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时间:2020-03-22
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1、第44卷第9期周灿,等:PP/POSS纳米复合材料热氧化稳定性·llI·复合材料的最大失重速率温度从361。7℃提高到[7]ZHOUZY,CUILM,ZHANGY,eta1.Preparationand381.7oC。并利用Kissinger法和Flynn-Wall—Ozawa方propertiesofPOSSgraftedpolypropylenebyreactiveblending[J].EurPolymJ,2008,44(10):3057-3066.法对5%OV.POSS含量的复合材料E进行了研究,研[8]ZHOUzY,ZHANGY,ZENGY,eta1.Prop
2、ertiesof究表明OV—POSS可以明显提高PP的E,通过上述POSS-filledpolypropylene:Comparisonofphysicalblending两种方法计算所得复合材料的E。分别为92.48kJ/molandreactiveblending[J].JApplPolymSci,2008,110和97.53kJ/tool,比纯PP分别提高了24.69kJ/mol(6):3745—3751.以及35.72kJ/tool,从热氧化降解动力学的角度解释[9]ZHOUZY,ZHANGY,ZHANGYX,eta1.Rheological了OV-POSS能提
3、高PP热氧化稳定性。behaviorofpolypropylene/octavinylpolyhedraloligomeric参考文献silsesqui—oxanecomposites[J].JPolymSei,PartB:[1]NIESB,ZHOUC,PENGC,eta1.ThermaloxidativePolymPhys,2008,46(5):526-533.degradationkineticsofnovelintumescentflame·-retardantpol·[10]ZHOUZY,CUILM,ZHANGY,eta1.Isothermalcrys·ypro
4、pylenecomposites[J].JThermAnalCalorim,2015,tallizationkineticsofpolypropylene/POSScomposites[J].120(2):1183—1191,JPolymSci,PartB:PolymPhys,2008,46(17):1762[2]BOUZAR,BARRALL,DIEZFJ,eta1.Studyofthermal—1772.andmorphologicalpropertiesofahybridsystem,iPP/POSS.[11]wUJC,WUZL,YANGHM,eta1.Crossl
5、inkingoflowEfectofflameretardance[J].CompositesPartB,2014,densitypolyethylenewithoctavinylpolyhedraloligomeric58:566—572.silsesqui—oxaneasthecrosslinker[J].RSCAdv,2014,[3]BUTOLABS,JOSHIM,KUMARS.Hybridorganic-inor-4(83):4030—4038.garlicPOSS(polyhedraloligo—mericsilsesquioxane)/polypro—[12
6、]卢成渝,田春蓉,王建华.POSS/PUE纳米复合材料的pylenelano-compositefilaments[J].FibersPolym,2010,制备与表征[J].材料导报:研究篇,2010,24(5):11(8):1137-1145.111—114.[4]SMITHER,HOWLINBJ,HAMERTONI.UsingPOSS[13]蔡华轮,许凯,刘欢,等.PC/POSS复合材料的制备及reagentstoreducehydrophobiccha-racterinpolypropylene热性能[J].高分子材料科学与工程,2011,27nanocompos
7、ites[J].JMaterChemA,2013,1(41):(12):114-118.12971—12980.[14]JIAOJ,LVPP,WANGL,eta1.Theefectsofstructure[5]王豪,王秀峰,王学智,等.POSS/聚合物纳米复合材ofPOSSonthepropertiesofPOSS/PMMAhybridmaterials料的研究进展[J].材料导报:综述篇,2012,26[J].PolymEngSci,2015,55(3):565-572.(3):144—148.[15]CHENYH,WANGQ.Ther
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