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1、ChemicalKineticsandReactionDynamicsChemicalKineticsandReactionDynamicsSantoshK.UpadhyayDepartmentofChemistryHarcourtButlerTechnologicalInstituteKanpur-208002,IndiaAnamayaAC.I.P.cataloguerecordforthebookisavailablefromtheLibraryofCongressISBN1-4020-4546-8(HB)ISBN1-4020-4547-6(e-b
2、ook)CopublishedbySpringer233SpringStreet,NewYork10013,USAwithAnamayaPublishers,NewDelhi,IndiaSoldanddistributedinNorth,CentralandSouthAmericabySpringer,233SpringStreet,NewYork,USAInallthecountries,exceptIndia,soldanddistributedbySpringer,P.O.Box322,3300AHDordrecht,TheNetherlands
3、InIndia,soldanddistributedbyAnamayaPublishersF-154/2,LadoSarai,NewDelhi-110030,IndiaAllrightsreserved.Thisworkmaynotbetranslatedorcopiedinwholeorinpartwithoutthewrittenpermissionofthepublisher(SpringerScience+BusinessMedia,Inc.,233SpringStreet,NewYork,10013,USA),exceptforbriefex
4、cerptsinconnectionwithreviewsorscholarlyadaptation,computersoftware,orbysimilarordissimilarmethodologynowknownorhereafterdevelopedisforbidden.Theuseinthispublicationoftradenames,trademarks,servicemarksandsimilarterms,eveniftheyarenotidentifiedassuch,isnottobetakenasanexpressiono
5、fopinionastowhetherornottheyaresubjecttoproprietaryrights.Copyright©2006AnamayaPublishers987654321springeronline.comPrintedinIndia.ToMyMotherPrefaceReactiondynamicsisthepartofchemicalkineticswhichisconcernedwiththemicroscopic-moleculardynamicbehaviorofreactingsystems.Molecularre
6、actiondynamicsiscomingofageandmuchmorerefinedstate-to-stateinformationisbecomingavailableonthefundamentalreactions.Thecontributionofmolecularbeamexperimentsandlasertechniquestochemicaldynamicshasbecomeveryusefulinthestudyofisolatedmoleculesandtheirmutualinteractionsnotonlyingass
7、urfacesystems,butalsoinsolute-solutionsystems.Thisbookpresentstheimportantfactsandtheoriesrelatingtotherateswithwhichchemicalreactionsoccurandcoversmainpointsinamannersothatthereaderachievesasoundunderstandingoftheprinciplesofchemicalkinetics.Adetailedstereochemicaldiscussionoft
8、hereactionstepsineachmechanismandtheirrelations
