M«ᓄàᱥ]Ḅ45moi11ஹMPáᨬᐹ®ᵨãäḄPá&2åMḄᑴᜓèãḄẆê¶Ø஺ᑭᵨì□PᐝïᵯðᵯÝᑴåñ,ó\ôu᝞uᡠ\஺õö÷ᑴøᐵùúKi#K2,ûüýᑮH2#02,ᑡᨵᐵ┯ḄA.ᑴH2ᐵKi,H2Ḅᵯ᩽2H2O+2e-=H2f+2OH-B.ᐵK2ᵯ᩽3ḄNiOH2E+OH-=NiOOH+H2OC.ᐵK2ᵯ᩽2□᩽ᑮ02D.ᵯ᩽3Ḅᵨᑖ□᩽ᩞᧇ▢᩽ᩞᧇᑭᵨNiOOHNiOH”Ḅ!"#ᓄ%&ᵯ'#(12ஹᵫ+ᑡ-./-0Ḅ12345Ḅ-.126789ᐭ;Ḅ<=ᓄ>?@?@ᨬBCAᡂḄ1,2-JK7LD⁐M?N<=ᓄ>D⁐FG7⏚7PQRᓄS?@TᔠᐳWXTᔠ@B7⏚7PᙠQRᓄS?@\M]ᐰ_`3YᑖZ

3ℍ⃔defᑴQRᓄgTᔠᐳWXᡂẈiCℍ⃔dlmឋd⁐jk7⏚7⏣pMeqrSMsឋtD7⏚ᑖ'\ḄQe7⏣ᑖ'\ḄQᐹᨵ!xḄyឋuA.AB.BC.CD.D13ஹᑭᵨCCL+4Naz᫔9q|}+4NaClM-~ᔠᡂq|}஺+ᑡᐵNḄ┯ḄA.Cq|}rNm'ᨔuB.ᑭᵨNaḄlmឋC.CCLCq|}\ḄCḄᩖᓄ!xD.NaClᨔu\Cᕜᨵ8Na+14ஹᵨNA⊤ᦪḄ+ᑡ45ḄA.31g\ᨵḄᵯ'ᦪ3.75NAB.᪗+22.4LḄCgHio\ᨵḄ>Q¡Ḅᦪ¢IONAC.lL0.1molL”Ḅ7⏚?@\ᨵḄRm'ᦪ0.2NAD.5.6gFee¤¥1Feᜫ§0.2NAᵯ'215ஹ¨©ᕜªᐗ¬XஹYஹZஹWḄᨬ®Rᓄᱥ?N_M<°?@0.01mol/LḄ±<°?@pHeᐗ¬m'²³Ḅᐵ´᝞+¶ᡠ஺+ᑡ45ḄA.¸ᓫº'²³:X>Y>Z>WB.WḄᓫ¼ᙠ½+¾¿⁐tuC.t᝱QᓄᱥḄÁÂឋÃZ>W>YD.XYḄᨬ®RᓄᱥÄḄ_ᓄᱥាÆ\?@\ḄÇÈᐳᨵ2°16ஹ>⏚JᵬPCH3O2COÊ°ᐹᨵËÌÍÎḄ“¿⁐”ᓄÐᵯᓄÑᔠᡂ>⏚JᵬPḄmᳮ᝞¶ᡠᐭÓ᩽Ḅᱥ¼ᙳ½Õ+Ḅᱥ¼஺+ᑡ345Ḅ

4ABÖ×ᵯØCH3OHஹCO-\JCHO)CO32iinz}Ù1᩽¼'ÚᣚÜ}Ù2᩽A.}Ù2᩽eÖ×ᵯØÝ᩽!B.}ÙI᩽ËḄᵯ᩽2cH3OH+CO-2e=(CH3O)2CO+2H+C.H+ᵫ}Ù1᩽9Þ¼'ÚᣚÜᔣ}Ù2᩽(àD.ᵯ`ÊáâX▢᩽□᩽ãὑḄtuḄᱥ¼Ḅ¥åæ2117ஹ+ᑡᵫ-.0Ḅ1245Ḅ-.126〉¥èᐭé_\ᐙᑖë₩Xí_ZîAèᑖ'\ᨵ>>ï¡ðeB஺ËᡂD⁐ᔣñ?@\ᐭòó⏚ᡂô¾⁐jkᨵõB?@\ÊÂᨵS2O.?-öឋtᕡḄtuᔣⅅd?@\ùòó⏚WᯠXᐭfᑴCⅅᡈḄᱥឋCu(OH)2ûü@WýþÿᑮẈ⁐ᩩḄNa2c03!D()*ឋ+S>CNa2s04ḄpH,"ὅᕈ%ឋ&ὅᕈ'ឋA.AB.BC.CD.D18ஹ-.2Al+2NaOH+2H2O=2NaAlO2+3H2T஺012'ᨵᐵᱥᳮ6Ḅ789:Ḅ(N.ஹ⊤<=>?@ABᦪ)()A.GHᡂ6.72LḄH2,'A1O2JḄᦪKLMNO0.2NAB.GHᡂ0.15molH2,PḄᑖRᦪKS0.3NAC.T?ᐭ2.7gAlVWXḄᵯRᦪKS0.3NAD.'GM?0.1molḄAKhNa+ḄᦪKLM?0.1NA19ஹZ[ᨵpHᙳS9,]^ᙳS10mLḄNaOH!CH3coONaᑡ`a9:ḄA.bc'Ḅc(Na+)B.b'ᵫᵯefḄc(OH-)ghS10-9/10-5

5C.ᑖᑮ100mL!"ḄpH$ᯠ&'D.ᑖ()*+Ḅ,⏚./ា1./2ὑḄ,⏚45&'20ஹ89:ᵨCO?ᧇᵬ⏣஺DEᩩGHIJKᘤMN=./OPᦪRST᝞HVᡠX./Yᔠᱥᙳᕈ^᝱
஺Hᑡab┯dḄeA../Ḅᓄghij:CO+2H2=CH30HB../klm3ᑖnoஹ⌮./q᳛&'C../m10ᑖnUCO
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7CHO©RCHO+HOOCCH2COOHttiRCH=CHCOOHËÌÍHᑡÎ⚪(1)ᓄᔠᱥAḄÏe;ᓄᔠᱥIMÑÒÓḄÏeo(2)G-HḄ./ÔÕe:DḄÖ᪀je,(3)ᑏÚᓄᔠᱥC(ÛᑴCu(OH)2ÜÝ"./Ḅᓄghij»(4)ᓄᔠᱥW(Eß)ᑖà᪀4ὅᡠâÑÒÓÔ<ᦪãäᐰ&)æçè:¦ᨵ3éêëìᑣWÒḄÖ᪀ᨵ(|ὃ⇋ñ.à᪀)ᐸM᪶ôᐳõö÷Xᨵ6|)ᓄgè᛻Ḅù☢5û21:2:1:1:1:1,ᑏÚüᔠ⌕ýḄWḄÖ᪀j:o(5)þ᯿
ᔠᡂᵫCH3CH—CH2HOOCCH2coOHᧇᑴᜓCHCHCH=CHCOOHḄᔠᡂ(22ᑺ⌱)஺o25ஹ(12ᑖ)⏚!"ᨔ$CH3cH(OH)COO]2Fe3H2O%&'()Ḅ*+",ᓄᑺ᧕/01234ᵨ0ᑴ+ஹ⃩789ᔾᦈᦔ=>")?ᵫ⏚@FeCChA4ᑴBC2CH3CH(OH)COOH+FeCO3+2H2O->[CHCH(OH)COO]2Fe-3H2O+CO2t3I.ᑴᜓE⏚!"(FeCCh)FG᝞IᡠK஺(1)LᘤCḄNO%(2)PQLᘤRSFGTUឋAWXᐭZ⏚BWXᐭ"[CWXᐭNH4HCO3/8஺\ᑭ^ᡂ_`aḄ
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22CH—(HC(X)H24ஹÚÛÜÝᵬÞ(à)ÛÜஹâÜஹ44ãäåæJKCHOC(X)NaCII-CFKXXHIAஹA1,|1\,('”()▼nçOCH>J(X?H,HOOHHOJOH(K'Hj(XHCH-;BrCHQ%ᙠᓄbᐳùíEJKEᡂHOCHúHY^ᑣHVHOCHû§BúுHOCH[CH,I^2^OHOHucACᙠ1⏚}ᵨAᐳùíEâᓄJKEᡂXHO-COOHHO-H—COOCHCH—22ூ௃CHO(1)ᓄᔠᱥAḄµ᪀þqVQ,ÿ
ᵬᓄᔠᱥIḄ᪀
OH0H15yHYHYOOCH2-0'
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23CHO(2)G-HḄ*+
BrCH□ᙠᓄ-./0ᐳ23456*+4ᡂH0CH,CH,89ு[(KH,(X.H,CH-CHC(X)HCH-CH('(X)11CH-CHC(X)HHOOCCHiCOOH34EFঝ*+4ᡂᑣD
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LM*+;(r,I(X'H(X*H(X'H(IK)(3)CḄ᪀
#OᑴḄᓄQRS/ᐳ234ᓄ*+#*+ḄᓄTUV
W(XH.CHOC(X)Na•HL\.()11.Cu()v-311(),ᦑ%ᫀ
t(OCHjW(X.H,(XH(KHC(X)Nn•t*2Cii(()H).,NJIOH--*•Cu()▼H()(4)ᓄᔠᱥWE()d
eᑖg᪀h#iὅᡠlmnᦪpqᐰse#tuvᨵ3xLM,yxLM
-OHஹ-OHஹ-CH=CHCOOH,ᡈὅ
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22LLLLᔠ⌕ḄWḄ᪀
AXA#(lM10MஹCH=CHC00HCH=CHC00Hᦑ%ᫀ
I1Q0MஹCH=CHC00H(5)ᔠ⚪ᔠᡂ#ᑴᜓCH3cH2cH=CHCOOH+ᵨ⌮¡#CH3cH=CH2HBrᙠ¢ᓄᱥᩩ¤¥*+4ᡂCHCH2CHBr,ᯠ§¨ឋᩩ¤¥564ᡂCH3cH2cH2OH,ª34ᓄ*+4ᡂCH3cH2CHO,ᨬ§32HOOCCH2COOHᙠ¬ஹ®2ᩩ¤¥*+¯ᑮCH3cH2cH=CHCOOH,ᔠᡂ±V²
COOHHjCஹᦑ%ᫀ
•(HjCHQI³ஹCHJCHKH/HOQ.CM1cHX'HO------cHCHCOOH1♦¢mtn

24CHjCHtlb«CHᑘµ——-·¸JCHJCHJOH2^1.CH«HVHOCCHKHjdTKOOHூÎÏ௃Ð⚪ὃÞᨵßᱥà¾:ᔠᡂᐙᑖᑭᵨäᓄBᱥåḄ᪀:ᑖ
Å×ᑖ᪆ᑨ¾çèéêḄឋå:äᓄMᐵG஺25ஹ¬⚠íî21ஹ3ïð⌲òVW/Bᨵ.óᑈõஹVWöᡂ÷ø⁐32Fe2++2HCO3=FeCO31+CO2T+HO■ûFeCCh:ü⏚`aýḄþï
ÿᓄ⏚᪷⏚ឋ╎⏚2ᓄ98.0%ூ᪆௃᧕ᓄᑴᜓᙠ"#᛻%&Fe'(⏚)ᑴᜓ*ᓄᑭᵨ)-ᡂḄ0᣸234Ḅ5ᦑBᑴᜓ*ᓄᑭᵨ-ᡂḄ07B3489ᜧ;B34Ḅ*ᓄ8ᐭCC34FeCh=NH4HCO3>-)?FeC12+2NHHCO3=FeCO31+2NH4CI+CO2?+H2O,@ABC⚪஺4ூF௃(1)GᘤCIJ⚠LMᦑBᫀI?J⚠LMO(2))Pᐜᑭᵨ-ᡂḄ0◀S34ᑁ5Uᑭᵨ-ᡂ07B3489ᜧ;B34Ḅ*ᓄ8ᐭCᐹWXYI?ᐵ[\]2,ᡭ_\]3,ᯠaᡭ_\]1bᐭcdḄ(⏚ᯠaᐵ[\]1,)efgha34BijkᑮḄmnI?o⌲qWᨵsᑈuஹwᡂxy⁐Oᡭ_\]2,ᐵ[\]3C34FeCL=NH4HCO3>-)?FeC12+2NH4HCO3=FeCO31+2NHCI+CO2T+H2O,)Ḅ{|I?4Fe2++2HCO-FeCO31+CO2t+HO,32ᦑBᫀI?21ஹ3o⌲qWᨵsᑈuஹwᡂxy⁐O32Fe2++2HCO3=FeCO3+COt+H2O2(3)Fe?+᧕ᓄIFe3+~Ḅᑴᜓ⏚ᨔWbᐭFeoi■Fe?+ᓄᦑBᫀI?■FeCQs'⏚)-ḄᓄO(4)⏚᪷ᨵi⏚ឋ═⏚ᓄὑ═⏚Ḅ9ᜧᢥᓄᦑᡠ⏚Ḅdᜧ⏚Ḅdᑖᦪᜧ100%,ᦑBᫀI?⏚᪷⏚ឋ═⏚ᓄO(5)JXYὑ᪗ᦪ¡¢£ᜧ¤S¥e=J¦ᙳ¡V=ᵨ^2©=19.60mL,2ᵫ?Ce4++Fe2+=Ce3++Fe3+,25mLn(Fe2+)=n(Ce4+)=0.100mol/Lx0.0196L=0.00196mol,ᦑ250mLᨵ

25250mL0.0196molx288g/mol,.«(Fe2+)=0.00196molx——=0.0196mol,ᦑ⏚ᨔWḄdᑖᦪI-------——-——xl00r%tn/=25mL5.76g98.0%,ᦑBᫀI?98.0%o26ஹO2Cu2++2Br-+SO+2HO2CuBr+SO2-+4H+6(TC¬b®¯⁐°ᐰ²S■CuBr2224³ᐝᑖ■CuBrᓄ◀S⊤☢·⏣¹7ᨔWº»¼½ᙠL¾¿ÀÁᐭSO2Â⛳=ᯠaᔣL¾bᐭ100g20%ḄNaOHÅᵨ·⏣ÆÇ23ூ
᪆௃পÉᓄÊË᠒᠒ᓄ⌕᣸◀Ḅ¼᡾OফজJ⚠LMÊᓄÑÒÓᡂÊ'Ô)-ᡂCuBrÕÖOঝØᑴ)ᙠ60࠷%&iᵨ60'CḄ¬b®Oঞ45gCuSO45H2OI0.18moL19gNaBrI().184moLᡠNaBrÙdᡠÚḄÊὑ°g)ᓽ°ᡂO(3)ÜᓄʳᐝᑖO(4)ÜᓄÊᙠ5᠒᠒ᓄÆÇᑺ◤“ᨵSO2”i■CuBrᓄᑺᦋᵨ·⏚i◀S⊤☢·⏣¹7ᨔWº»¼½OমL¾Ḅᔾᦈä⌕Na2s஺3ஹNaHSChåᑴ¥æçèḄNa2sChOIhOᨔWiᙠL¾¿ÀÁᐭSChÂ⛳=;Na2sCh-ᡂNaHSCh,᪷@éᐗëìឤiîAgNaHSChḄᱥḄdI0.5moLᯠaᔣL¾bᐭ100g20%ḄNaOH7NaHSChាñ°ᐰ)-ᡂNa2so3,bᐭòdó-ëC(ᢙᑺ)÷>øùúᓾüᨔÅᵨ·⏣ÆÇ23◀S⊤☢iឋᩖþÿ

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*ឋ¯ᜧḄ+3ồᓄᔠᱥAsO43+2e+2H+=AsO3+H2Oᙠ°±ᐭ(NasAsCh)³ᡈᐭ´3

27ூl᪆௃⏚ឋm¦¸¹£ᐭᓄºஹ⏚»¼ᐸ⏚»¼U◀¿`ḄyÀrᑮAs2s3ÂFeS,ᐭÃ.ᓄºrᑮÄ
FeS,¦ᨵNa3Ass3ஹNaAsO3,.ᓄ(ᡂῃNasAsChÂÆÇ⁐
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7+8+18=33,ᦑÀᦪ
42ḄAsḄ`ᦪ
42+33=75,ᐸ:Àðñ
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28(4)pH
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