Advances in analytical methods and occurrence of organic UV-filters in the environment — A review

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1、ScienceoftheTotalEnvironment526(2015)278–311ContentslistsavailableatScienceDirectScienceoftheTotalEnvironmentjournalhomepage:www.elsevier.com/locate/scitotenvReviewAdvancesinanalyticalmethodsandoccurrenceoforganicUV-filtersintheenvironment—AreviewSaraRamos,VeraHomem⁎,ArmindaAlves,LúciaSantosLEPABE—L

2、aboratoryforProcessEngineering,Environment,BiotechnologyandEnergy,FacultyofEngineering,UniversityofPorto,RuaDr.RobertoFrias,4200-465Porto,PortugalHIGHLIGHTS•StudiesaboutanalysisandoccurrenceofUV-filtersinenvironmentwerereviewed.•RiverwatershowedthehighestandbroadestUV-filterconcentrations.•UV-filtersa

3、repoorlystudiedinsoilandsediments,butdetectedintheμg/Lrange.•Tenstothousandsofng/gofBP3weredetectedinaquaticbiota.•Benzophenonederivativesarethemoststudiedanddetectedcompounds.articleinfoabstractArticlehistory:UV-filtersareagroupofcompoundsdesignedmainlytoprotectskinagainstUVAandUVBradiation,butRece

4、ived13March2015theyarealsoincludedinplastics,furniture,etc.,toprotectproductsfromlightdamage.TheirmassiveuseReceivedinrevisedform14April2015insunscreensforskinprotectionhasbeenincreasingduetotheawarenessofthechronicandacuteeffectsAccepted14April2015ofUVradiation.SomeorganicUV-filtershaveraisedsignifi

5、cantconcernsinthepastfewyearsfortheircon-tinuoususage,persistentinputandpotentialthreattoecologicalenvironmentandhumanhealth.UV-filtersEditor:D.Barceloendupinwastewaterandbecausewastewatertreatmentplantsarenotefficientinremovingthem,lipophilicKeywords:compoundstendtosorbontosludgeandhydrophilicsendup

6、inriverwater,contaminatingtheexistingbiota.UV-filtersTobetterunderstandtheriskassociatedwithUV-filtersintheenvironmentathoroughreviewregardingtheirEnvironmentphysicochemicalproperties,toxicityandenvironmentaldegradation,analyticalmethodsandtheiroccurrenceOccurrencewasconducted.AnalyticalmethodsHigher

7、UV-filterconcentrationswerefoundinrivers,reaching0.3mg/Lforthemoststudiedfamily,thebenzo-phenonederivatives.Concentrationsinthengtoμg/Lrangewerealsodetectedforthep-aminobenzoicacid,cinnamate,cryleneandbenzoy