大学有机化学第三部分：醛酮、羧酸、羧酸衍生物

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1、大学有机化学第三部分：醛酮、竣酸、竣酸衍生物第三部分：醛酮、竣酸、竣酸衍生物1.HOOCCOOH2・+HOCH2CH2OH(C4H4O4)HOOCCH2CH2COOH3.2CHMgl(mol)(C4H4O3)CH3COOC2H54.12H3O+2CHMgl(mol)HCOOC2H55.12H3O+6・IPCICHOHmolHCOOC2H5+CH3COOC2H51CHONaH3O+27・1CH3COOC2H52CHONaH3O+NaOH8・29・CHONaOH2H3C10.OCHOPhCOOC2H5+CH3COPhll・12CHONaH3O+HCHO12・HCNHCHO

2、13・NaHSOHCHO14・(HO)HCHO15・CHOH/HCIHCHO16・2NHOHHCHO17・NHOHCH3COCH318・CH3COCH319・NaHSOCH3COCH320・C2H5OH/HCICH3COCH321・NH2OH・(H2O)10CH3COCH322.-(H2O)H2/PtCH3COCH323.CH3COCH324・HCN25.NaHSO326.(H2O)27.CHOH28.C2H5OH/HCINaOH30.H/Pt31.CH3COCH2CH332・H/PtCH3COCH2CH3NaHSO33.CH3COCH2CH334・12/NaOHCH

3、3COCH2CH335・C2H5OH/HCICH3COCH2CH337・NHOHCH3CH2CH2CHO38・NHOHNaHSO3CH3CH2CH2CHO39・CH3CH2CH2CHO40・H/PtCH3CH2CH2CHO41・C2H5OH/HCICH3CHO42・C2H5OH/HCICH3CHO43・H2/PtCH3CHO44・12/NaOHCH3CHO45・NaHSO3CHONaHSO346.CHOCHOH/HCI2547.CHOH/Pt4&H/Pt49.12/NaOH50.NaHSONH20H52.HCN53.l/NaOHCH3CH2CHOHCH2354.CH3

4、COCH3+NH2NHCONH255.(CH3)3CCHO+HCHO56・02N+NH2OH(CH3)3CCHO+H2NNHNO257・58.CH2=CHCHO+[Ag(NH3)2OH]59CH3CH2CHO60・CH3CH2CHO61.+Br262.HNO63・+64.CH3CHOC2H5OH/HCICH365.KCrO/H+HH3CCH3OH66.CH3CH2CHO67・HCN(CH3)2COHCH2CH368・CH3CH2CH2CHO69.0H・CHCHC0CIAICI370.COCH2CH3Zn/Hg/HCl71.CH3(CH2)4COOH72.SOCI1CH

5、3(CH2)4COCI2NH373.COOH74.COCI75CHOHCH3CH2COOH76.OHCH3COCI77・+COOHCH3CH2COOH78.CH3CH2COOC2H5+NH379.H3CH3C80.NH2+COOHOH812CH3CHOHCOOH82・COOHCOOH83・CH2COOH84・OHCOOH85・（CH3CO）2OH3C86.COOHCI/Fe2COOHCH2COOH87・2LiAlH4CH3COCH3OH・88・CH3CH2CH2COOH89.Cl/PCH3CH2CH2CI90・NaCNCH3CHCICOOH91.2CH2COOH2CH

6、2COOH92・CH2COOHCI/hv93.HNO/HSO94.+NO295.AICICH3COCOOH96・H/PtCH3COCOOH97・LiAIHCH3COCH2COOH9&LiAIHCH3COCH2COOH99・H/PtHOCH2CH2OH100・+CH3CHONHCOCH3H3C101.HNO/HSOZn/Hgcon.HCI102.CH3CH2CH2OHCrO103.Br2/0H-0104.ONaHSO3105.OHCCH2CH2CH2CH2CH2CHO106.CH2=CHCH2CHO107.H/NiCH2=CHCH2CHO10&UAIH4109・CHOH

7、NHNH2HOOCCOCH2COOH+110.2NHOHO111.0112.+NaOHNH113.+NaOHNaOH114.CH2C00HC00H115・Cl/hv116.CH3CHO117.+HCN卄+NaHS03CH3CH011&CH3CHO119.HOCH2CH2OH12CH3CHO120.C2H5MgBrCHOCHH2O/H+02NO+H2NNHNO2H121.CH3(CH2)2CHO+Ph3P+CH3C2H5OC2H5122.C2H5122.2CH3CH2CH2CHOKOH/H2O123.(CH3)3COCH31Br,NaOH/H2OH+2