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1、METHOD8260CVOLATILEORGANICCOMPOUNDSBYGASCHROMATOGRAPHY/MASSSPECTROMETRY(GC/MS)SW-846isnotintendedtobeananalyticaltrainingmanual.Therefore,methodproceduresarewrittenbasedontheassumptionthattheywillbeperformedbyanalystswhoareformallytrainedinatleastthebasicprinciple
2、sofchemicalanalysisandintheuseofthesubjecttechnology.Inaddition,SW-846methods,withtheexceptionofrequiredmethodusefortheanalysisofmethod-definedparameters,areintendedtobeguidancemethodswhichcontaingeneralinformationonhowtoperformananalyticalprocedureortechniquewhic
3、halaboratorycanuseasabasicstartingpointforgeneratingitsowndetailedStandardOperatingProcedure(SOP),eitherforitsowngeneraluseorforaspecificprojectapplication.Theperformancedataincludedinthismethodareforguidancepurposesonly,andarenotintendedtobeandmustnotbeusedasabso
4、luteQCacceptancecriteriaforpurposesoflaboratoryaccreditation.1.0SCOPEANDAPPLICATION1.1Thismethodisusedtodeterminevolatileorganiccompoundsinavarietyofsolidwastematrices.Thismethodisapplicabletonearlyalltypesofsamples,regardlessofwatercontent,includingvariousairsamp
5、lingtrappingmedia,groundandsurfacewater,aqueoussludges,causticliquors,acidliquors,wastesolvents,oilywastes,mousses,tars,fibrouswastes,polymericemulsions,filtercakes,spentcarbons,spentcatalysts,soils,andsediments.ThefollowingRCRAanalyteshavebeendeterminedbythismeth
6、od:aAppropriatePreparationTechnique5030/DirectbCompoundCASNo.50355031503250215041Inject.Acetone67-64-1htccndccAcetonitrile75-05-8ppcndndndcAcrolein(Propenal)107-02-8ppccndndcAcrylonitrile107-13-1ppccndccAllylalcohol107-18-6htcndndndcAllylchloride107-05-1cndndndndc
7、t-Amylethylether(TAEE)919-94-8c/htndndcndct-Amylmethylether(TAME)994-05-8c/htndndcndcBenzene71-43-2cndccccBenzylchloride100-44-7cndndndndcBis(2-chloroethyl)sulfide505-60-2ppndndndndcBromoacetone598-31-2ppndndndndcBromochloromethane74-97-5cndccccBromodichloromethan
8、e75-27-4cndcccc4-Bromofluorobenzene(surr)460-00-4cndccccBromoform75-25-2cndccccBromomethane74-83-9cndccccn-Butanol71-36-3htcndndndc2-Butanone(MEK)78-93-