2022-2023学年天津市河东区高考化学仿真模拟试题（二）有答案

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2022-2023
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ᵫ+ᜫᵯᦪ/0ឤ2+ᨵ᝞5ᐵ782cle)212292$2஺32C102,;ὑV|mLcmol/L⏚ᑣᡂ⏚᪷Ḅᱥ>Ḅ?l(T3cNmol,ᵫ+ᜫᵯᦪ/0ឤ2+ᨵ᝞5ᐵ78C102124Na2s2O3,;ὑVimLcmol/L⏚ᑣ@⏚᪷Ḅᱥ>Ḅ?*X10-3cV2moiT0-3cVimol,ᡠB@xlO%V2moi-©cymolc—)⏚᪷ḄCD10'VL=4Vmol/L,ᦑ)*
4V஺9.(1)GHஹJ⏚ফ6NaCN+FeSO+CaCl=Na[Fe(CN)J+CaSO1+2NaCl42444K++[Fe(CN)J4'+3H,O=K[Fe(CN)]-3HOJ362(3)b(4)4

15(5)ᵨgᴻiᔣkᧅmn⏣pqrstun⏣vᯠx5yz{|2-3(6)95.0%CD(1)⏚GG᧕ᓄG᧕@⏚ឋ,ᦑᵨᨔᑴ⏚G■ᐸ#>◤⌕mḄᑺGHஹJ⏚J⏚2BᢓᑴG@GH¢£¤¥G¦ᓄ¥G
(2)ᵫx§2¨ᘤNaCNஹFeSOCaCl?᪷«>?0ឤᨬᱥ4K®Fe(CN)j3HQ±ᵗ³´µNa®Fe(CN)Jஹ¶SO®NaCl·´.ᓝ,¹ºº4L'2¼½ᡂ4L\4,Ḅ¿⌕6NaCN+FeSO+CaCl=Na[Fe(CN)]+CaSOJ+2NaCl42464(3)ᘤ+ᑮÁÂᨵNaÃFe(CN)],rÁÄÁÂᨵr?Ḅ┛2Bmᐭ〉?ḄÈ⏚┛ᡂÈ⏚┛stqᨵÉᐭÊḄᩖ>ᦑᙠ“◀ᩖ”ÐÑᔣ7mᐭ〉?ḄᑺXÈ⏚
ᦑ⌱b8(4)ᵫx§2¨¦ᓄᘤmᐭᓄÔÄᨬᡂGÕᓄÔᨔᦑNa[Fe(CN)]ᓄÔ¦ᓄÖ/©!>],Û§Ü464K"+[Fe(CN)Þ+3HO=K,[Fe(CN)]-3HOJ262(5)GÕᓄÔᨔ2Þ@qᨵÞn⏣2rÁ+ᑮGᓄÔᨔ◀ßᨔ⊤☢Ḅᩖ>â2Bn⏣ãäᦑåæÐÑaḄ{|ᵨgᴻiᔣkᧅmn⏣pqrstun⏣vᯠx5yz{|2-3
যজ᪷«Û§Ü'Ḅᐵ72¨1°K4[Fe(CN)6}3HQ+122KMnO-299H2SO,ᑣ᪵44K130.50X10-3LX2.000mol.L1x—x10000mL=o.020molòKye(CNô®Ḅᱥ>Ḅ?]2225.00mL,4O.()2()mRx422g´õ*100%a95.0%ᑣ÷᪵òḄøDù8.884g.ঝA.ÐÑ1r§þ⊈ᡠᙠᑖᓄ᪗ᵨA┯B.!"#$%!"&'ᦪ!")'ᦪ*+'ᦪ,B┯;C.!"/)!"&ᑁ1▬Ḽ!'ᦪᜧ5C*+D.!"#!"&7ᘂᑖᨵ:!")7ᘂᑖ;:᪗ᵨᜧ5D*+:5

16ᦑ⌱CD஺10.-1155.5A,FᓄᑺAᙠHIJKᐹᨵH5ḄNឋ⁚QRSTUVWX,(0.5x50)2IᨵᑭZ[ḄᔠᡂT,925x50)4NᓄRgᜧUVh23᳛g᠒BCDᐜlm᪷oN2(g)+()2(g)=2N0(g)u"᪷owx"y:জ+ঝ-ঞ}CH4(g)+4N0(g)=2N(g)+C0(g)+2H0(g)uᙠIJT250MPa,ᑡmUVḄ222N,ঞ〉Ḅ◌¨஺2©ᐰUV«¬ᡂ2.24L(᪗®¯K)2N0ᓽ¬ᡂ0.ImolNO,ᔾᦈ8.9kJḄXᑣ¬ᡂImolNO,ᔾᦈ89kJḄX஺¶}N(g)+0(g)=2N0(g)A/A178kJ-mor1,᪷owx"y:জ+ঝ-ঞᑣ¸ভ+4N0(g)22=2N(g)+C0(g)+2H0(g)uº-865.0kJ-molT-112.5kJ-mol-'-178kJ•2221155.5kJ•mol-1,ᦑ-1155.5(2)জᔠᡂ[◤⌕⌱¾ᔠ〉ḄFᓄᑺ¿▭¬Á〉Â⌱¾ḄFᓄᑺÃA,ᳮᵫÃFᓄᑺAᙠHIJKᐹᨵH5ḄNឋ⁚QRSTUVWXIᨵᑭZ[Ḅᔠᡂ஺ᦑAFᓄᑺAᙠHIJKᐹᨵH5ḄNឋ⁚QRSTUVWXIᨵᑭZ[Ḅᔠᡂঝ᝞Æ2,ᔠᡂ[ÃWXUVÇÈÉ•ᓣ5IJ⊝⌮ᔣÍÎ[ḄÏÐᑖᦪgÑஹ12ஹÓ3ᵫ,ᑮᜧḄ᣸Ö×Ø<Ó2<Ó3ᙠ12ஹ50MPaᩩÚKAÛÜZÝ⊝®᝱UVᔣ*ᔣßà2>%(áᡈ"=").ᙠIJ50MPaM(g)+3%(g)U2N4(g)/mol1020ᓄ/ᑗ஺/X3x2x2x-05⊝/mol10-x20-3x2x10-x+20-3x+2x,x=5mol,ᔜ^-^=0.2520-5x3n”ᱥḄᱥḄᑖᦪ:ᵯ×20,ᵯ×20”ë×0.5,P(N2)=50X25%MPa,p(H)=50X25%MPa,p(NH)=50X50%MPa,⊝åᦪæ=236

17(0.5x50)2(0.5x50)2(0.25x50)(0.25x50)3©25x50)4)12(ᑡm⊤îᑖ=ïXᱥḄᑖᦪ)஺ᦑ=(0.5x50)2T(825x50)4123ঞi.ñUVḄNᓄREióôõñUVḄNᓄRE2Èö÷E|>E2,ᑨúᳮᵫNᓄRgᜧUVh᳛g᠒஺ᦑNᓄRgᜧUVh᳛g᠒ii.A.IJû5ZüIÃ×ýþÿᓄᑺḄឋᦑA┯B.ᔠᡂᡂᡂᱥḄᓄḄᜧᱥḄᓄᔾᦈḄ#ᙠ%ᨵ'()*Ḅ+஻-./ᔠᡂ#011234Ḅᙠ%ᨵ'()*Ḅ-./ᦑB56C.NH3᧕=ᓄ%ᨵ>?=@A34ᡂᱥB)ᑭᔣEFᦑC5D.Hᧇ0JMᵫᑖNO0Pᑮᵫᜩᯠ0TUV0ᡂHᧇ0◤⌕Yᓄᜐᳮ\■ᓄᑺJ^_`ᦑaᦑD5ᦑBCD»11.0sp2SO2TH0᩽ឋk'(ᡈS02TH0ᙳo᩽ឋᑖp)22248x1()21N02+58Ma(1)vwஹUஹyzᓄ{ᡠ}ᐗᨵHஹCஹ0ஹNaஹS,'ᕜᐗᑮᵯឋ'ᐗᑮ*ᵯឋ3ᑣᵯឋᨬo0,vwJ▢NpoHpḄ±2=3ᵯpᦪy2,ᵨsp2ᩖᓄᦑosp2ᔩ(2)yzᓄ{HpḄᵯpᦪo62,ᨵᵯpoV᪀ᵯ₹%ᨵ¢ᔠo᩽ឋᑖp᪷¤k¥k¦Hᳮ§¨ᐸ᧕¦᩽ឋ¦ᑺUªᵯp1#Hpᦪ_ᵯpᦪk'Ḅ«pTyzᓄ{¬oªᵯp1Ḅ▢NpᨵN0"ᦑSO2TH0᩽ឋk'2(ᡈS02TH0ᙳo᩽ឋᑖp);N02(3)ᵫ᪀¯§¨᪗ᨵ“*”Ḅ{T´µzHpᡂᐳᨵ5ᐳᵨᵯpᓄᔠo+5,ᦑ+5ভজᵫᨔº᪀§¨6\☢¼½ᳫo¿ÀÁ§¨ᐸᙠµᨔºJÂÃḄÄᳫᨵ4µᵫ7

18Ƨ¨▢NpᕜǪÈḄ□Npᨵ8µÊËᦪo8,ᦑ8ঝNa?஺ᨔºoÍÎᨔºJNaË1ᑁµᦪo8,஺ᨵ8µᙠ⚔Ñ6µᙠ☢¼µᦪo8x23+4x16248C1/14-----------------------8x-+6x—=4782ᨔºḄÒo6"ANAgÔᨔºḄ12oÕ'×஺6'cm',ᑣᨔ2487T248x1()21248xlO21A___________________ºḄØ)=(axl°"N@'g.cm-3,ᦑ¼'12.CDÙCBAÚÛÜÝÞᡂßA50-CHOcCHjCHQ2i!2CHKKjO!—CH>CHO-*Q-

19⏣ᓄᓄiᡂ''gᵬ'ᙠ9ᓄ¡ᩩiᡂCHYHCH஺ᙠ9¢/Rhᩩhi5ᡂiᡂUVWXL£O-CH0__CK>CH^1C&CHOB(OH)-O-