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1、SupportinginformationforAllPolycarbonateElastomersBasedonTriblockCopolymersDerivedfromTriethylborane-MediatedCopolymerizationofEpoxidesCO2withVariousEpoxidesMingchenJia,†DongyueZhang,†GijsW.deKort,‡CarolusH.R.M.Wilsens,‡SanjayRastogi,‡NikosHadjichristidis,†YvesGnanou,†andXiaoshuangFeng††Physica
2、lSciencesandEngineeringDivisionandKAUSTCatalysisCenter,KingAbdullahUniversityofScienceandTechnology(KAUST),Thuwal23955,SaudiArabia‡Aachen-MaastrichtInstituteofBiobasedMaterials(AMIBM),MaastrichtUniversity,P.O.Box616,6200MDMaastricht,TheNetherlandsS1CONTENTSEXPERIMENTALSECTIONFigureS1.1HNMRofPBC
3、inCDCl3.FigureS2.1HNMRofPHCinCDCl3.FigureS3.1HNMRofPBGECinCDCl3.FigureS4.1HNMRofPEHGECinCDCl3.FigureS5.1HNMRofPAGECinCDCl3.FigureS6.1HNMRshowstheinteractionsofepoxideswithTEB:(A)BGEandEHGEmixedwithequalequivalentofTEB;(B)AGEmixedwith4equivalentsofTEB.FigureS7.DSCcurveofPBC(Entry3,Table1)ataheat
4、ingrateof10oC/min.FigureS8.DSCcurveofPHC(Entry10,Table1)ataheatingrateof10oC/min.FigureS9.DSCcurveofPOC(Entry5,Table1)ataheatingrateof10oC/min.FigureS10.DSCcurveofPOC(Entry17,Table1)ataheatingrateof10oC/min.FigureS11.DSCcurveofPBGEC(Entry12,Table1)ataheatingrateof10oC/min.FigureS12.DSCcurveofPB
5、GEC(Entry18,Table1)ataheatingrateof10oC/min.FigureS13.DSCcurveofPAGEC(Entry15,Table1)ataheatingrateof10oC/min.FigureS14.DSCcurveofPEHGEC(Entry19,Table1)ataheatingrateof10oC/min.FigureS15.DSCcurvesofthetriblockcopolymersinhightemperaturerange.S2FigureS16.Phaseangleandtanδofthetriblockcopolymersa
6、safunctionoftemperature.TableS1.EstimationofMeUsingGuth-Smallwoodapproximation.FigureS17.CyclictensilecurveforP(C-O-C)1withultimatestressof1.5MPaandnodelaybetweencycles.FigureS18.CyclictensilecurveforP(C-O-C)2withultimatestressof1.5MPaandnodelaybetweencycles.S3EXPERIMENTALSECTIONMaterialsAllthe
7、reagentswerepurchasedfromSigma-Aldrichandusedasreceivedunlessotherwisestated.BO,HO,OO,BGE,EHGE,AGEandtetrahydrofuran(THF)werepurifiedbydistillingfirstlyoverCaH2andthenovern-butyllithiumforfourtimesusingstandardSchlenktechnique.The
